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T-4518 <br />61 <br />electrum-stromeyerite occurrences also contain chalcopyrite. Petrographic observations <br />and the high percentage of electrum grains sharing boundaries with chalcopyrite indicate <br />that electrum is most closely related to the second stage of chalcopyrite (Figs. 37a and b). <br />The common intergrowth of electrum with galena and sphalerite may be attributed to <br />replacement of these minerals during chalcopyrite-electrum deposition. Gold could not be <br />correlated with copper, zinc, or lead geochemically but a weak correlation between gold <br />and siiver was found (Appendix D). <br />Electrum grains were analyzed by microprobe to determine the Au:Ag ratio and to <br />determine any relationship between the ratio and associations with other minerals such as <br />chalcopyrite, sphalerite, and galena. Thirty analyses on thirteen electrum grains (Appendix <br />E) revealed a cluster of compositions at approximately 70% gold and 30% silver (Fig. 38). <br />However, compositions range from 37% to 85% gold. Variable compositions were <br />recorded within several grains (Fig. 39). It is unclear if the low and high gold electn~m <br />reflect different stages of mineralization from the more common 70% gold or if the <br />electrum composition is simply variable. <br />Electrum with a gold:silver ratio of 85:15 shared grain boundaries with only <br />chalcopyrite and gangue minerals. However, there was also electrum with lower At.:Ag <br />ratios sharing grain boundaries with only chalcopyrite. <br />A third period of chalcopyrite deposition resulted in the blebs in sphalerite (Fig. <br />35). The timing of this event is unclear. It is distinct from the second stage of <br />chalcopyrite, however, in that it is not replaced by stromeyerite. <br />One grain of acanthite was found occurring with galena and tetrahedrite during <br />microprobe analysis. It was approximately 2µm in diameter, irregular in shape, and could <br />not be distinguished from the tetrahedrite under the microscope (Fig. 40). <br />