G:
<br />MATERIAL SAFETY DATA SHEET
<br />
<br />lipoaun Limib:
<br />PEHL•A ACGIN
<br />TLL'g•
<br />sTEL
<br />Unity
<br />Aoa&eW, t0^ 10" NG mglm°
<br />(z,aolmknpn.wny},
<br />naogy112<tnyne,yq
<br />ester
<br />'&hour TWA unless otherwise noted.
<br />"Based w adopted limn for 2,4-D.
<br />Ventilation:
<br />Where engbeering cwVORs are Indicated by sPecinc
<br />use wntllGons or a potential for excessNe exposure,
<br />use kxal exhaust ventilation at the point of generatan.
<br />9. PHYSICAL AND CHEMICAL PROPERTIES
<br />NOTE: Physical data are typical values, but may vary
<br />from sample b sample. A typical value should not be
<br />wnstmed as a guaranteed-anaysis or as.a specifica-
<br />tion.
<br />Physical Appearenu: Amper liquid.
<br />Odor: Characteristic phenolic.
<br />pH; Not Available.
<br />Specific Gravity: Approxbnatey 1.13
<br />Water Solubility: Product is emulsifiable in water.
<br />Melting Point Range: Not Avadable.
<br />Boiling Point Range: Nat Available. Based on cam.
<br />portents, expected to be >20D'C.
<br />Vapor Pressure: 3.6 x 10'B mm Hg ~ 25'C (data
<br />on 2,4-D 2EHE)
<br />Molecular Weight: 333.27 (data an 2.4D 2EHE)
<br />10. STABILITY AND REACTIVrTY
<br />Chemical Stability: This maledal b stable under nor-
<br />mat handCVig and sorage coriditlons described b Seo-
<br />don 7.
<br />Conditions To Be Avoidetl: Excessive heat
<br />Incompatibility With Other Matedals: Shong oxid'a-
<br />ing agents: bases, acids.
<br />Hazardous Decompositon Products:
<br />Decompostion Type: Thermal
<br />Decomposition Products: Hydrogen chloritle, other
<br />chbdne wmpountls, oxides of carbon and nitrogen.
<br />Hazardous Polymerization: Does not occur.
<br />11. TOXICOLOGICAL INFORMATION
<br />Toxieoloeical Data;
<br />Data on Nis prwuct
<br />Eye Inhation: Minimally 4dtadrrg (RabbN).
<br />sate Irritation: slgnty imitanrg (Rabbit).
<br />Dermal: Slighty toxic. (Rabbit LDsa >2020 mgbtg).
<br />Inhalation: Sfghty toxb. (Ratbhr LCso: >5.12 mgIL)
<br />Oral: Slghty toxb. (Rai LDso 1360 mg/kg).
<br />This product wntada substances drat are wrtsklered
<br />to be probable or suspected human carcinogens as
<br />follows:
<br /> Rngubtory Agncy
<br />uatmv Aa a.unnvw
<br />Ingndbnb Namn GSNA IARC NTP ACGIN
<br />Cnbropnanoxy nenluana No 29 No No
<br />(Also see Section 3J
<br />12 ECOLOGICAL INFORMATION
<br />Aouatic Toxici
<br />Data on 2,4-D 2EHE or EC formulation:
<br />9fihr LCso Bluegdl: >5 mgq
<br />9C>hr LCso Rainbow Trout 72 rtgA
<br />48-hr ECso Daphnia: >5 m9/l
<br />Avian Toxici
<br />Data on 2,4-D 2EHE:
<br />Bobwhite Ouail Dietary LCso: >5620 pPm
<br />Mallard Duck B-day Dietary LCso: >5620 ppm
<br />Environmental Fate:
<br />In representative laboretory and field studies, 2,4D
<br />2EHE repitly hytlroyzetl to parent acid. The typcal
<br />half-life of the resultant 2,4•D acid ranged from a few
<br />tlays to a few weeks.
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2
<br />13. DISPOSAL CONSIDERATIONS
<br />Waste Disposal Method:
<br />Pesticitle wastes are toxic. Improper disposal of ex-
<br />cess pesticitle is a vblatbn of Federal Law and may
<br />crontambate ground water. N d,ese wastes canrpf be
<br />disposed of by use according to label Instructbns,
<br />wntact your State Pesticide or Environmental Con-
<br />trol Agency, or the HazaNous Waste representatve at
<br />the nearest EPA Regional Office for guidarrz.
<br />Container Handllne and Disposal:
<br />Do wtreuse empty wntainer. Triple dose (ar equiv-
<br />alent) adding dnsate to application equipment Then
<br />offer empy wntainer for recycling or recond'NOnbg, or
<br />puncture arW dispose of in a sandary Iantlfi0 or by kl-
<br />cineretion, or, if alkrbred by State and ktcal autipdties,
<br />by burning. If bumetl, stay out of smoke.
<br />14. TRANSPORTATION INFORMATION
<br />NOTE: Information is for surface transportation of
<br />package saes gerrerady offered antl tloes rwt atltlress
<br />regulatory variatbns due to changes in package sae,
<br />mode of shipment or other wnd'NOns.
<br />Packages containing less than 18.5 gallons of this
<br />product are generely not regulated. For packages
<br />containing 16.5 8adons or higher.
<br />DO7 Proper Shipping Name: ENVIRONMENTALLY
<br />HAZARDOUS SUBSTANCE, LIOUID, N.O.S. (2,4D
<br />ESTER), RO (2,4D ESTER)
<br />DOT HazaM Class f I.D. No.: 9l UN3082
<br />DOT Label: Class 9
<br />U.S. Sur/aw Fmfght ClassfOcatlon: Weed killNg
<br />compound, N.O.I.B.N
<br />15. REGULATORY INFORMATION
<br />Federal Reaulations•
<br />TSCA Inventory: This product Is excepted from TSCA
<br />because tt's~wley for FIFRA regulatetl use.
<br />SARA Hazard Notification:
<br />Hazard Categories Under Crneda of SARA Trite III
<br />Rules (40 CFR Part 370):
<br />Fin: RaacWn: MNUaoI
<br />Proavra: Awtn
<br />x..nn: Cnronk
<br />x..ah:
<br />W No No Yes Van
<br />Seclbn 373 Toxic Chemical(s):
<br />ACETIC ACID, (2,4DICHLOROPHENOXY}, 2-
<br />EfHYLHEXYL ESTER, GAS NO. 1928-43-4 (efi.6%
<br />by weight in product)
<br />Reportable Ouantiry (RO) under U.S. CERCLA:
<br />Ingnabnr Rq
<br />ACETIC ACm, (2.4DH:MLOROPHENOXY}, tpD ®a
<br />2-ETHYLHE%YL ESTER
<br />Selected State Repulations•
<br />This product contains the following wmponents Nat
<br />are regubtetl under Caldomia Pr0P0°Id00 65:
<br />InpntlNnt Gnco Wproaucwa Rbx Lavnl lopMay)
<br />Mama Lbt Lbl Gpromia NNnrm
<br />Not Not Ap- NM Not ~ Nol
<br />ApprnbN p°nDN Appl®bb ApDinbN pppF
<br /> ®bN
<br />18. OTHER INFORMATION
<br />National Fire Protection Assadation (NFPAo) Haz
<br />and Ratings:
<br />Ratlnpa Inr Thb Pr00oct Nry to Ratbga
<br />z H.aM HanN o Mbkul
<br />i Fbmmabaly i SIgM
<br />o inNabay z Hna.raN
<br /> 3 aarbua
<br /> a seven
<br />Abbreviations and Acronyms Nat Defined Else-
<br />where:
<br />ACGIH American Conference of Govemmentaf Indus-
<br />trial Hygienists
<br />ANSI Amedcan National Standards Institute
<br />CERCLA Comprehensive Environmental Response,
<br />Campensatlon and Liability Act
<br />Database and format copyright ®by C&P Press. All tights reserved.
<br />DOT Department of Transporaation -
<br />FIFRA Fedeal Insecticide, Fungicide end Rodenticide
<br />Act
<br />IARC Intemadonal Agency for Research on Cancer
<br />MSHA Mine Safety and Health Administration
<br />NIOSH Natlonal InsOWte for Owupational Safey and
<br />Health
<br />NTP Nafiwal Tozbobgy Program
<br />OSHA Occupational Safety end Health Administration
<br />PEL Permissible Exposure Unlit
<br />SARA Suparfund ~Amentlmerds and Reatrdror¢adon
<br />Act of 1866
<br />STEL Shart Tenn Exposure lJmit
<br />TLV Threshold Limit Value
<br />TSCA Toxic Substances Comrd Act
<br />TWA 7rtne Weightetl Average
<br />USEPA U.S. Ernironmerdat ProteLlbn Agency
<br />This Matedal Safety Data Sheet (MSDS) serves tln-
<br />ferem purposes then and DOES NOT REPLACE OR
<br />MODIFY THE EPA-ACCEPTED PRODUCT LABEL-
<br />ING (attachetl to and awompanyNg Ne Drotlud core
<br />tattier). This MSDS provides important health, eatery
<br />and environmental Informetbh for ampbyers, empby-
<br />ees, emergency responders and others hantlling large
<br />quant0ies of the product in activities generely oNei
<br />than prwucl use, whte the IabepnB Provides drat d}
<br />formadw specifrcally for pradud use b the ordinary
<br />worse.
<br />Use, storage and disposal of pestlcide products are
<br />regulated by the F3A under dre auNorily of die Federal
<br />Insectcde, Fungicide, and RodenSUtle Act (FIFRA)
<br />through tits prwucl labeling, and all necessary end
<br />apPropnata precautionary, use, storage, and deposal
<br />Informaton b sal forth on Nat label"gg. It is a vkdadon
<br />of fetlerel law to use a pesddde product b any manner
<br />not prescdbetl on Ne EPA-awePted label.
<br />Adhough the ldormatbn emf rewmmendations set
<br />forth herein (bere'mafter "Information") are presented
<br />b good fatth and beliavetl to be wnect as of the
<br />tlate hereof, Nufarm,-Inc, makes no-representatbns
<br />as to the wmpletertess or acwrecy thereof. Inforrrla-
<br />don is supDpetl upon Ne condnbn Nat the.persoris
<br />receiving same wfil make their own detertninatbn as
<br />to Its suitabiltty for Neir Durfroses pHOr to use. In w
<br />event will Nuhann, Inc. be responsible for damages
<br />of any nature whatsoever resultirg from the use or of
<br />reliance IlpDfl Intortnafion. NO REPRESENTATIONS
<br />OR WARRANTIES, ETfHER EXPRESS OR IMPLIED,
<br />OF MERCHANTABILfTY, FITNESS FOR A PARTIG
<br />ULAft PURPOSE OR OF ANY OTHER NATURE ARE
<br />MADE HEREUNDER WITH RESPECT TO INFORMA-
<br />710M ORTHE PRODUCTTO WHICH tNFORMA710N
<br />REFERS.
<br />WEEDONEa b a registered trademark of Nufann, inc.
<br />VID 5.14.03
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