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6 <br />nitrate+nitrite and phosphorous. It is possible that samples with higher alkalinities may <br />require more preservative to reach the desired preservation pH values. <br />3.0 SUMMARY AND ASSESSMENT OF ANALYTICAL ACTIVITIES <br />3.1 Analytical Results <br />The field parameters and analytical results are displayed in Tables 3 and 4, respectively. A <br />discussion of any elevated concentrations or unusual results is provided below. <br />RS-5. The total aluminum and silver concentrations (160 and 30 µg/1, respectively) are <br />relatively high for a stream with a pH as high as 7.96. Total aluminum concentrations are <br />over three times the detection limit Total silver concentrations are three times the <br />detection limit. Without knowing mere about natural background conditions, it is impossible <br />to determine the cause cf these metal values. Cadmium concentrations were below <br />detection at 5µg/1. <br />Process Points. Total cyanide concentrations in the lower tailings pond, upper tailings pond <br />and the collection pond/duplicate were 0.58, 0.24 and 8/7.9 mg/1, respectively. WAD cyanide <br />concentrations were 0.56, 0.2 and 7.9/7.8 mg/1, respectively in these same process points. <br />Dissolved copper concentrations were 1.72, 2.33 and 17.4/18.9 mg/1 in the lower tailings, <br />upper tailings and collection ponds, respectively. <br />Field and Rinse Blank. The field blank (BMRI DI water) had somewhat elevated <br />concentrations of iron (80 µg/1), silica (34.5 mgp) and zinc (20 µg/I). The rinse blank had <br />somewhat elevated concentrations of iron (30 µg/I), but they were below those in the field <br />blank. <br />Groundwater Wells. Well M-13 had a cyanide concentration of 30 µg/l, which is above the <br />detection limit of 20 µg/1; WAD cyanide was below detection. According to Core <br />Laboratories, 20 µg/t is the appro~dmate practical quantitation limit (PQL). The instrument <br />detection limit for this vety sensitive colorimetric technique is approximately 5 µg/I (personal <br />communication, Lyn Benkers, Core Laboratories, 4/15/93). This well also had a silver <br />concentration (60 µg/I) that was higher than that of the other wells or RS-S. Dissolved <br />copper concentrations in well M-12 (20 µg/l) were higher than in the other wells, which were <br />below detection in copper. <br />RCG/Hagler, Bailly, Inc. <br />