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y ~ a , <br />Division of Mining and Geology <br />Department of Natural Resources <br />January 13, 1993 <br />Page 2 <br />The ground water and surface water samples were collected according <br />to the procedures identified in the Protocols by Halepaska and <br />Associates, Inc. personnel during the period October 12 through <br />October 15, 1992. In addition, water samples were collected from <br />the five process points; upper and lower tailings impoundments, <br />collection pond, pre-detox and post-detox. These samples are <br />labelled accordingly on the attached analysis report. No samples <br />were obtained from the lysimeters, due to the absence of <br />collectible fluid in the lysimeters. <br />The samples were submitted for analyses of the water quality <br />parameters listed in Table 1. Sample handling and analyses <br />proceeded in accordance with the Protocols. A copy of the report <br />prepared by Core Laboratories is enclosed as Appendix A. <br />Field quality control was instituted with the collection of a field <br />duplicate, field blank and rinse blanks, to evaluate analytical and <br />sample handling techniques. The sample identified as M-24 is a <br />duplicate sample of M-4. The sample identified as FB is a field <br />blank consisting of on-site laboratory-provided de-ioni2ed, <br />distilled water. The samples identified as BFRB and BLRB are rinse <br />blanks of the barrel filter used in filtering field samples and the <br />bailer used in collecting ground water samples, respectively. <br />Surface water samples were collected at surface stations RS-1, RS-2 <br />and RS-5. The other surface water stations were found to be dry or <br />have insufficient flow to collect samples. In addition, the lower <br />sediment sampler was removed from station RS-1 and submitted for <br />total suspended solids analyses. The sample is identified as RS- <br />1SS. Sediment samplers at the other surface water stations were <br />dry. <br />During the purging of well M-4, the discharge water progressively <br />became cloudy and turbid. This behavior is common to past sampling <br />events. During this sampling event, however, the water had a <br />chlorine-like odor, and the specific conductivity (1,524,µs/cm) and <br />pH (6.3) measurements were anomalous with past trends. Analysis <br />indicates that this sample has elevated levels of ammonia (3.76 <br />mg/L) and chloride (G3 mg/L) over historical values. <br />With the exception of cadmium, the analyses from any of the other <br />surface and ground water samples do not indicate any anomalous <br />values. Core Laboratories has prefaced their analysis report with <br />a narrative indicating that several cadmium values (samples <br />collected at RS-1, RS-2, RS-5) had dissolved values that were <br />