|
MATERIAL SAFETY DATA SHEET
<br />RSENAL®
<br />ERBICIDE
<br />roduct No :579605
<br />Arsenal® hebicide
<br />Date Prepared: 6/13/2000
<br />Date Revised: tYL1l2004
<br />BASF Corporetion
<br />Agricultural Poducts Group
<br />P.O. Box 13528,
<br />Reseimh 7dangle Park, NC 27709
<br />(819) 547-2000
<br />EMERGENCY TELEPHONE NUMBERS:
<br />BASF Corporation: 1 (809) 832-HELP
<br />CHFJA7REC: 1 (80D) 424-9300
<br />SECTION 1
<br />Trade Name: Arsena herbicitle
<br />Chemical Name: 2-[4,5-0ihytlro-4-memyF4jl-ma-
<br />Mylethyl)-5-oxo-l H-imidazoL2•y~-3•pydtlinecarhoxylic
<br />ack1, salt with 2-propanamine (1:1)
<br />Synonyms: Isapropytamine of inrszapyr, AC252, 025;
<br />Arsenal NS Herbicide
<br />Formula: C(13)H(15)N(3K1(3).C(3)H(8)N
<br />Chemical Fatuity: Imidazolinone
<br />Mol Wt: 320.4
<br />SECTION II -INGREDIENTS
<br />PEVfLV.
<br />fAMPONENr CAS NO. X SOURCE
<br />nopmpylamhe 81510-03-0 28.1 a.5 mphn3
<br />rBY Of lmvaPYr TWA 845E
<br />remmm.,wetl
<br />Imm WA 11.3 Nona rnabtir5atl
<br />SARA TWe 111 Section 313: Not listed
<br />SECTION III -PHYSICAL DATA
<br />~OILING/MELTING POINT ~ 760mm Ng: NIO
<br />H: 6.6 - 7.2
<br />rAPOR PRESSURE mmHg (aJ 20'C: N/D
<br />~.~` ~PECIFIC GRAVITY OR BULK DENSITY: 1.04 - 1.07
<br />ghpL
<br />SOLUBILRY IN WATER: Soluble
<br />APPEARANCE: Clear bWe fpuid
<br />ODOR: Amnania
<br />INTENSmr: slgm
<br />SECTION N -FIRE AND EXPLOSION DATA
<br />FLASH POINT (TEST METHOD): >210'F SFCC
<br />AUTOIGNRION TEMP: > 200'F
<br />FLAMMABILITY LIMITS IN AIR (% BY VOL):
<br />LOWER: N/D
<br />UPPER: N/D
<br />NFPA 704 HAZARD CODES
<br />HEALTH: 1
<br />FLAMMABLE:1
<br />INBTABUIrr: D
<br />OTHER: N/R
<br />NFPA 30 STORAGE CLASSIFICATION: Class IIIB
<br />EXTINGUISHING MEDIUM: Use water fog, foam,
<br />CO(2), or dry chemical extinguishing media.
<br />SPECIAL FIREFIGHTING PROCEDURES: Firefght-
<br />ers shoultl be equipped with sets-contained breathing
<br />apparatus and turnout gear.
<br />UNUSUAL FIRE EXPLOSION HAZARDS: None
<br />krwwn.
<br />SELECT ACRONYM KEY
<br />N/A -Not available; N1D -Not determined; N1R -Not
<br />rated; N/E -Not established
<br />SECTION V -HEALTH DATA
<br />TOXICOLOGICAL TEST DATA:
<br />Data for formulated product:
<br />Rat, Oral LD50 (wmbined sexes) > 5000 mgrkg
<br />Rabbn, Dermal LD50 (combined sexes) > 2000 mgbcg
<br />at, Inhalation LC50 (4 hr) > 4.62 m9/L
<br />Rat, Inhala9on LC50 (1 hr calculated) > 10.48 mg/L
<br />"4~tabbiL Eye Irdtatbn -Not In0a0ng
<br />`J~ Rabbit, Skin Imitation -Mildly irr0anng
<br />Guinea pig, Dermal Senstt¢er -Not Sensitaer
<br />UPDATES AVAILABLE AT W4VW.GREENBOOK.NET t
<br />OSHA, NTP, or WRC Carcinogen: Not NSted.
<br />EFFECTS OF OVEREXPOSURE:
<br />See ProduW Label and Dlrecypns For Use for ad
<br />tlitional precautionary statements.
<br />CAUTION
<br />Avoid contact with skin, eyes, and cbthing. Avok
<br />breaMing spray mist
<br />Existing medical condi0ons aggravated by this product
<br />None known.
<br />FIRST AID PROCEDURES
<br />If on skin: Wash w8h plenty of soap and water. Gel
<br />medical anention 0 iriation persists.
<br />K in eyes: Flush eyes cairn plenty of water. Call a
<br />physldan if irritation persists.
<br />If inhaled: Remove victim to freshair. If not breathing,
<br />give arOflGal respkation, prefereby moulMto-mouth.
<br />Get medical aaeMron.
<br />If swallowed: Coe a physician or Poispn Conbol Cen-
<br />ter. Drink 1 w 2 glasses of water and induce vomiting
<br />by touching back of throat with finger. If person H un-
<br />wnscbus, do not give anything by mouth and tlo not
<br />induce vomting.
<br />Note to physician: Treat sympbmaticaly. Nospecific
<br />antidote.
<br />Note: Have the product wnWicer or label with you
<br />when tailing a poison comrol center w doctor or going
<br />iw Vestment
<br />SECTION VI - REACTIWTY DATA
<br />STABILfTY: Stable. Do not stare below 32'F Or above
<br />100'F.
<br />CONDITIONS TO AVOID: Store in origmal container
<br />In cool, dry, well vemllated pWce away from ignltbn
<br />sources, heat or flame.
<br />CHEMICAL INCOMPATIBILITY:OzW¢ing agents and
<br />reducing agents.
<br />HAZARDOUS DECOMPOSITION PRODUCTS: In-
<br />cluding but not IMited b oxides of carbon and nitrogen.
<br />HAZARDOUS POLYMERIZATION: Does not occur.
<br />CONDITIONS TO AVOID: Does not poymerae.
<br />CORROSNE TO METAL: MOd steel, brass
<br />O%IDIZER: No
<br />SECTION VII -PERSONAL PROTECTION
<br />Users Q a pesticidal end use r uCt should
<br />refer Ito [he rodu tabet (or ep rsanef orotecthre
<br />eppipmeni repUlremenl3.
<br />RECOMMENDATIONS FOR MANUFACTURING.
<br />COMMERCIAL BLENDING. A~1D PACKAGING
<br />w~RKeRS:
<br />aspiratory Protection: Supplied air respvafors
<br />shoWd be worn if large quantifies of m¢Vtlust are gen-
<br />erated w probn9etl exPoswe possible.
<br />Eye Protection: Chemical goggles when respirator
<br />does rwt provide eye protectipn.
<br />Protective Clothing: Gloves and protective cbthing
<br />as necessary to prevent skin camacl
<br />Yennlation: Whenever possibte, engineering controls
<br />should be used to minimze the need fw personal pro-
<br />tective equipment.
<br />SECTION VIII -ENVIRONMENTAL DATA
<br />ENVIRONMENTAL TOXICITY DATA
<br />See the product label for information regarding envF
<br />ronmental toxicity.
<br />SARA 311!312 REPORTING
<br />FIRE: N
<br />PRESSURE: N
<br />REACTIVITY: N
<br />ACUTE: Y
<br />CHRONIC: N
<br />TPQ(Ibs): N/R
<br />SPILL AND LEAK PROCEDURES:
<br />In case of large scale spillage of this product, avoid
<br />contact, isolate area antl keep out animals and unpro-
<br />tatted persons. Ca0 CHEMTREC (800 424-9300) or
<br />BASF Corporation (900 832-HELP). For a smaA spill,
<br />wear personal protective equipment as specified on
<br />the label.
<br />FOR A LIQUID SPILL: Dike and contain the spill wtth
<br />inert material (san4 earth, etc.} and trensfer the liquid
<br />and solid diking materials [o separete containers for
<br />tlsposal.
<br />FOR A SOLID SPILL: Sweep solid into a drum for re-
<br />use or disDOSaI. Remove personal protective equip-
<br />ment and decontaminate n prgr to re-use.
<br />HAZARDOUS SUBSTANCE SUPERFUND: No
<br />RO(Ibs): None
<br />WASTE DISPOSAL METHOD:
<br />Pesticide wastes are acutey hazardous. Wastes re-
<br />sultirg from this product may be disposed of on site
<br />w at an approved waste dsposal faciliy. Improper
<br />disposal of excess pesOcide, spray mix or finsate rs
<br />a violation of federal law. If these wastes cannot be
<br />disposed of accOrd'urg tp label instructions, contact the
<br />stare agency responsible Tor pesticltle regulationwthe
<br />Hazardous Waste represemative at me nearest EPA
<br />Regional Office For gukfance.
<br />HAZARDOUS WASTE 40CFR281: No
<br />HAZARDOUS WASTE NUMBER: None
<br />CONTAINER DISPOSAL:
<br />FOR PLASTIC CONTAINERS: Triple rinse (or equiva-
<br />lent) aM atld dnsate to the spray tank. Then orter for
<br />recycling w rewndifioning, w puncture and dispose of
<br />In a sanitary landfill, or by Inckremtion, or i(ellovred 6y
<br />state and local authorities, b)' burning. If burned, stay
<br />out of smoke.
<br />FOR BULK CONTAINERS: Reusable wntainers
<br />shouts be returned to the /pint of purchase for
<br />ckantng and refiMng.
<br />FOR MINIBULK CONTAINERS: Clean all tanks on an
<br />approved loading pad so dnsate can be collected and
<br />maed Into the spray solution or into a dedicated tank.
<br />Using a high Dressure sprayer, dose several limes with
<br />small volumes of water to minimize dnsate.
<br />SECTION IX -SHIPPING DATA- PACKAGE AND
<br />BULK
<br />D.O.T. PROPER SHIPPING NAME (49CFR172.101-
<br />102): None
<br />HAZARDOUS SUBSTANCE (49CFR CERCLA LIST):
<br />None
<br />RQ(Ibs): None
<br />D.O.T. HAZARD CLASSIFICATION (CFR 172.101-
<br />102):
<br />PRIMARY
<br />None
<br />SECONDARY
<br />None
<br />D.O.T. LABELS REQUIRED (49CFR1 7 2101-1 0 2):
<br />D.O T. PLACARDS REQUIRED (CFR172.504): None
<br />POISON CON3TRUENT (49CFR172.203(K)): None
<br />BILL OF LADING DESCRIPTION
<br />Compounds. tree w weed ki0ing, NOIBN
<br />This produce is not reguWted by the Depadment of
<br />Transportation (DOT). It does not meat [he defini0on
<br />of DOT Corrosive (49 CFR 173.136).
<br />CC NO.: Nw applicable
<br />UWNA CODE:
<br />SECTION X -ADDITIONAL INFORMATION
<br />Arsenate herbicide
<br />EPA Reg. No. 241-346
<br />KEEP OUT OF REACH OF CHIL-
<br />DREN
<br />CAUTION
<br />BASF Corporation
<br />Agricultural Products Group
<br />P.O. Box 13528,
<br />Research Tdangle Park; NC 27709
<br />(919) 547-2000
<br />DISCLAIMER
<br />IMPORTANT: WHILE THE DESCRIP710NS, DE-
<br />SIGNS, DATA AND INFORMATION CONTAINED
<br />HEREIN ARE PRESENTED IN GOOD FAITH AND
<br />BELIEVED TO BE ACCURATE, R IS PROVIDED
<br />FOR YOUR GUIDANCE ONLY. BECAUSE MANY
<br />FACTORS MAY AFFECT PROCESSING OR AP-~
<br />PLICATIONIUSE, WE RECOMMEND THAT VOU
<br />MAKE TESTS 70 DETERMINE THE SURABIL-
<br />ITY OF A PRODUCT FOR YOUR PARTICULAR
<br />PURPOSE PRIOR TO USE. NO WARRANTIES OF
<br />4NY KIND, ERHER FJCPRESS OR IMPLIED, IN-
<br />CLUDING WARRANTIES OF MERCHANTABILITY
<br />DR FITNESS FOR A PARTICULAR PURPOSE, ARE
<br />MADE REGARDING PRODUCTS DESCRIBED OR
<br />DESIGNS, DATA OR INFORMATION SET FORTH,
<br />DR THAT THE PRODUCTS, DESIGNS, DATA OR
<br />Database and format copyright ~i by Vance Communication Corporation. All rights reserved.
<br />a
<br />
|