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MATERIAL SAFETY DATA SHEET
<br />DUPONTLANDMARK
<br />P HERBICIDE
<br />0000490
<br />evised 31-JUL-2003
<br />CHEMICAL PRODUCTlCOMPANY IDENTIFICA~
<br />TION
<br />Material IdentiRCation
<br />TELAR DF, OUST XP are registered trademarks a
<br />DuPont
<br />LANDMARK MP, DUPONT ate trademarks of DuPont.
<br />Tredenames and Synonyms
<br />DUPONT LANDMARK MP
<br />LANDMARK MP
<br />Company ldentfFicatfon
<br />MANUFAC7URERIDISTRIBUTOR
<br />DuPont
<br />1007 Market Street
<br />Wilmington. DE 19698
<br />PHONE NUMBERS
<br />Product IMOrtnation: 1-500441-7515 (outsitle Me U.S.
<br />302-774-1000)
<br />• Trenspon Emergency: CHEMTREC 1-600424-9300
<br />{outside U.S. 703-527-3887)
<br />Metligl Emergency: 1.800-441-3637 (outsidethe U.S.
<br />302-7741000)
<br />COMPOSITIONIINFORMATION ON INGREDIENTS
<br />Components
<br />M~britl
<br />LAe Numen X
<br />oust xR ]e2zz-wa so
<br />(sULFOMETURON MEfHYI)
<br />( AMINOICAPBONriIAMIN09ULFONYL~ENZOATE)
<br />TEIAR DF 60902-]2-3 25
<br />(uaoRSULFU6orq
<br />12-GHLORO.NI(4METHOXY-6-METHri-1,3,5; TRIA2IN-
<br />2YL)4MNOCARBOML) 6ENZENESULFONM1mE
<br />INERT NGREDIEMS 26
<br />Disclosure as a toxic chemical H required under Sec-
<br />- ion 313 of Title III of the SuperfurM Amendments and
<br />~` eauthorization AM of 7986 and 40 CFR part 372
<br />Components (Remarks)
<br />DuPont landmark H a two comparbneM bagged prad-
<br />uct cons'stirg of DuPont Oust XP and Telar DF.
<br />HAZARDS IDENTIFICATION
<br />Emergenry Overview
<br />CAUTIONI Harmful 'rf swallowed or absorbed Mrough
<br />skin. Causes moderate eye irdtatbn. Avoid wmact
<br />with eyes, skin or clothing.
<br />Potential Health Effects
<br />Based on animal data from components, eye contact
<br />with DuPont Landmark MP may cause eye irdtation
<br />wiM diswmfort teadng, or blurring of vision.
<br />Based on animal data horn components, ingestion of
<br />DuPont Landmark MP may lead to red blood cell tle-
<br />smrctbn.
<br />Carcinogenicity Information
<br />None of the components present in this material at
<br />concentraflons equal to or greater than 0.7 % are listed
<br />by IARC, NTP, OSHA or ACGIH es a caroinogen.
<br />- FIRST AID MEASURES
<br />First Aid
<br />EYE CONTACT:
<br />IF IN EYES: Holtl eye open and dose slowly and gently
<br />w6h water for 15-20 minutes. Remove wntact lenses,
<br />N present, after the first 5 minutes, Men continue dosing
<br />eye. Call a poison control centeror doctor for treatrnent
<br />advice.
<br />INHALATION:
<br />IF INHAt.ED: No specific intervention a indicated as
<br />the Droduct is not Ikey to be hazardous by.Inhalafion.
<br />Consul) a physician ff necessary.
<br />INGESTION:
<br />IF SWALLOWED: Call poison control center or doctor
<br />Immediatey for heatment advice. Have a person sip
<br />a glass l water tt able to swallow. Do not induce
<br />o - omiting unless told to do so by Me poison control
<br />4: enter or dolor. Do not give anyNing by mount to an
<br />unconscious person.
<br />SKIN CONTACT:
<br />UPDATES AVAILABLE AT WNJW.GREENBOOK.NET
<br />IF ON SKIN OR CLOTHING: Take off wntaminated
<br />clothing. Rinse skin immediatety with plenty of wa-
<br />ter for 15-20 minutes. Call a poison control center or
<br />dolor for treatment atlvice.
<br />Have the product wntalner or label wiM you when
<br />calling a poison confrol center or doctor, or going for
<br />treMmeM. You may also confad 1-600-041-3637 for
<br />emergency medical treatment Information,
<br />FlRE FIGHTING MEASURES
<br />~ Flammable Properties
<br />Flammable limks M Air, % by Volurrre
<br />LEL: 0.092 g2
<br />Not a fire or explosion hazard.
<br />Like most organic powders or crysta5, antler severe
<br />dusting conditions, Nis material may form explosive
<br />mbctures in air.
<br />EMinguishing Media
<br />Water SDrey, Foam, Ory Chemical, C02.
<br />Fire Fighting Instructions
<br />Wear sellaoncained breaching apparatus. Wear fir)1
<br />protective equipment Use water spray. Runo# from
<br />fire control may be a pollution hazard.
<br />H area Is exposed to fire and conditions penntt, let
<br />fire bum flsett oN. Burning chemicals may produce
<br />bY-producM mwe toxic than the odgmal materal. #
<br />product H on fire, wear self-contained breathing appa-
<br />ratus and full protectve equipment Use water spray.
<br />Control mnoff.
<br />ACCIDENTAL RELEASE MEASURES
<br />Safeguards (Personnel)
<br />NOTE: Review FIRE FIGHTING MEASURES and
<br />HANDLING (PERSONNEL) sections before proceed-
<br />ing with clean-up, Use aDPropriate PERSONAL PRO-
<br />TECTVE EQUIPMENT tlurirg clean-up.
<br />Emergency Response -Chemical resistant coveralls,
<br />waterproof gbves, waterproof boots and face/eye pro-
<br />faction. If dusting occurs, use NIOSH approvetl respF
<br />rotor protection.
<br />Initial Corrtalnment
<br />Dike spill. Prevent material from entedng sewers, wa-
<br />terways, or low areas.
<br />Folkrw eppficeble Federal, State/Provincial and Local
<br />Wvrs/regulations.
<br />Splll Clean Up
<br />Shovel or sweep up.
<br />HANDLING AND STORAGE
<br />Handling (Personnel)
<br />USERS SHOULD: Wash hands before eating, drink-
<br />ing, chewing gum, using tobacco m using the bllet.
<br />Do not get in eyes. Avoid breathing tlusL vapors or
<br />mist. Avoid contact wtth eyes, skin or cklihing. Wash
<br />thoroughy after handling. Wash cbihirg alter use.
<br />Do not store w consume food, drink or totuwco In
<br />areas where they may become contaminated with this
<br />material,
<br />Handling (Physical Aspects)
<br />Avoitl dust generation. Keep away from heat, sparks
<br />and flames.
<br />Storege
<br />Store product in original container ony. Do not con-
<br />taminate water, other pesticides, fer81¢er, food or feetl
<br />in storage.
<br />EXPOSURE CONTROLSIPERSONAL PROTECTION
<br />Engineering Controls
<br />Use ony wiM adequate venAlation. Keep container
<br />fighty closed.
<br />Personal Protective Equtpmen!
<br />Always follow the label instrulions when handling this
<br />product
<br />Use of Landmark MP herbicide on noncrop skes is not
<br />wkhin Me scope l the Worker Protection Standard.
<br />Do no7 enter w aAOw others to enter The treated area
<br />uMJ sprays have dried.
<br />Exposure Guidelines
<br />Applicable-Exposure Limits
<br />DUST XP
<br />AEL (OSHA): None Established
<br />RV (ACGIH): 5 mg/m3, 8 Hr, TWA, A4
<br />4EL' (DuPont): 10 mg/m3, 6 8 12 Hr. TWA total dust
<br />fELAR DF
<br />°EL (OSHA): None Established
<br />rLV (ACGIH): None Established
<br />Database and format wpyright ®by Vance Communication Corp.. All rights reserved.
<br />AEL' (DuPont): 10 mg/m3, 8 8 12 Hr. TWA .
<br />' AEL is DuPonTS Acceptable Exposure Limn Where
<br />govemmeMaly inposetl occupational exposure limits
<br />which are lower than the AEL are in eftecL such limbs
<br />shall take precedence.
<br />PHYSICAL AND CHEMICAL PROPERTIES
<br />Physical Data
<br />Physical Data -Oust XP
<br />SolubTlry in water: Dispersible
<br />Odor. None
<br />', Form: Solid, tlry flowable
<br />Color. Off-white
<br />Bulk denslry (Loose): 33 Mlcu ft
<br />Bulk tlereiry (Packed): 39 IWCU ft
<br />Physical Deta - Telar DF
<br />Solubliry in water. Dispersible
<br />pH: 4.5 @ t%suspension
<br />Otlor. None
<br />Form: Solid
<br />Cobr. Tan
<br />Specific Brevity: 0.69 @ 25C (77F)
<br />Density: 0.64-0.74 g/mL
<br />STABILITY AND REACTIVITY
<br />Chemical Stability
<br />Stable a[ nomwl temperatures and storage contlitbns.
<br />Incompatibility with Other Materials
<br />None reasonabty foreseeable.
<br />Deoompositlon
<br />Dewmposkion w7tl not occur.
<br />Polymanzatlon
<br />Polymerization will not occur.
<br />TOXICOLOGICAL INFORMATION
<br /># Animal Data
<br />Oust XP
<br />Inhalatbn 4 hour LC50: > 5.3 mgA. M refs (Very krv
<br />toxkiry by inhalation)
<br />Skin absorption LD50: > 5000 mgtkg N rabbits
<br />(Slightly to motleretey toxic by contact)
<br />Orel LD50: > 5000 mg/kg m rats (Very bw toxicity by
<br />ingesibn)
<br />Oust XP H slight to mAd skin inttanL and a mild eye
<br />imlant but Ls not a skin sensit¢er in animals.
<br />Single inhalatbn exposure with Oust XP (SUtfometuron
<br />Methyl 75%) in rats caused slight b moderate body
<br />weight bss, nasal and owWr tlischarge, and other
<br />nonspecific effects.
<br />Sing@ high oral doses of Oust XP (SuROmeiuron
<br />Methyl 75%) produced no clinical signs of toxictly
<br />antl no lesions were observetl tludng pathological ex-
<br />amination of tlssue. Repeatetl oral studies with the
<br />active ingredient, Sulfometuron Methyl, caused do-
<br />creased body weight gain, Trvercharges, red blood cell
<br />hemolysis, and aeeretl wh&e blood cell differentiation.
<br />Long-term exposure causetl mint henroy8c acemta,
<br />decreased body weight. akeration aF clinical chemical
<br />parameters, antl changes in Me bik duct.
<br />Oust XP (SVUaneturon Mehyl 75%) administered M
<br />single high demml doses caused temporary severe to
<br />sl"ght skin irritation and sporadic weight loss.
<br />Animal testing indicates Mat the alive ingredient, Sul-
<br />fometuron Methyl, does not have carcinogenic eflecfs.
<br />!n a two generation rat reproduction study w1M the ac-
<br />tive MgretlienL Suttometuron Mehyl, decreasetl num-
<br />bers of pups were observed at Me 5000 ppm level, e
<br />dose Mat was ako mmemaly toxic. No reprotluctive
<br />effects were observed at 500 ppm,
<br />Su7ometwon meMYl did not produce developmental
<br />toxicity when tested in animaLS. Suttometuron meMyl
<br />ditl not protluce genetlc damage in haledal or mam-
<br />malian ce4 cultures.
<br />Telar DF Herbicide
<br />Oral LD50: > 5000 mglkg M rats (Very knv tozid y)
<br />Skin Absorption LD50~ > 2000 mg/kg in rabbits
<br />(Slightly to moderately toxic)
<br />Telar DF Herbicide is a mild reversible skin irdtant, and
<br />a moderate eye ird[ant bN is not a skin sensit¢er in
<br />animals.
<br />Chlorsulfuron
<br />Inhalatlon 4 hour LC50: > 5.9 mglL in rats (Very k»v
<br />toxicity by inhalation)
<br />The effects in animals from repeated exposures by
<br />inhalation to Chkxsuifuron incNde decreased weight
<br />.--»-
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