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121911 IS:323S FNUM TOCC G11mH TO Mnc~ AIDeO S OF ~ <br />irnmediatz Project aria. <br />~~ Rreter chemistn of the bedrock ayuiters is dis4inet from surface and outwash aquifer waters. Water <br />tram the Depot. Clark. R' ooteu and northvvzst wells has mazkedly greater TDS concentrations, plus a <br />shift in water pPe toward calcium-sodium sulfate. <br />Given the preszncz of sulfatzs and organic carbons in shaley and limey bedrock aquifers such as the <br />Niobrara, Carlisle or Greenhorn Formations, plus the natural occurrence ofsulfate-reducing bacteria, <br />hydrogen sulfide (gas having a rotten egg odor) can bz naturally formed in these aquifers and <br />produced from springs and wells. <br />No reports of hydrogrn sulfide are known in the immediate area of the Project, north of the Arkansas <br />River, South of the River, where several wells develop water supplies from the Niobrara, Carlisle or <br />Greenhorn Formations, hydrogen sulfide odors may readily, and naturally, occur. Such oceurrrnces <br />can be seasonal in response to water level and nutrient availability changes, or may be episodic due to: <br />longer-period climatic changes, <br />changes in net water withdrawals, and/or <br />local recharge of nutrrnt- and carbon-rich water from leach fields, pastures or feedlots. <br />These occurrences have no cause-and~ffect relationship to the Project. <br />Conclusions <br />(1) The impact ofthe Project will be io increase the water table elevation beneath the plant area. <br />This may also be reelected in the Dakota Group underlying the plant area, with iLs water table <br />• or potentiometric head increasing somewhat (2 to 5 feet), with lesser rises away from the plant. <br />Slightly greater spring and seep flows may also result. <br />(2) The increased water table elevation in the outwash aquifer will be more than offset by <br />removing irrigation from the hayfields and pastures of the adjacent ranch. This change would <br />occur at the direction of the Division of Water Resources, as the result of its administration of <br />junior water rights. This may lower the water table sufficiently to reduce spring flows at the <br />river and adversely affect dovmgradient springs or wells. <br />(3) The possible increases in potrntiometric head or water table in the Dakota Group could be <br />manifested as somewhat greater bedrock spring discharge rates to the Arkansas River, if DWR <br />does not administer the junior irrigation rights. >f irrigation is stopped, a decline in bedrock <br />spring flows may occur. <br />(4) Hydraulic impacts [o the Dakota Group and other bedrock ayuifers cannot be expected to <br />occur south of the River, as the River serves as a hydraulic boundary having nearly conslant- <br />head conditions. Furthermore, faults to the southwest, south, southeast and east of the Project <br />create sWctural blocks that will be hydraulically separate bedrock units. <br />(5) Changes in bedrock well production or water quality (including hydrogen sulfide presence) in <br />areas south of the River, and in wells producing water from bedrock aquifers structurally <br />isolated from the Project, will he duz to natural or other non-Project related factors. <br />Hvdrogeo(ogy Raporr-Porkdala Prolacl Page J of J <br />