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G: <br />MATERIAL SAFETY DATA SHEET <br /> <br />lipoaun Limib: <br />PEHL•A ACGIN <br />TLL'g• <br />sTEL <br />Unity <br />Aoa&eW, t0^ 10" NG mglm° <br />(z,aolmknpn.wny}, <br />naogy112<tnyne,yq <br />ester <br />'&hour TWA unless otherwise noted. <br />"Based w adopted limn for 2,4-D. <br />Ventilation: <br />Where engbeering cwVORs are Indicated by sPecinc <br />use wntllGons or a potential for excessNe exposure, <br />use kxal exhaust ventilation at the point of generatan. <br />9. PHYSICAL AND CHEMICAL PROPERTIES <br />NOTE: Physical data are typical values, but may vary <br />from sample b sample. A typical value should not be <br />wnstmed as a guaranteed-anaysis or as.a specifica- <br />tion. <br />Physical Appearenu: Amper liquid. <br />Odor: Characteristic phenolic. <br />pH; Not Available. <br />Specific Gravity: Approxbnatey 1.13 <br />Water Solubility: Product is emulsifiable in water. <br />Melting Point Range: Not Avadable. <br />Boiling Point Range: Nat Available. Based on cam. <br />portents, expected to be >20D'C. <br />Vapor Pressure: 3.6 x 10'B mm Hg ~ 25'C (data <br />on 2,4-D 2EHE) <br />Molecular Weight: 333.27 (data an 2.4D 2EHE) <br />10. STABILITY AND REACTIVrTY <br />Chemical Stability: This maledal b stable under nor- <br />mat handCVig and sorage coriditlons described b Seo- <br />don 7. <br />Conditions To Be Avoidetl: Excessive heat <br />Incompatibility With Other Matedals: Shong oxid'a- <br />ing agents: bases, acids. <br />Hazardous Decompositon Products: <br />Decompostion Type: Thermal <br />Decomposition Products: Hydrogen chloritle, other <br />chbdne wmpountls, oxides of carbon and nitrogen. <br />Hazardous Polymerization: Does not occur. <br />11. TOXICOLOGICAL INFORMATION <br />Toxieoloeical Data; <br />Data on Nis prwuct <br />Eye Inhation: Minimally 4dtadrrg (RabbN). <br />sate Irritation: slgnty imitanrg (Rabbit). <br />Dermal: Slighty toxic. (Rabbit LDsa >2020 mgbtg). <br />Inhalation: Sfghty toxb. (Ratbhr LCso: >5.12 mgIL) <br />Oral: Slghty toxb. (Rai LDso 1360 mg/kg). <br />This product wntada substances drat are wrtsklered <br />to be probable or suspected human carcinogens as <br />follows: <br /> Rngubtory Agncy <br />uatmv Aa a.unnvw <br />Ingndbnb Namn GSNA IARC NTP ACGIN <br />Cnbropnanoxy nenluana No 29 No No <br />(Also see Section 3J <br />12 ECOLOGICAL INFORMATION <br />Aouatic Toxici <br />Data on 2,4-D 2EHE or EC formulation: <br />9fihr LCso Bluegdl: >5 mgq <br />9C>hr LCso Rainbow Trout 72 rtgA <br />48-hr ECso Daphnia: >5 m9/l <br />Avian Toxici <br />Data on 2,4-D 2EHE: <br />Bobwhite Ouail Dietary LCso: >5620 pPm <br />Mallard Duck B-day Dietary LCso: >5620 ppm <br />Environmental Fate: <br />In representative laboretory and field studies, 2,4D <br />2EHE repitly hytlroyzetl to parent acid. The typcal <br />half-life of the resultant 2,4•D acid ranged from a few <br />tlays to a few weeks. <br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET 2 <br />13. DISPOSAL CONSIDERATIONS <br />Waste Disposal Method: <br />Pesticitle wastes are toxic. Improper disposal of ex- <br />cess pesticitle is a vblatbn of Federal Law and may <br />crontambate ground water. N d,ese wastes canrpf be <br />disposed of by use according to label Instructbns, <br />wntact your State Pesticide or Environmental Con- <br />trol Agency, or the HazaNous Waste representatve at <br />the nearest EPA Regional Office for guidarrz. <br />Container Handllne and Disposal: <br />Do wtreuse empty wntainer. Triple dose (ar equiv- <br />alent) adding dnsate to application equipment Then <br />offer empy wntainer for recycling or recond'NOnbg, or <br />puncture arW dispose of in a sandary Iantlfi0 or by kl- <br />cineretion, or, if alkrbred by State and ktcal autipdties, <br />by burning. If bumetl, stay out of smoke. <br />14. TRANSPORTATION INFORMATION <br />NOTE: Information is for surface transportation of <br />package saes gerrerady offered antl tloes rwt atltlress <br />regulatory variatbns due to changes in package sae, <br />mode of shipment or other wnd'NOns. <br />Packages containing less than 18.5 gallons of this <br />product are generely not regulated. For packages <br />containing 16.5 8adons or higher. <br />DO7 Proper Shipping Name: ENVIRONMENTALLY <br />HAZARDOUS SUBSTANCE, LIOUID, N.O.S. (2,4D <br />ESTER), RO (2,4D ESTER) <br />DOT HazaM Class f I.D. No.: 9l UN3082 <br />DOT Label: Class 9 <br />U.S. Sur/aw Fmfght ClassfOcatlon: Weed killNg <br />compound, N.O.I.B.N <br />15. REGULATORY INFORMATION <br />Federal Reaulations• <br />TSCA Inventory: This product Is excepted from TSCA <br />because tt's~wley for FIFRA regulatetl use. <br />SARA Hazard Notification: <br />Hazard Categories Under Crneda of SARA Trite III <br />Rules (40 CFR Part 370): <br />Fin: RaacWn: MNUaoI <br />Proavra: Awtn <br />x..nn: Cnronk <br />x..ah: <br />W No No Yes Van <br />Seclbn 373 Toxic Chemical(s): <br />ACETIC ACID, (2,4DICHLOROPHENOXY}, 2- <br />EfHYLHEXYL ESTER, GAS NO. 1928-43-4 (efi.6% <br />by weight in product) <br />Reportable Ouantiry (RO) under U.S. CERCLA: <br />Ingnabnr Rq <br />ACETIC ACm, (2.4DH:MLOROPHENOXY}, tpD ®a <br />2-ETHYLHE%YL ESTER <br />Selected State Repulations• <br />This product contains the following wmponents Nat <br />are regubtetl under Caldomia Pr0P0°Id00 65: <br />InpntlNnt Gnco Wproaucwa Rbx Lavnl lopMay) <br />Mama Lbt Lbl Gpromia NNnrm <br />Not Not Ap- NM Not ~ Nol <br />ApprnbN p°nDN Appl®bb ApDinbN pppF <br /> ®bN <br />18. OTHER INFORMATION <br />National Fire Protection Assadation (NFPAo) Haz <br />and Ratings: <br />Ratlnpa Inr Thb Pr00oct Nry to Ratbga <br />z H.aM HanN o Mbkul <br />i Fbmmabaly i SIgM <br />o inNabay z Hna.raN <br /> 3 aarbua <br /> a seven <br />Abbreviations and Acronyms Nat Defined Else- <br />where: <br />ACGIH American Conference of Govemmentaf Indus- <br />trial Hygienists <br />ANSI Amedcan National Standards Institute <br />CERCLA Comprehensive Environmental Response, <br />Campensatlon and Liability Act <br />Database and format copyright ®by C&P Press. All tights reserved. <br />DOT Department of Transporaation - <br />FIFRA Fedeal Insecticide, Fungicide end Rodenticide <br />Act <br />IARC Intemadonal Agency for Research on Cancer <br />MSHA Mine Safety and Health Administration <br />NIOSH Natlonal InsOWte for Owupational Safey and <br />Health <br />NTP Nafiwal Tozbobgy Program <br />OSHA Occupational Safety end Health Administration <br />PEL Permissible Exposure Unlit <br />SARA Suparfund ~Amentlmerds and Reatrdror¢adon <br />Act of 1866 <br />STEL Shart Tenn Exposure lJmit <br />TLV Threshold Limit Value <br />TSCA Toxic Substances Comrd Act <br />TWA 7rtne Weightetl Average <br />USEPA U.S. Ernironmerdat ProteLlbn Agency <br />This Matedal Safety Data Sheet (MSDS) serves tln- <br />ferem purposes then and DOES NOT REPLACE OR <br />MODIFY THE EPA-ACCEPTED PRODUCT LABEL- <br />ING (attachetl to and awompanyNg Ne Drotlud core <br />tattier). This MSDS provides important health, eatery <br />and environmental Informetbh for ampbyers, empby- <br />ees, emergency responders and others hantlling large <br />quant0ies of the product in activities generely oNei <br />than prwucl use, whte the IabepnB Provides drat d} <br />formadw specifrcally for pradud use b the ordinary <br />worse. <br />Use, storage and disposal of pestlcide products are <br />regulated by the F3A under dre auNorily of die Federal <br />Insectcde, Fungicide, and RodenSUtle Act (FIFRA) <br />through tits prwucl labeling, and all necessary end <br />apPropnata precautionary, use, storage, and deposal <br />Informaton b sal forth on Nat label"gg. It is a vkdadon <br />of fetlerel law to use a pesddde product b any manner <br />not prescdbetl on Ne EPA-awePted label. <br />Adhough the ldormatbn emf rewmmendations set <br />forth herein (bere'mafter "Information") are presented <br />b good fatth and beliavetl to be wnect as of the <br />tlate hereof, Nufarm,-Inc, makes no-representatbns <br />as to the wmpletertess or acwrecy thereof. Inforrrla- <br />don is supDpetl upon Ne condnbn Nat the.persoris <br />receiving same wfil make their own detertninatbn as <br />to Its suitabiltty for Neir Durfroses pHOr to use. In w <br />event will Nuhann, Inc. be responsible for damages <br />of any nature whatsoever resultirg from the use or of <br />reliance IlpDfl Intortnafion. NO REPRESENTATIONS <br />OR WARRANTIES, ETfHER EXPRESS OR IMPLIED, <br />OF MERCHANTABILfTY, FITNESS FOR A PARTIG <br />ULAft PURPOSE OR OF ANY OTHER NATURE ARE <br />MADE HEREUNDER WITH RESPECT TO INFORMA- <br />710M ORTHE PRODUCTTO WHICH tNFORMA710N <br />REFERS. <br />WEEDONEa b a registered trademark of Nufann, inc. <br />VID 5.14.03 <br />Powered by C&P Press. <br /> <br /> <br />s <br /> <br />