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MATERIAL SAFETY DATA SHEET
<br />ORDON* 22K
<br />ERBICIDE
<br />' mergenuy Phone: 80D-992-5994
<br />_ ow AgroBdences LLC
<br />Indianapolis, IN 46268
<br />Effective Date: 5.29-02
<br />Product Code: 87116
<br />MSDS: 000380
<br />1. PRODUCT AND COMPANY IDENTIFICATION:
<br />PRODUCT: Tordon' 22K Herbicide
<br />COMPANY IDENTIFICATION:
<br />Dow AgroSCiencas
<br />9330 Zbnsville Road
<br />Indianapolis. IN 46266-1169
<br />2. COMPOSRIOWINFORMATION ON INGREDt
<br />ENTS:
<br />Pidoram: I-Amhw-3,5,8- CAS a pOT5dSe0-0 20.1%
<br />MMbmPxvink AqE.
<br />PMaWUm fe0.
<br />Inert MyrsCienb. TOdl, InrLein9: r5A%
<br />PoHgarnl CAS M W90T43&e
<br />This document's prepared pursuant b the OSHA Fiaa
<br />and Communkaaon Standard (29 CFR 1910.1200). In
<br />eddiaon, other substances not 11azaNous' per this
<br />OSHA Standard may be listed. Where proprietary'vl-
<br />gredientshows, Me itlentiy may be made ovapable as
<br />provkled in t/lls standard.
<br />3. HAZARDOUS IDENTIFICATIONS;
<br />EMERGENCY OVERVIEW
<br />H3zardOUS chemical. Dark brown liquid. May cause
<br />severe eye inflation. LDsa fro skin absorption in rab-
<br />bits a >5000 mg/kg. Orel LDso for skin absorp0on
<br />in rabbits is >5000 mg/kg. InhaFa60n LCso for refs
<br />for 4 hours is >8.71 mglL Material K Blighty toxic to
<br />aquaac organ5ms and preclicaly non-toxic to birds.
<br />EMERGENCY PHONE NUMBER: 800-992-5994
<br />POTENTIAL HEALTH EFFECTS: This section ir~
<br />udes Posslbte adverse effects, which couU occur H
<br />Is material is not hantlled In Me rewmmended man-
<br />or.
<br />YE: May rouse severe eye irritation. Corneal injury
<br />~- is unlikely. EOects likey to heal reatliy.
<br />SKIN: Probnged orrepeafed exposure may cause skin
<br />irrtaton, even a bum. Prolongetl skin contact is un-
<br />likely to result m absorptbn of harmful artrounts. Tne
<br />LDso for skin absorption N rabbits k >5D00 rtxykg.
<br />Has caused allergic skin reactions when tested in
<br />guinea Pigs. Did trot cause allergic skin reactions when
<br />tasted in humans.
<br />INGESTION; Very krw toxicity I( swallowed. The oral
<br />LDso for male end female rats ta >5000 mg/kg. Snap
<br />amounts swallowed incitlental to normal handling op-
<br />emtrons are not Ipcey to cause injury; however, swaF
<br />lowing grger amounts may cause injury.
<br />INHALATION: No aWerse effects are anticipated tram
<br />single exposure tb vapor. The LCso for refs for 4 hours
<br />is >e.tt mglL.
<br />SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: In
<br />animals, effects have been reported on the fdknving
<br />organ: liver.
<br />CANCER INFORMATION: Did not cause cancer In
<br />laboratory animals.
<br />TERATOLOGY (BIRTH DEFECTS): 8ir}h defects are
<br />unlikey, Even exposures having an adverse effect on
<br />Me mother shoutl have no eaect on Me feNS.
<br />REPRODUCTIVE EFFECTS: PiUoram acid did not in•
<br />terfere with reproduction in laboratory animal'stutlies.
<br />4. FIRST AID:
<br />EVES: Hokl eyes open and rinse sbwty and genty
<br />with water for 1 S20 minutes, Remove contaU lenses,
<br />H present, after the first 5 minutes, then continue rins-
<br />ing eyes. CaN a poison control center or doctor rot
<br />treatment advice.
<br />SKIN: Take o0 wntaminated cloMin9. Rinse skin im
<br />metliately wiM plenty of water for 1520 minmes. Call
<br />a poison control center or doctor for heatment atlvice.
<br />GESTION: CaN a Poison control center pr tloctor
<br />mmediatey (or treatment advice. Have person sip
<br />e glass of water H able to swallow. Do not induce
<br />miting unless told to do so by the poison control
<br />earner or tloctor. Never give anything by mouth to en
<br />unwnscious person.
<br />UPDATES AVAILABLE AT Y/WW,GREENBOOK.NET
<br />INHALATION: Move person to hash air, i( efecs or
<br />cur, consult a physician.
<br />NOTE TO PHYSICIAN: If bum is present treat a
<br />any Merrtal bum,-after decontamination. No spedFu
<br />antidote. 7reatrnent of exposure should be daected a
<br />the control of symptoms and Me clinical condition a
<br />Me patlent
<br />5. FIRE FIGHTING MEASURES:
<br />FLASH POINT: None observed up to 214'F
<br />METHOD USED: TCC
<br />FLAMMABLE LIMBS
<br />LFL' Not tletertnined
<br />UFL: Not detertninetl
<br />EXTINGUISHING MEDIA: Alcohol foam, COr, tlr)
<br />chemical.
<br />FIRE 8 EXPLOSION HAZARDS: Noauto-igniaon lam
<br />pereture when tested to 1022'F (550'Cj. Toxic, irtitaf
<br />trig vapors may be produced H produU is invotvetl In
<br />fire.
<br />FIRE-FIGHTING EDUIPMENT: Wear poskive-
<br />pressure, seH-contented breathng apparetus and
<br />full protective clothing. Do not allow water From
<br />fire-fighting to enter water supplies.
<br />fi. ACCIDENTAL RELEASE MEASURES:
<br />ACTION TO TAKE FOR SPILLSILFAKS: Absorb
<br />smap spies In antl inert material, such as dry sand.
<br />In case of large spills, tlike area to contain produU
<br />end repon b Dow AgroSc(ences at 800.992-5994.
<br />7. HANDLING AND STORAGE:
<br />PRECAUTIONS TO BETAKEN IN HANDLING AND
<br />STORAGE: Keep out of reaUt of children. Causes
<br />suhstantial but temporary eye injury. Harmful H Inhaled
<br />or ahsorbed Mrough skin. Oo not get (n eyes or on
<br />clohing. Avoid breathing spray mist Avakl skin con-
<br />tact Users shoultl wash hands before eatlng, drinking,
<br />mewing gum, using tobacco, a using are toner. Store
<br />in Me original wntainer wIM tbe lid tightly closed.
<br />8. EXPOSURE,CONTROLSIPERSONAL PROTEC-
<br />TION:
<br />These precautions are suggested for conditions where
<br />Ole potential for exposure exists. Emergency condF
<br />eons may require addHional precaNions.
<br />EXPOSURE GUIDELINE(S): Picloram: ACGIH TLV
<br />is 10 mg/Ms, A4, OSHA PEL is 5 mgMts respirable.
<br />PELS are in accord wIM Mose rewmmended by OSHA,
<br />as M Me 1989 revisbn of PELS.
<br />Polygtycol: Dow AgroSciences Intluslrial Hygiene
<br />Guide is 2 mgrMa.
<br />ENGINEERING CONTROLS: Provide generel anNor
<br />bcal exhaust ventilation to control airborne levels be-
<br />low the exposure guidelines.
<br />RECOMMENDATIONS FOR MANUFACTURING,
<br />COMMERCIAL BLENDING, AND PACKAGING
<br />WORKERS:
<br />RESPIRATORY PROTECTION: Atrnospherk levels
<br />should he maintained below Me exposure guidelines.
<br />When respiratory proteUion is required fa certain op•
<br />eretions, use a NIOSH approvetl air-puriyklg respir~-
<br />kN.
<br />SKIN PROTECTION: When prolonged or frequency
<br />'epeatetl contaU mould occur, use chemicapy proteu
<br />live cbNing resistant to Mis material. Selectbn of ~il~~
<br />;fic items such as faceshielQ gbves, hoots, apron, or
<br />'ulFbody suH will depend on operetron.
<br />.YE PROTECTION: Use chemical goggles.
<br />4PPLICATORS AND ALL OTHER HANDLERS: Re-
<br />ar to the Woduc! label for personal protective cbMing
<br />rod equipment.
<br />1. PHYSICAL AND CHEMICAL PROPERTIES:
<br />301LING POINT: 212'F (700'C)
<br />/APOR PRESSURE: Approximatey 23 mmHg (+d,
<br />!0'C
<br />/APOR DENSIT': Not applicable
<br />tOLU81LITY IN WATER: Miscble
<br />iPECIFIC GRAVITY: 1.760 (68/e6'F, 20'C)
<br />rPPEARANCE: Dark brown liquid
<br />IDOR: Not available
<br />10, STAetLITY AND REACTMTY:
<br />STA8ILRY: (CONDRK)NS TO AVOID) Stable urMer
<br />normal storage wndifions.
<br />INCOMPATIBILITI': (SPECIFIC MATERIALS TO
<br />pYOID) None under normal use cond8ions. Under
<br />abrromtal wnditions evoW ozitlizing materials and
<br />' strong aUds. ConSUM manuhacnuer for specific roses.
<br />HAZARDOUS DECOMPOSRION PRODUCTS: Hy-
<br />drogen chloride and nitrogen oxides may be produced
<br />H product N Involved in fire.
<br />HAZARDOUS POLYMERIZATION: Not known to 0o-
<br />cur.
<br />11. TOXICOLOGtCA1 INFORMATION;
<br />MUTAGENICfTY; The prepontlerance of data shows
<br />p'ICldmm to be non-mutagenic in 'in vitro' (test tube)
<br />tests and in animal test systems.
<br />Database and format copyright ©by C&P Press. All rights reserved.
<br />12. ECOLOGICAL INFORMATION:
<br />ENVIRONMENTAL FATE
<br />MOVEMENT 8 PARTRIONING: Based largety or
<br />wmpletefy on information for DiUOram. Bioconcentre-
<br />aon potental is ktw (BCF <100 w Log Pow <3).
<br />DEGRADATION 8 PERSISTENCE: Basetl largely or
<br />wmpletery on inforrnatlon for plCkuam. Biodegradation
<br />under aerobic laboratory cond'ears is bak>w detectable
<br />emits (<2.5%j.
<br />ECOTOXICOLOGY: Material b slightty toxicto aquatic
<br />organisms on an acute basis (LCso/ECso behveen 10
<br />and 100 mg4_ in most seralave species).
<br />Acute LCso for rainbow troN (Oncomynchus mykiss)
<br />is 26 mgrL.
<br />Acute LCso for zebra fish (Brechydanio ratio) B 35.5
<br />mgt.
<br />Acute LDSa for sheep5head minrrow (Cypnrrodon var-
<br />iegaNs) is > 131 mg/L.
<br />Acute ECso for shetl deposition inhibition in eastern
<br />oyster (Cressostrea v(rginica) is 1&32 mglL
<br />Acute LCso for pink shrimp (Penaeus duoramm) is 125
<br />mg/L
<br />Materal Is practically non-toxic to birtls on a dietary
<br />basis (LCso >5000 ppm)
<br />Growth inhibi0on ECso in tluckweetl (Lemrs sp.) is
<br />196.2 mg/L
<br />Growm Inhibilbn ECso for marine diafom (Skef~
<br />fanema cosfatum) k 14mgIL.
<br />Growth InhbHion ECso for blue-gmen alga (Anabaena
<br />aosaquae) is 590 mglL
<br />Grovrth inhibition ECso for d'atam (Navieula sp.) k 3.9
<br />mg4.
<br />13. DISPOSAL CONSIDERATKNJS:
<br />DISPOSAL METHOD: Do not contaminate food, feed,
<br />or water by storage pr disposal. Wastes ere toxic.
<br />Improper disposal or excess waste, spray mUlure, or
<br />rinsate is a vida0on Of federel law. If wastes resuking
<br />horn Me use of this poduU cannot be disposed of
<br />according to label instructiore, dispose of Mese wastes
<br />at an approved faUliry. ContaU your state pesticide or
<br />environmental control agency, or the hazardous waste
<br />representative at the nearest EPA regional office for
<br />guidance.
<br />14. TRANSPORT INFORMATION:
<br />US. DOT
<br />ih's Material is not regulated far Transportation.
<br />15. REGULATORY INFORMATION:
<br />NOTICE; The information herein is presented in good
<br />~Hh and believed b be accurate as of the effective
<br />late shown above. However, rro warranty, express or
<br />mpl'letl, is given. Regulatory requirements are subject
<br />o change and may tliffer from one bcation to anoMer;
<br />t K the buyeYS responsibpily to ensure that hs activF
<br />ies comply wtth fedeml, state or provincial, and hxal
<br />aws. The following specific infortna0on is made for
<br />he purpose of comptying wAh numerous federal, state
<br />x provincial, and beat laws ant regulations.
<br />REGULATIONS
<br />iARA 313 INFORMATION: To the hest of our knovA-
<br />sdge, this protluct wntains no chemical subject to
<br />iARA Tale III Section 313 supplier notification require-
<br />nens.
<br />iARA HAZARD CATEGORY: This product has been
<br />eviewetl accoming ta the EPA "Hazard Categories"
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