|
MATERIAL SAFETY DATA SHEET
<br />Plateau® herbicide
<br />Protluct No.: 579651
<br />tateau° herbicide
<br />ate Prepared: 6l1fi/2000
<br />Date Revised: 1114f2001
<br />BASF Corporafion
<br />Agdcullurel Produces Group
<br />P.O.BOx 13528,
<br />Researoh Tdargle Park, NC 27709
<br />(919)547-2000
<br />EMERGENCY TELEPHONE NUMBERS:
<br />BASF Corporation: 1 (600) 832-HELP
<br />CHEMTREC: 1 (800) 424-9300
<br />SECTION I
<br />Trade Name; Plateau° herbirJtle
<br />Chemical Name: ammonium salt of Z-[4,5-0ihydro-
<br />4-methyl-4-(1-mettrylethyl}5-oxo-t H-imidazol-2-yIJ-S-
<br />rtlethyF3-pyridrnecarboxylc acid.
<br />Synonyms: Imazapic ammonium salt; AC263,222
<br />Formula: C14 H16 N3 03. NH4
<br />Chemical Famiy: imidazolinone
<br />Mol Wt: 292.337
<br />SECTION II -INGREDIENTS
<br />COMPONFM CAS NO. % PEL/fLV -
<br />SOURCE
<br />Imarapk, taaosaJ9-e 23.60 Nan.
<br />ammon~m nn aamnranea
<br />' Inam WA J6A0 None
<br />ewetan.a
<br />SARA Tdle III Section 313: Not Gsted
<br />SECTION III -PHYSICAL DATA
<br />BOILING/MELTING POINTQ760mm Hg: NN
<br />pH: 6.4 - 7
<br />VAPOR PRESSURE mmHg ~ 20'C: N/D
<br />SPECIFIC GR4VRY OR BULK DENSf1Y: 1.07 -1.09
<br />mL
<br />OLUBILITY IN WATER: Miscible
<br />APPEARANCE: Pale yelbw to green liquid
<br />DOR: N/D
<br />. ,,,,, INTENSITY: N/D _
<br />SECTION N-FIRE AND EXPLOSION DATA
<br />FLASH POINT (TEST METHOD): >200'F
<br />Al1TOIGNITION TEMP: NN
<br />FLAMMABILITY LIMBS IN AIR (% BY VOL):
<br />LOWER: Nrt1
<br />UPPER: NN
<br />NFPA 704 HAZARD CODES
<br />HEALTH: N/R
<br />FLAMMABLE: N/R
<br />INSTABILITY: 0
<br />OTHER: Nd2
<br />NFPA 30 STORAGE CLASSIFICATION: Class III B
<br />EXTINGUISHING MEDIUM: Use water fog, foam,
<br />DO(2), or tlry chemkal exfinguishing media.
<br />SPECIAL FIREFIGHTING PROCEDURES: Firefight-
<br />ers should be equipped with sekcontained breathing
<br />apparatus antl tumour gear.
<br />UNUSUAL FfRE EXPLOSION HAZARDS: None
<br />known.
<br />SELECT ACRONYM KEY
<br />N/A -Not available; N/D -Not determined; N!R -
<br />Not rated; NIE -Not established
<br />SECTION V -HEALTH BATA
<br />TOXICOLOGICAL TEST DATA:
<br />Data for the formulated product
<br />Rat, Orel LD50 (combined sexes) > 5000 mg4eg
<br />Rabbit, Dermal LD50 (wmbined sexes)> 5000 mg/kg
<br />Rat, Inhalaton LC50 (4 hr, anayfica0 > 2.38 rtglL
<br />Ra[, Inhalation LC50 (1 hr calcuWted) > 9.52 mg/L
<br />Rabbi4 Eye Irtkation -Not irrhatirg
<br />Rabbq Skin Hdtaaon - No! irka8ng
<br />Guinea pig, Denial Sensk¢er - Not a sk'm 5ensit¢er.
<br />OSHA, NTP, or IARC Carcinogen: Not listed.
<br />EFFECTS OF OVEREXPOSURE:
<br />See Product label and Directions For Use for ad-
<br />ditional precautionary statements.
<br />.~°.Vf`.-- CAUTION: KEEP OUT OF REACH OF CHILDREN
<br />HARMFUL IF INHALED OR ABSORBED THROUGH
<br />SKIN. AVOID BREATHING SPRAY MIST.
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET
<br />AVOID CONTACT WITH SKIN, EYES ORCLOTHING
<br />Exisfing medical corufi0ons aggravated by mis product
<br />None known
<br />FIRST AID PROCEDURES
<br />N Inhaled: Move person to hash air. If person is rw
<br />breaching, cak 977 or an ambulance, Then give arfificia~.
<br />respiration, preferaby mouth-to-moulh k po551b1e. Cal'.
<br />a poison central center or dollar for further treatment
<br />advice.
<br />If on skin: Take oft contaminated cbMing. Rinse skir
<br />immediately with plenty of water for 15-20 minutes.
<br />Call a person centrol center or doctor for Treatment
<br />advice.
<br />H in eyes: Hold eye open and rinse Blowy and genty
<br />wkh water fw 1 S20 minutes. Rertrove contact lenses,
<br />iF present, after first 5 mimes, then wnfinue rinsing.
<br />CaG a poison centrol center or tloctw for treatment
<br />advice.
<br />If swallowed: Call a poison control center or doctor
<br />irwnediateN lw leatmen! advice. Have person sip
<br />a glass of water 'rf able to swaGOw. Da not induce
<br />vomiting unless told b by a poison wntrd center or
<br />domes. Do not give anything to an uncenacious person.
<br />Note to physician: There is no specific an5dote for
<br />exposure to this material. Treatment of overexposure
<br />shoultl be directed at the canfml of symptoms and the
<br />clinical conditions.
<br />Note: Have the product container or label wkh you
<br />when calling a po'ISOn central cemer w doctor or going
<br />for treatment
<br />SECTION W - REACTIVITY DATA
<br />STABILT': Stable. Do not store below 20'F.
<br />CONDITIONS TO AVOID: Store in original wntainer
<br />in tool,tlry, well ven0latetl place away from Ignitron
<br />sources, heat or flame.
<br />CHEMICAL INCOMPATIBILITY: Oxidizing agems,
<br />corrosive zinc, iron antl Mld steel
<br />HAZARDOUS DECOMPOSITION PRODUCTS: In-
<br />clutling but not limked to oxides of carbon and nitrogen.
<br />HAZARDOUS POLYMERIZATION: Does not occur.
<br />CONDITIONS TO AVOID: Does not pclymedze.
<br />CORROSIVE TO METAL: No
<br />O7(IDD:ER: No
<br />SECTION VII -PERSONAL PROTECTION
<br />Users gf a oesticidal end use p or duN hs Quell
<br />er ter to the ro otluct abet for ersona protective
<br />eaufomant recuirements:
<br />RECOMMENDATIONS ~(~ MANUFACTURING.
<br />COMMERCIAL BLENDING AND PACKAGING
<br />WORKERS:
<br />Respiretory Protection:
<br />Supplied ak respiretors stwukl be worn N large quant4
<br />ties of misLdust are generated or prolonged exposure
<br />possible.
<br />Eye Protection:
<br />Chemical goggles when respirator does not provide
<br />eye pro[ecfion.
<br />Protective Clothing:
<br />Gbves antl protective cbthing as necessary to prevent
<br />skin wntact.
<br />Vemilation:
<br />Whenwer possible, engineering controls should be
<br />used to minim¢e the need for personal protective
<br />equipment -
<br />SECTION VIII -ENVIRONMENTAL DATA
<br />ENVIRONMENTAL TOXICITY DATA
<br />See the Woduct label fw information regarding envi-
<br />ronmental toxkiy.
<br />SA17q 311/312 REPORTING
<br />FIRE: N
<br />PRESSURE: N
<br />REACTIVIT': N
<br />ACUTE: V
<br />CHRONIC: N
<br />iP0(Ibs): N/R
<br />SPILL AND LEAK PROCEDURES:
<br />In case of large scale spillage of this protlud, avoid
<br />:ontact, isolate area and keep out animals and unpro-
<br />acted persons. Call CHEMTREC (800 424-9300) or
<br />3ASF Corporation (800 832-HELP). For a smaG spill,
<br />year personal protectve equipment as specified on
<br />he label. i
<br />FOR A SOLID SPILL: Sweep solitl into a tlmm for re-
<br />use or disposal. Remove personal protective equip-
<br />mentand decontaminate k prior to re-use.
<br />HAZARDOUS SUBSTANCE SUPERFUND: No
<br />RO(Ibs): None
<br />WASTE DISPOSAL METHOD:
<br />' Pesticide wastes are aculey hazardous. Wastes r&
<br />sul8ng from this product may be deposed of on eke
<br />or at an approved waste disposal facility. Improper
<br />disposal of excess pestcide, spray m& or rinsate is
<br />a viOlaOon of federal law. If these wastes cannot be
<br />tlisposed of accordalg to label instructions,~contaq the
<br />state agency responsible fw pesticide regula0on w the
<br />Hazardous Waste represemative at the nearest EPA
<br />Regronal Office for guidance.
<br />HAZARDOUS WASTE 40CFR261: No
<br />HAZARDOUS WASTE NUMBER: None
<br />COMAINER DISPOSAL:
<br />FOR PLASTIC CONTAINERS: Tdple dose (or equiva-
<br />lent) and add rinsafe to the spray tank. Then offer for
<br />recycling or recentlkioning, qr puncWre and depose of
<br />in a sanitary landfill, w try incineration, or k aGowed by
<br />state and local aulhodties, by burning, If bumetl, stay
<br />out of smoke.
<br />FOR BULK CONTAINERS: Reusable containers
<br />shoud be retained to the point of purchase for
<br />cleaning and refilling.
<br />FOR MINIBULK CONTAINERS: Clean all tanks on an
<br />apprwetl boding pad sD dnsate can be collected and
<br />meted into the spray solutlon or Inm a dedicated tank.
<br />Using a high pressure sprayer, dose several dines with
<br />smaE volumes of water b minimize rinsate.
<br />SECTION IX -SHIPPING DATA- PACKAGE AND
<br />BULK
<br />D.O.T. PROPER SHIPPING NAME (49CFR172.101•
<br />102): None
<br />HAZARDOUS SUBSTANCE (d9CFR CERCLA LLST):
<br />RO(Ibs): None
<br />O.O.T. HAZARD CLASSIFICATION (CFR 172.101-
<br />102):
<br />PRIMARY
<br />None
<br />SECONDARY
<br />D.O.T. LABELS REQUIRED (49CFR172.101.102):
<br />None
<br />D.O.T. PLACARDS REQUIRED (CFR172.504):
<br />POISON CONSTITUENT (49CFR172103(IC)):
<br />BILL OF LADING DESCRIPTION
<br />Compounds, lrea or weed kllling (herbicides), NOIBN
<br />This product is not reguWtetl by the Department of
<br />Transportation.
<br />CC NO.: Not applicable
<br />UNMA CODE: None
<br />SECTION X - ADDITIONAL INFORMATION
<br />Plateau° hadJicfda
<br />EPA Reg. No. 241-365
<br />KEEP OUT OF REACH OF CHIL-
<br />DREN
<br />CAUTION
<br />BASF Corporation
<br />Agdcultural Products Group
<br />P,O.BOx 13528,
<br />Research Tdangle Park, NC 27709
<br />(919) 547-2000
<br />DISCLAIMER '
<br />IMPORTANT: WHILE THE DESCRIPTIONS, DE•
<br />SIGNS, DATA AND INFORMATION CONTAINED
<br />HEREIN ARE PRESENTED IN GOOD FARM AND
<br />BELIEVED TO BE ACCURATE, R IS PROWDED
<br />FOR YOUR GUIDANCE ONLY. BECAUSE MANY
<br />FACTORS MAY AFFECT PROCESSING OR AP-
<br />PLICATIONNSE, WE RECOMMEND THAT YOU
<br />MAKE TESTS TO DETERMINE THE SUTTABIL-
<br />ITV OF A PRODUCT FOR YOUR PARTICULAR
<br />PURPOSE PR10R TO USE. NO WARRANTIES OF
<br />ANY KIND, ERHER EXPRESS OR IMPLIED, IN-
<br />CLUDING WARRANTIES OF MERCHANTABILITI'
<br />OR FITNESS FOR A PARTICULAR PURPOSE, ARE
<br />MADE REGARDING PRODUCTS DESCRIBED OR
<br />DESIGNS, DATA OR INFORMATION SET FORTH,
<br />OR THAT THE PRODUCTS, DESIGNS, DATA OR
<br />INFORMATION MAYBE USED WITHOUT INFRING-
<br />ING THE INTELLECTUAL PROPERTY RIGHTS OF
<br />Database and format copyright ®by Vance Communication Corp.. All dghts reserved.
<br />3iai:a2-r
<br />i
<br />
|