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MATERU\L SAFETY DATA SHEET
<br />UPONT KRENITE
<br />k BRUSH CONTROL
<br />GENT
<br />M0000022
<br />Revised 2-APR-2004
<br />CHEMICAL PRODUCT/COMPANY IDENTIFICA
<br />710N
<br />Material 7dentr(cation '
<br />"KreMe" is a reg'IStered trademark of DuPont
<br />"DuPonP is a trademark of DuPont
<br />Corporate MSDS Number. D0003056
<br />Grade: CONTAINS 4 LB ACTIVE INGREDIENT PEF
<br />GALLON
<br />Tradenames and Synonyms
<br />"KRENITE"
<br />"KRENITE" S BRUSH CONTROL AGENT
<br />Company Identiflcetion
<br />MANUFACTURER/DISTRIBUTOR
<br />DuPont
<br />'1007 Market Strcet
<br />Wlmingtan, DE 19698
<br />PHONE NUMBERS
<br />Product Information: t-SOOd41-7515 (outside the U.S.
<br />302-774-1000}
<br />Tansport Emergency: CHEMTREC 1.800>24-9300
<br />(outside U.S. 703-527-3857)
<br />Medical Emergency: 1-BOOd41-3637 (outside Me U.S.
<br />302-774-1000}
<br />COMPOSITIOWINFORMATION ON INGREDIENTS
<br />Components
<br />Malarial CRa Number X
<br />FOSAMINE AMMONIUM 159541]-fi ir.5
<br />(AMMOMUM SALT OF FOSAMIHE (ETHYL
<br />HYDROGEN IAMINOCARBONYL)
<br />PHOSPHONATE9
<br />INERT WGREDIEMS 59.5
<br />~ /rAZARDS IDENTIFICATION
<br />Emergency Overview
<br />CAUTIONI Causes (moderate) eye injury (inhation).
<br />Avoid contact wah eyes or cbMing.
<br />Potential Health Effects
<br />Inhaation Or Krenhe may cause imatbn of nose,
<br />throat, antl bogs, with cough, difficulty breathing a
<br />shortness of breaM. and nonspecifc disconrfort, such
<br />as nausea, headache, or weakness.
<br />Skin contact with Krenite may cause skin irtttation with
<br />itching, buming, redness, swelling a rash. Significant
<br />skin penetration and systemic roxiury after skin contact
<br />appears unlikey.
<br />There are inwnclusWe or umedfied reports of human
<br />sensitization.
<br />Eye contact with Krenite may rouse eye irritation wiM
<br />tearing, pain or blurted vis'lon.
<br />Ingestion of high doses of Krenite maY cause nompe-
<br />cific discomfort such as nausea, headache or weak-
<br />ness.
<br />Carcinogenicity Information
<br />None of Me components present in Mis material at
<br />wncentations equal M or greater than D.1 % are listetl
<br />by IARC, NTP, OSHA or ACGIH as a carcinogen.
<br />FIRST AID MEASURES
<br />First Aid
<br />IF IN EYES: Hold eye open and dose sbwy and genty
<br />who water for 15-20 mkrutes. Remove wntact lenses,
<br />a present, after the first five minutes, then wntinue
<br />dosing eye. Call a poison control center or doctor for
<br />treatment advice.
<br />IF INHALED: No specKc intervention b indicatetl as
<br />Me compound b not likely to be hazardous by inhala-
<br />tion. Consult a physician g necessary.
<br />IF SWALLOWED: No specNC intervention is indicated
<br />s Me wmpound ce not likely to be hazardous by in-
<br />estion. Consult a physician a necessary.
<br />;. F ON SKIN OR CLOTHING: No specific intervention is
<br />",ntlicated as the wmpound is not likey to be hazardous
<br />to skin by dermal exposure. Consult a physician it
<br />necessary.
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET 1
<br />Have the product container label wtth you when calimc
<br />a poison control center or doctor, or going for treab
<br />ment. You may also contact i-600.441-3637 formed
<br />ical emergencies involving this product
<br />FIRE FIGHTING MEASURES
<br />Flammable Properties
<br />Not a fire or expbsion hazard.
<br />Extinguishing Medal
<br />Water Spray, Foam, Dry Chemical, C02.
<br />Fire Fighting MStructions
<br />Wear sag-corrtained breathing apparatus. Wear
<br />full protec8ve equipment. Use water spay. Cool
<br />iank/wntainer with water spray. Runofr from foe
<br />wnuot may be a pottutbn hazard.
<br />If area is exposed fo fire and conditions permit, let
<br />fve bum aseg oW. Buming chemicals may produce
<br />by-products more toxic than the original marorial. If
<br />' product is on (ore, wear self-conainetl breathing appa-
<br />ratus and full protective equipment Use water spay.
<br />CDmrol mnOR.
<br />ACCIDENTAL RELEASE MEASURES
<br />Safeguards (Personnen
<br />NOTE: Review FIRE FIGHTING MEASURES and
<br />HANDLING (PERSONNEL) sections before proceed-
<br />ing with clean-up. Use appropriate PERSONAL PR0.
<br />TECTIVE EQUIPMENT tludng clean-up.
<br />Emergency Response -Chemical resistam wverelPS,
<br />waterproof gloves, waterproof boots and laceleye pm
<br />fecdon. If dusting occurs, use NIOSH approved raspF
<br />refor protection.
<br />Initial Contalrunent
<br />Dke spill. Prevent material fran entering sewers, wa-
<br />terways, or bw areas.
<br />Spill Clean Up
<br />Soak up wiM sawdus4 sand. oil dry or other absorbent
<br />material. Shovel w sweep up. Never return to wn-
<br />uinerfor reuse Scoop into tugs or boxes wiM plasfic
<br />or aluminum stavel.
<br />Accidental Release Measures
<br />fr spill area is on grountl near valuable plants or trees,
<br />remove top 2 inches of soft after initial cleanup.
<br />HANDLING AND STORAGE
<br />Handling (Personnel)
<br />Do not get In eyes, on skin, or on cloming. Avoltl
<br />breahing vapors or Mst. Wash Moroughy offer han-
<br />tlling. Do not store or consume food, drink or tobacco
<br />in areas where Mey may become contaminated wiM
<br />Mis material.
<br />USERS SHOULD: Wash hantls before eating, drink-
<br />ing, chewing gum, using tobacw or using the toilet.
<br />Storage
<br />Store product M original wntainer Doty. Do no[ don-
<br />taminate water, Omer pesticides, fertil¢er, (ootl or feed
<br />in storage.
<br />EXPOSURE CONTROLS/PERSONAL PROTECTION
<br />Engineering Controls
<br />Use only with adequate ventilation. Keep container
<br />tighty cbsed.
<br />Personal Protectwe Equipment
<br />Applicarors and omer handlers must wear.
<br />Long-sleevetl shirt antl bog pants,
<br />Shoes plus socks.
<br />Follow manufacturer's instructons for dean-
<br />ng/maimaining PPE, tt no such instructions for
<br />Mashables, use detergent and hot water. Keep and
<br />rash PPE sepaatey from omer laundry.
<br />WE required far eany entry to treated areas Mat is per-
<br />nhtetl under the Worker Protection Sundard and Mat
<br />nvolves contaG wiM anything that has been treated,
<br />:uch as plants, snit, or water, a:
<br />:overalls.
<br />ihces plus socks.
<br />:xposure Guidelines
<br />:xposure Limits
<br />'DMPont" "KRENTE" S BRUSH CONTROL AGENT
<br />'EL (OSHA): None Establishetl
<br />1V (ACGIH): None Esublished
<br />Database and fonnaE copyright ®by Vance Communication Corp.. AI! rights reserved.
<br />PHYSICAL AND CHEMICAL PROPERTIES
<br />PhysMa7 Data
<br />SolubOiry in Water. Soluble
<br />Fonn: Lpuid
<br />Color. Colorless ro brown
<br />Specific Gravity: 1.77 ~ 24'C (75'~
<br />STABILRY AND REACfMTY
<br />Chemical Stability
<br />Stable at normal temperatures and storage corWidons.
<br />Incompatibility with OMer Materials
<br />None reasonably roreseeabfe.
<br />Decomposition
<br />Decomposition wi0 not oww.
<br />PotymertzaUOn
<br />Polymeraation will tort occur.
<br />TOXICOLOGICAL INFORMATION
<br />Animal Data ,
<br />Krenite
<br />Oral ID50: > 5000 mg4cg h rats
<br />Dermal LD50: > 5000 mg4rg M rabbits
<br />Inhalation LC50, 4 hr: > 5,8 mgt M rats
<br />Krenite LR a reversible moderate b severe eye irritant, a
<br />mOd ro moderate skin inian; but not a skin sensitaer.
<br />the effects of skm exposwe to nigh doses d Wenite
<br />include non-specific effects such as weight loss. Re-
<br />peated exposures ro lower doses caused rw sgns of
<br />toxicity.
<br />The effects of ingestion of single high doses of Krenite
<br />include diarrhea and vomiting. Repeated or brg-term
<br />ingestion of lower doses causetl mild Diarrhea in some
<br />animals, bW no other clinical or pathobgical evidence
<br />of toxicity.
<br />The effects from single. high exposures by Inhalation
<br />o(Krentte, include resp'neroryand eye irraatiw, weight
<br />bss, and weakness.
<br />No animal data are available to define the carcinogenic
<br />hazarcls of Krenae.
<br />Krenite has not pusetl tlevebpmental toxicity in an-
<br />imals. The active Ingretlient Fosamkie ammonium,
<br />has not caused reproducdve toxicity b animals.
<br />Tests have shown Mat Wenae does not cause genetic
<br />tlamage in bacterial or mammalian cell culbres, or ih
<br />animals. h has not been tested for heritable genetic
<br />damage.
<br />ECOLOGICAL INFORMATION '
<br />Ewtoxlcologiwl Information
<br />FOSAMINE AMMONIUM
<br />AQUATIC TOXICITY:
<br />96 hour LC50 -Rainbow trouC 330 mglL
<br />96 hour LC50 - Blue9ill sunfish: 590 mglL.
<br />96 hour LC50 - FeMead mintaws: > 1000 rtglL.
<br />46 hour LC50 - paphnia magna: 1524 ppm.
<br />AVIAN TOXICITY:
<br />LD50 • Mallard Duck: > 500D mg/kg,
<br />LD50 - Quell. > 5000 mg4cg.
<br />Acute Dietary LC50 - Mattard Duck: > 5620 ppm.
<br />Acute Dietary LC50 -Quail. > 5620 ppm.
<br />DISPOSAL CONSIDERATIONS
<br />Waste Disposal
<br />Treatment storage, transportation, antl disposal
<br />must be In accordance with appttcable Federal,
<br />state/provincial, and bcal regulations. Remover
<br />nonusable free ligWtl and dispose of m approved aM
<br />pemJaetl incinerator. Do not flush to surtaw water or
<br />sanitary sewer system.
<br />Do not contaminate water, food or feed by disposal.
<br />Wastes restating horn Me use o/ tors product may be
<br />disposetl of on sae or at an approved waste disposal
<br />IacOiry,
<br />ENVIRONMENTAL HAZARDS
<br />Do not appy direcay to water, or to areas where sw-
<br />lace water is present, or to inror6dal areas below the
<br />mean high water mark. Do not contaminate water by
<br />:leaning of equipment or disposal of equipment wash-
<br />Maters.
<br />Container Disposal
<br />triple rinse (or equivalent) Me container. Then offer for
<br />~ecyding or rewntlabning, or puncture and dispose of
<br />n a saniary landFll, or by Incineration, or if allowed by
<br />;tare and local authorities, by buming. If burned, stay
<br />1W of smoke.
<br />..r'
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