|
MATERIAL SAFETY DATA SHEET
<br />TRANSLINE*
<br />ER8ICIDE
<br />mergency Phone: 7-800.992-5994
<br />ow AgmBdences LLC
<br />Intlianapolis, IN 46268
<br />EBectiva Date: ?114/03
<br />Product Code: 11388
<br />MSDS: 002805
<br />1. PRODUCT AND COMPANY IDENTIFICATION:
<br />PRODUCT: Transline• Herbidde
<br />COMPANY IDENTIFICATION:
<br />Dow AgroSdences
<br />9330 Zionsville Road
<br />Indianapolis, IN 4626&1789
<br />2. COMPOSTfIONIINFORMATION ON INGREDI•
<br />EMS:
<br />Gopyra9tl: 13,6DIMbro-2- CASH 05]]50-e5-5 Op.9%
<br />pyrbbataNOxylceW).
<br />MprweNendemins sell
<br />Inert b9rttlbnle, bbl, iMutlin9: 59.1%
<br />uoprwrr.bonw case oooos]-ss-o
<br />Poyplywl 26.2 ChSM 0690$9-a9.e
<br />This document is prepared pursuant ro the OSHA Haz-
<br />ard Communicadorl Standard (29 CFR) 1910.1200).
<br />In additbn, other substances not'Hazardous' per this
<br />DSHA Stantlartl maY be listed. Where Proprietary in-
<br />gretlbnt stxrvrs, the identity may be made available as
<br />provided b mss standard.
<br />3. HAZARDOUS IDENTIFICATIONS:
<br />EMERGENCY OYERYIEW
<br />Hazardous Cherrriol. Reddsh-brovm IiquW, sweet
<br />odor. Sight transient corneal injury may occur. Pro-
<br />longed exposure rosy cause skin irnfa8on. LDSp for
<br />skin absorption In rabbis is >5000 mgacg. Oral LDSp
<br />for refs H >5000 mg/kg. Inhalation LCSO for rats 15
<br />>3.0 mglL.
<br />EMERGENCY PHONE NUMBER: 7.800-992-5994
<br />POTENTIAL HEALTH EFFECTS: This section in-
<br />clutles possible adveree effects, which could occur 'rf
<br />his material is not handled in the recommended mas-
<br />er.
<br />~ :May cause very slight transient (temporary)
<br />corneal injury. Vapors may instate me eyes.
<br />SKIN: Prolonged exposure may cause moderate skin
<br />irritation. A single probn9ed exposure N not likety to
<br />result in the material being absorbed mrough me skin
<br />in harmful amounts. The LOso for skin absorption in
<br />rehbds is >5000 mg/kg.
<br />INGESTION: Single dose oral toxicity b extremey low.
<br />The Dint LDSp for rats is >5000 mglkg. No hazards
<br />anticipated horn swallowing small amounts incidental
<br />to normal handling operations.
<br />INHALATION: Excessive vapor concentrations are at-
<br />tainable and could be hazardous on single exposure.
<br />The aerosd LCSp far rats h >3.0 mg/L for 4 hours. Ez-
<br />cessiveexposure (400 ppm) to isopropanol may cause
<br />eye, nose and throat Irritation. Incoortlinadon, confu-
<br />sion, hypenensbn, hypomertnia, ciroulatory collapse,
<br />respiratory arest antl death may occurfolbwing bnger
<br />duration of higher levek. Observations in animals hr-
<br />clude middle ear lining damage upon exposure to va-
<br />pors d isopropand.
<br />SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: In
<br />animals, effects have been reposed on me rolbwing
<br />organs: liver acrd kidney. Obeervatigns in animals co-
<br />crude lethargy. For isopropanol: Kidney effects acrd/w
<br />tumors have been observed In male rats. These ef-
<br />fects are believed to be spades specdc antl unlikely
<br />to occur in humans.
<br />LANCER INFORMATION: Fw the components
<br />tested, did not cause cancer in laboratory animals.
<br />TERATOLOGY (BIRTH DEFECTS): Clopyral'b
<br />causetl birth defects in test animals, but Doty at greatty
<br />exaggerated doses that were severely toxic to the
<br />mothers. No b(sh tlefects were observed in animals
<br />given clopyradd atl doses severe) times greater than
<br />those expected during normal exposure. Isopropyl
<br />akohd at extremely hgh fgrreenlrafiona has been
<br />reposed to cause hinh tlefects and fetal toxicity in
<br />rats. At lower wncenUafions meta were no effects on
<br />y; . me fetus.
<br />'~ ~~#` REPRODUCTIVE EFFECTS: Fw the components
<br />testeq in animal studies, has been shown tort b inter-
<br />fere with reproducfwn.
<br />UPDATES AVAILABLE AT VJVJW.GREENBOOK.NET ~
<br />4. FIRST AID:
<br />EYES: Hd0 eyes open and rklse skrvdy and gently
<br />wRh water for iS20 minutes. Remove contact lenses,
<br />8 present after the first 5 Mnutes, then cantinue rins-
<br />ing eyes. Call a poison control center or doctor for
<br />treatment advice.
<br />SKIN: Take oft contarrunatetl coming. Rinse skin im
<br />mediateN wim plenty of water far 15-20 minutes. Call
<br />a poison control center or doctor for treatmem advice.
<br />INGESTION: Ca0 a poison control center or tlousar
<br />lrrunediatety for beatment advice. Have person sip
<br />a glass d water 6 able to swallow. Do not intluce
<br />vomifing unless IoW to do so by the poison contra
<br />center or doctor, Do not give artyming bt' mouth to an
<br />unconscious person.
<br />INHALATION: Move person to Sesh air. If person is
<br />not breaching, caA 811 or ambulance, then give arti-
<br />fidal respimfion, preterabN by mourn to motNt. Ca0
<br />a poison Wntrol center or doctor for further treatment
<br />advice.
<br />NOTE 70 PHYSICDIN: No specific antidote. Support-
<br />ive care. Treatmem based on jutlgmem of the physV-
<br />cian in response ro reactions of me pedant
<br />5. FIRE FIGHTING MEASURES:
<br />FLASH POINT: 11TF (47.2'C)
<br />METHOD USED: TCC
<br />FLAMMABLE LIMBS
<br />LFL• Not determined
<br />UFL• Not determined
<br />EXTINGUISHING MEDIA: Water fog, alcohol resisl8nt
<br />foam, COr, tlry chemical, or foam preferted.
<br />FIRE & EXPLOSION HAZARDS: Toxic, inilallng
<br />fumes may be produced B product k kwoNed in a
<br />fire. Contain water from fire-fightlng to prevent entry
<br />IMO surtace w ground water.
<br />FIRE-FIGHTING EQUIPMENT: Under fire wrldi6ons
<br />use a posttive-pressure sect-contained breathing appa-
<br />ratus acrd protective doming.
<br />6. ACCIDENTAL RELEASE MEASURES:
<br />ACTION 70 TAKE FOR SPIIlSNEAKS: Absorb
<br />small spills with ineR materal such as sawtlustor sand.
<br />Repos large sptds ro Dow AgroSci'ences an 1-800.992-
<br />5994.
<br />7. HANDLING AND STORAGE:
<br />PRECAUTONS TO BE TAKEN IN HANDLING AND
<br />STORAGE: Keep out d reach of df8tlren ant ani-
<br />mals. Do not swalow+. Avoid cantacl wim eyes, skin
<br />and clothing. Wash thoroughy after handling. Re-
<br />move and wash contaminated Doming. Store b org-
<br />inal container vbm the lid lightly cased. Thos product
<br />ks combustible. Do not use or store mss product near
<br />a heat source, open flame or other sources of IgnNon,
<br />pasicularN 'rf storage rompereW res are near the flash
<br />point (117'F, 47.2'C). Noxias fumes maY De formed
<br />under fse contlttbns.
<br />8. EXPOSURE CONTROLS/PERSONAL PROTEC-
<br />710N:
<br />These precautions are suggested for contlitlons where
<br />me pdentlal for exposure exists. Emergency condF
<br />bons may require adtldanai Precautions.
<br />EXPOSURE GUIDELINES:
<br />Isopropyl alcohol: ACGIH TLV and OSHA PEL are
<br />4D0 ppm TWA 500 ppm STEL.
<br />PELs are in accord whh mose recommended by OSHA,
<br />as in the 1989 revision of PELs.
<br />PoN9Ncol 26-2: Dow AgroSciences IMUStrial Hygiene
<br />Guideline is 2 mg/Ma.
<br />CtopyrelW: Dow AgroSciences lntlustsa! Hygiene
<br />Guideline is 10 mglM .
<br />ENGINEERING CONTROLS: Provide general and/or
<br />local exhaust ventilation to rgnhPl airborne levels be-
<br />low the exposure guidelines. Use Doty with adequate
<br />ventdatbn.
<br />RECOMMENDATIONS FOR MANUFACTURING,
<br />COMMERCIAL BLENDING, AND PACKAGING
<br />WORKERS:
<br />RESPIRATORY PROTECTION: Atmospherb levels
<br />should be maintained below me exposure guidelines.
<br />Jyhen inspiratory protection M required use a NIOBH
<br />5pprovetl air-puritying or pos'Itive-pressure supplied-air
<br />~espvatw depentling on the pofentiai airborne concen-
<br />radon. For emergency and other condttbns where
<br />Database and format copyright ©by C&P Press. Att rights reserved.
<br />me exposure guideikte may be greatN exceetled, use
<br />a NIOSH approved posttive-pressure se8-contained
<br />breathing a0paratus or posttive-pressure aisine with
<br />auxi0ary se8-contained air supply. In confined w poorly
<br />venLlated areas, use a NIOSH approved Ix9sifive-
<br />pressure supplied-ak respirator,
<br />SKIN PROTECTION: Use gbves impervbus ro this
<br />material when prolonged w trequentN repeated can-
<br />tata mould occur.
<br />EVE PROTECTION: Use safety glasses. H vapor ex-
<br />posurecauses eye dscomfwt, use a NIOSH approved
<br />fu0-face respirator.
<br />APPLICATORS AND ALL OTHER HANDLERS: Re-
<br />fer to the product libel for personal protective clothing
<br />antl equipment,
<br />9. PHYSICAL AND CHEMICAL PROPERTIES:
<br />BOILING POINT: 212'F (f00'C)
<br />VAPOR PRESSURE: 23.5 mmHg Q 20'C
<br />VAPOR DENSfTY; 7.06 @ 20'C
<br />SOLUBILITY 1N WATER: Mkcible
<br />SPECIFIC GRAVT': 1.761 Q 68-F, 20-C
<br />APPEARANCE: Reddish-Drwm liquid
<br />ODOR: Sweet
<br />pH: 7.5-8.0
<br />f0. STABILf7Y AND REACTIVITY:
<br />STABILITY: (CONDRIONS TO AVOID) Store under
<br />cool, dry ngrMitbns. Avdd elevated temperatures and
<br />direct wnlighL Cwnbustible. Do not use w store near
<br />heat, open flame, or other sources d ignitlon, espy
<br />ciady M temperaWres are near or at fbe flash pant
<br />INCOMPATIBILT': (SPEGFIC MATERIALS TO
<br />AVOID) Avoid ado oxidking material, halogenated
<br />organks, Dress, copper, zinc, eM aluminum.
<br />HAZARDOUS DECOMPOSITION PRODUCTS: Hy-
<br />drogen chbride, nitrogen oxbes under fire wnd'Itbns,
<br />chlorinatetl pystline.
<br />HAZARDOUS POLYMERIZATION: Not known to oc-
<br />cur.
<br />1:1. TOXICOLOGICAL INFORMATION:
<br />MUTAGENICITY: far the componens tested, in-vitro
<br />and animal muWgenbiN stWles were negaWe.
<br />1T. ECOLOGICAL INFORMATK7N:
<br />ENVIRONMENTAL FATE:
<br />MOVEMENT 8 PARTRIONING: Based largeN w
<br />completely on informaton for dopyreGd. Blxoncely
<br />tration potential is low (BCF <700 w Log Pow <3).
<br />Pdemial for mohiliry In soil is very high (I(oc between
<br />0 and 50).
<br />DEGRADATION 8 PERSISTENCE: Basetl brgely or
<br />completey on irdortnation for cbpyrslW. Biotlegretla-
<br />tron under aerobic laboratory condlfigns fs below de-
<br />tectable limits. Tne photolysis half-life In water H 261
<br />tlays. The photolysis hah-life in soil is >12 years. Un•
<br />tler aerobic soli mrbitbns me hah-189 Ls 77 days.
<br />ECOTOXICOLOGY: Based IargeN or completey
<br />on information for copyread. Material is practically
<br />sort-toxic to aqua8c organisms on an act8e bases
<br />(LCsplECsp > 100 rrlg/L in most sensitive species.
<br />73. DISPOSAL CONSIDERATIONS:
<br />DISPOSAL METHOD: Do not contaminate food, feed,
<br />or water by storage or disposal. Wastes are toxic.
<br />Improper disposal w excess waste, spray mixWre, or
<br />snsate fs a violation of federal Ww. d wastes resuking
<br />from the use of IhIS product cannot be disposed w
<br />according to mbel insWdions, dispose of mere wastes
<br />at an approved facility. Conrad your state pesticide w
<br />environmental gxtbd agency, w me hazardous waste
<br />representable at the nearest EPA regional office for
<br />guidance.
<br />14. TRANSPORT INFORMATION:
<br />U.S. DEPARTMENT OF TRANSPORTATION INFOR-
<br />MATION:
<br />FOR ALL PACKAGE SIZES:
<br />BY LAND: Not regulated for Irensposafxm.
<br />BY AIR OR VESSEL: FLAMMABLE LIQUIDS, N.O.B.
<br />(CONTAINS ISOPROPANOL)13NN1993/PGIII
<br />Powered by CSP Press.
<br />
<br />
|