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• comparing irrigation versus non-irrigation periods is at well GW-N20. The TDS level <br /> decreases 672 mg/1 during periods of no irrigation. Slight TDS increases occur at Wells <br /> CW-N14 and GW-N17P1 during periods of no irrigation. Mean TDS levels for the three Dakota <br /> coal wells (GW-N14, GW -N 17P1 and GW-N20) during periods of irrigation and no irrigation <br /> are 4,323 and 4,366 mg/1, 2,740 and 1,798 mg/1, and 2,198 and 2,251 mg/1, respectively. <br />Schoeller diagrams, showing mean milliequivalent values for the Dakota coal wells for the <br />two above-referenced time periods, are presented on Figures 7-12 through 7-14. During <br />periods of no irrigation, Well GW-N14 shoes a decrease in magnesium, but increases in <br />calcium, bicarbonate and sulfate that account for the small increase in mean TDS. On <br />first appearance, one would conclude that Figure 7-13 is showing an accounting of a <br />decrease in TDS during periods of no irrigation. TDS actually increases when irrigation <br />is discontinued. the seemingly large decreases in calcium and magnesium are more than <br />offset by the increases in sodium, bicarbonate and chloride. The sodium increase is <br />principally responsible for the increase in TDS because it occurs at milliequivalent <br />levels that are a factor of 10 times greater than the calcium and magnesium levels. The <br />Schoeller plot for Well GW-N17P1 looks atypical for coal aquifer chemistry. The high <br />• sodium values and very alkaline pH level strongly suggest that the well completion zone is <br />partially open to high sodium overburden and interburden units as well as the coal. Well <br />CW-N20 shows a significant decrease in TDS during non-irrigation periods. Calcium, <br />magnesium, sodium antl sulfate levels all decrease r,hen irrigation is discontinued. Only <br />bicarbonate increases slightly, but at very low milliequivalent levels. <br />The pH level for Wells CW-N14 and CW-N20 range from 4.7 to 7.6 while Well GVl-N17P1 ranges <br />from 8.2 to 9, 8. As was previously mentf oned, these very alkaline pH's are atypical of <br />coal aquifer levels and are believed to be due to the well completion. Mean pH values for <br />Wells GW-N14, GW-N20 and GW-N17P1 are 4.95, 5.03 and 8.45, respectively, <br />There is some suggestion of a limited amount of seasonal variability to the Dakota coal <br />chemistry at the Nucla East mining area. In comparing spring versus fall chemistry, <br />magnesium, sulfate and TDS levels decrease and sodium and potassium levels increase in the <br />fall. A comparison of sunnier versus fall chemistry suggests that bicarbonate, chloride <br />and pM levels increase and magnesium levels decrease in the winter. <br />Chemical trends over time are also evident in the Dakota coal aquifer, Well GW-N 14 shows <br />• a decreasing trend in calcium levels during irrigation periods. Well GW-N17P1 shows a <br />7-65 Revised 04/11/88 <br />