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MATERIAL SAFETY DATA SHEET
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET
<br />EDEEM* R8LP
<br />ERBtCiDE
<br />-. nergency Phone: 800-992-5994
<br />ow AgroSCiances LLC
<br />Indianapolis, IN 46268
<br />Effective Date: 3/12/01
<br />Produet Cade: 78163
<br />MSDS: 003599
<br />1. PRODUCT AND COMPANY IDENTIFICATION:
<br />PRODUCT: Redeem' R&P Herbicide
<br />COMPANY IDENTIFICATION:
<br />Dow AgroSCiences
<br />9330 Zionsville Road
<br />Indianapolis, IN 46268-7189
<br />2. COMPOSRION/INFORMATION ON INGREDI~
<br />ENTS:
<br />TnGopyr CAS# 33.0%
<br />((3,5,fi-Wddoro-2- 05]213-fig-1
<br />pyddinNWaYlaceBC eddy,
<br />as the 1daNylamine calf
<br />Clbpyrelk (3,6Eidtloro-2- LASp 12,1%
<br />pydtlinerarboxylic add), 057754.85.5
<br />ac me trieNylamine salt
<br />Inert irgredienrs, Inlal, CAS# 54,9X
<br />indutlin9: 000121-044
<br />N,N-DietnyleManemine
<br />EDTA (Ethylenediamine
<br />TeOaa~eOC CAS#
<br />Add)(Ethanol) 000060-004
<br />This document is preparetl pursuant to the OSHA Haz-
<br />ard Communicatbn Siantlard (29 CFR 1910.1200). In
<br />atltli8on, other substances not 'Hazardous' per this
<br />DSHA Standard may be listed. Where proprietary in-
<br />gredient shows, the itleMiy may be made available as
<br />provided in this standard.
<br />3. NAZARDOUS IDENTIFICATIONS:
<br />MERGENCY OVERVIEW
<br />azardous chemical. Clear amber liquid, sight amine
<br />r. May cause severe eye initatbn arW/or moderate
<br />meal injury. The LDso for skin absorptlon in rabbits
<br />>2000 mglkg. The orel LDso for refs is 2164 mg4;g
<br />~-'- male) and 1521 (female). Material is sfigMy toxic b
<br />aquatic organisms.
<br />EMERGENCY PHONE NUMBER: 800-992-5994
<br />POTENTIAL HEALTH EFFECTS: This sectbn in-
<br />cludes possible adverse effects, which wukf occur H
<br />this material is not handled b the rewmmended man-
<br />ner
<br />EYE: May cause severe eye irritation wtth moderate
<br />corneal Injury. Effects may be sbw to heal. Vapors
<br />of amines may cause swelling of the cornea resulting
<br />in visual disturbances such as blurred, smoky or halo
<br />vision.
<br />SKIN: Prolonged exposure is not I&ey to rouse signH-
<br />icent skin irdtaton. Proonged or frequenity repeated
<br />skin contact may cause allergic skin reactions b some
<br />individuals. A single prolonged exposure is not likely
<br />to result in the material being absorbed through skin
<br />in harmful amounts. The LDso for skin absorpton In
<br />rebbtts is >2000 mg/kg. May cause allergic skin re-
<br />action in susceptible individuals. Wah the dilute mu,
<br />no allergic skin reaction is expected.
<br />INGESTION: Single dose oral tozbiry is bro. The orel
<br />LDso for male rats a 2764 mg/kg and females a 1521
<br />mg4cg. Small amounts swalbwed incidental to nor-
<br />mal hantlling operations are not Ikey b cause injury;
<br />swalbwing larger amounts may rauseinjury. Ingestion
<br />may cause gastro'intesdnal imita0on or uberation.
<br />INHALATION: Single exposure to vapors is no[ likely
<br />to be hazardous. LCsp for rats B >1.06 mg0. for 4
<br />hours.
<br />SYSTEMIC (OTHER TARGET ORGAN)EFFECTS: In
<br />animals, effects have been reported on the folowing
<br />organs: heart, kidney, antl liver.
<br />CANCER INFORMATION: Triclopyr and ciopyralid did
<br />not cause cancer in laboratory animals. This material
<br />wntains ethanol. Epidemiology studies provitle evi-
<br />ence That tlnnking of alcoholic beverages (containing
<br />ihanoq is associated with cancer, and IARC has clas-
<br />-= ifietl alcoholic bevereges as caroinogenic to humans.
<br />'gy'p'".'<' RATOLOGY (BIRTH DEFECTS): Tdclopyr tlid not ~I
<br />use biM defects in laboatory animals. ClopYralid
<br />caused birth defects in test animals, but ony at greatly
<br />exaggerated doses that were severely toxic to the
<br />mothers. No birth defects were observed In animals
<br />given cbpyralid at doses several Hmes greater Than
<br />those expected during normal exposure.
<br />REPROOUCTNE EFFECTS: For iricbpyr antl cbpy-
<br />relid, in laboratory animal studies, effects on repro-
<br />tlumbn have been seen ony al doses that produced
<br />significant toxicity b the parent
<br />4. FIRST AID:
<br />EYES: Irrigate wtth flowing water immediatey and cen-
<br />gnuousy for 15 minutes. Gonsutt medical personnel.
<br />SKIN: Wash off in flowing water or shower.
<br />INGESTION: Do not Induce vomlertg. Give large
<br />amounts of water or milk H available ant transport
<br />to medical facility. Do not give anything by mouth to
<br />an unconscious person.
<br />INHALATION: Remove to fresh air H effects occur.
<br />Consult a physician.
<br />NOTE TO PHYSICIAN: May cause tissue destruct(on
<br />leading b strbture. If lavage is pedonned, endotra-
<br />cheal and/or esophageal control is suggested. Ex-
<br />posure to amine vapors may cause minor transient
<br />edema of the corneal epBheGUm (glaucopsia) cairn
<br />blurted vision, blue haze and halos around bright ob-
<br />jects. Effects disappear in a few hours and lemporerly
<br />reduce abilHy to drive vehicle. No specific anOdote.
<br />Supporfive care. Treatment based on judgment of Me
<br />physician in response to reactions M [he pafient
<br />5. FIRE FIGHTING MEASURES:
<br />FLASH POINT: 150'F (66'C)
<br />METHOD USED: FCC
<br />FLAMMABLE LIMBS
<br />LFL: Not determined
<br />UFL Not determined
<br />EXTINGUISHING MEDfA: Foam, COr
<br />FIRE AND EXPLOSION HAZARDS: IrrkaOng vapors
<br />under ine contlitions. Malerale a water solution and
<br />except under gross fire conditions should not bum.
<br />Avdd contaminatlng water supplies with mn-oH water.
<br />FIRE-FIGHTING EQUIPMENT: Under fire conditlons
<br />use positlve-pressure, seH-contained breaming appa-
<br />ratus and fu0 protective clothing.
<br />6. ACCIDENTAL RELEASE MEASURES:
<br />ACTION TO TAKE FOR SPILLS: AhSOrD small spills
<br />wHh inert materials such as ZoroaU, Hazorb or sent.'
<br />Report large spills to Dow AgroSciences i-800-992-
<br />5999.
<br />7. HANDLING AND STORAGE:
<br />PRECAUTIONS TO BE TAKEN IN HANDLING AND
<br />STORAGE: Keep out o/ reach of chOdren. Narm/W H
<br />swalbwed, inhaled, or absor6etl through skin. Causes
<br />eye irritation. May rouse allergic skin reactors in some
<br />intlivbuals. Avoid contactwim eyes, skin, antl cbming.
<br />Sbre in original container with the lid fighty cbsed.
<br />& EXPOSURE CONTROLS/PERSONAL PROTEC-
<br />These precautions are suggestetl for conditions where
<br />the potential for exposure ezisis. Errrergency condo
<br />Lions may requce addhbnal precautbns. -
<br />EXPOSURE GUIDELINES:
<br />3,5,6Trichbro-2-pyntlyloxyaceec acid (Trbbpyr), Vi-
<br />ethylamine salt: Dow AgroSciences Indus dal Hygiene
<br />Guideline b 2 rtg/Ms as acid equivalen4 Skin.
<br />iriethyWmine: ACGIH TLV is 1 ppm, TWA, 3 ppm
<br />STEL, Skin, A4. OSHA PEL 's 10 ppm TWA, 15 ppm
<br />STEL
<br />3,6Dichloropicolinic acid (Clopyrelid): Dow Ago-
<br />6ciences Intlustrial Hygiene Guideline is 10 mg/M .
<br />ihanol (ethyl abohol): ACGIH TLV and OSHA PEL
<br />are 1000 ppm. ACIGH classNcation is A4.
<br />'Els are in accord with those recommentled by DSHA,
<br />rs in me 1989 revision M PELs.
<br />> "skin" notation following the exposure guideline
<br />efers to the potential br tlermal absorption of the ma-
<br />erial. It is intendetl fo alert the reader that inhalation
<br />nay not be the ony route of exposure and That mea-
<br />sures to minimize dermal exposures should be wnsid-
<br />~retl.
<br />:NGINEERING CONTROLS: Provide general and/or
<br />oral exhaust ventila0on to control airborne levels be-
<br />rw the exposure guitlelines.
<br />Database and forma[ copyright ©by C&P Press. AIf rights reserved.
<br />RECOMMENDATIONS FOR MANUFACTURING,
<br />COMMERCIAL BLENDING, AND PACKAGING
<br />WORKERS:
<br />RESPIRATORY PROTECTION: Atmospheric levels
<br />should be maintained bebw the exposure guitleline.
<br />When respiratory protection (s required for certain op-
<br />erations, use a NtOSH approvetl air-purlyklg respira-
<br />br,
<br />SKIN PROTECTION: When prolonged or fmquenfly
<br />repeated contact could occur, use protective clothing
<br />impervious to this material. Selectlon of specific items
<br />such as faceshieM, gbves, boots, apron, or full-body
<br />su0 w01 depend on operations.
<br />EYE PROTECTIDN: Use chemical goggles. If vapor
<br />exposure causes eye discomfort, use a NIOSH ap-
<br />proved fulFface respirator.
<br />APPLICATORS AND ALL OTHER HANDLERS: Re-
<br />fer to the product label for personal protectve cbihing
<br />and equipment.
<br />9. PHYSICAL AND CHEMICAL PROPERTIES:
<br />BOILING POINT: Approximarey 212'F (100'C)
<br />VAPOR PRESSURE: Similar to that of water
<br />VAPOR DENSITY (Air =1): Nm determined
<br />SOLUBILITY IN WATER: MSdble
<br />SPECIFIC GRAVITY: 1.14 Q 68'F/68-F
<br />APPEARANCE: Clear amber liquid
<br />DOOR: SIigM ambe sme8
<br />10. STABILITY AND REACTMTY:
<br />STABILITY: (GONDITIDNS TO AVOID) Stare under
<br />cool, dry wndidons. Avoid elevated temperatures and
<br />direct sunllgM
<br />INCOMPATIBILT': (SPECIFIC MATERIALS 70
<br />AVOID) Avoid acid, oxid'¢ing material, habgenated
<br />organice, brass, copper, zinc, and aluminum.
<br />HAZARDOUS DECOMPOSfTION PRODUCTS: Hy-
<br />drogen chloride, nitrogen oxides untler Poe cond'Rions;
<br />chlorinated pyridine.
<br />HAZARDOUS POLYMERIZATION: Not known to oo-
<br />cur.
<br />17. TOXICOLOGICAL INFORMATION:
<br />MUTAGENICfTY; For trictopyr and ctopyralid, in-v0ro
<br />antl animal mutagenicily stutlies were rregative.
<br />72 ECOLOGICAL INFORMATK)N:
<br />ENVIRONMENTAL FATE:
<br />MOVEMENT 6 PARTITIONING; Based largey or
<br />comple[ey on component udonna0on. Bioconcentra-
<br />flon potentials bw (BCF <700 or Log Pow <3).
<br />DEGRADATION 6 PERSISTENCE: Basetl largey or
<br />completey on tlafa for major components. Biodegre-
<br />dation under aerobic static laboratorycondi8ons is high
<br />(80020 or BOD28lThOD s >40%).
<br />ECOTOXICOLOGY: Based on in(ormatlon for tricbpyr
<br />TEA sak antl triethylarrrine. Material Is slghty bxic b
<br />aquatic organisms on an stole basis (LCSO/ECyp is be-
<br />tween 10 and 700 mg21n me most sensttive species).
<br />Based on information for cbpyrelid. Material is practF
<br />caly rwn-toxic to aquatic organisms on an acute basis
<br />(LCsp/ECsa is > 700 mg/L in most sens8ive species).
<br />73. DISPOSAL CONSIDERATIONS:
<br />DISPOSAL METHOD: Excess wastes are bxic. Im-
<br />proper disposal of excess wastes are a vbWibn of
<br />tederel Law. H these wastes cannot be disposed of
<br />by use according b label Insfruc0ons, wntact your
<br />state pesticitle or environmental control agency, or the
<br />hazardous waste representative at Ne nearest EPA
<br />regional office for guidance.
<br />14. TRANSPORT INFORMATION:
<br />For DOT regulatory informa0on, H required, consult
<br />Vansponatbn regulations, product-shipping papers, or
<br />contact your Dow AgroSciences representative.
<br />15. REGULATORY INFORMATION:
<br />NOTICE: Tha iMOnnation herein b presented in good
<br />faith and believetl b be accurate as of the effective
<br />date shown above. However, no warranty, express or
<br />implied, is given. Regulatory requirements are subject
<br />to change and may tlrffer from one bcation to anomer;
<br />a is the huyeYS responslblily to ensure that its activi-
<br />ties compty web federel, state or provincial, and local
<br />laws. The bllowirg specific IMOrmation is made for
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