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- TIIE GEOLOGICAL INl'ERPRET,ITIO~\' OF {tiELL LOGS - <br />Table 7 <br />7 Unwant <br />d e <br />vi <br />o <br />tal <br />t~a <br />e <br />ff <br />l <br />s <br />. e <br />n <br />r <br />nm <br />n <br />e <br />ec mma ray <br />og <br />. <br />Factor Effect on log Sererity <br />Simple Taol <br />caving lowers values, bigger the common <br /> cave, lower the value <br />barite in mud lowering o(value common <br /> in thick mudcakes <br />KCI mud significant increase present <br /> in 'background' <br />Spectral Tao! <br />caving lowers value in caves: common <br /> tool eccentred so <br /> effect much reduced <br />barite in mud increase in calculated common <br /> thorium and uranium <br />KCI mud increase in calculated present <br /> potassium and <br /> uranium <br />values (Figure 7.10). It is sometimes proposed that this <br />is simpl}• a 'base line shift', because the mud volume <br />through the hole is relatively constant so there will only <br />be a constant increase in the background: relative ampli- <br />tude changes will remain unaffected. This is not always <br />the case, especiall}' so when there is invasion and KCI- <br />rich mud enters into the formation. Such a situation will <br />cause an invaded resen•oir to show too high a gamma ray <br />reading (see also the spectral log below). <br />Spectra( gamma ray -The spectral gamma ray log is <br />run held near the borehole wall by a bowspring to reduce <br />the borehole effects which occur when a tool is centred. <br />However, this does not eliminate mud effects entirely and <br />Table 7.8 Potassium in clay minerals: chemical content. From <br />Serta (1979). Dresser Atlas (1983). <br /> 'Potassium content <br />A1ineral Sc by weight Average 9o Construction <br />Illite 3.51-8.31 5.20 K, AI.Silicate <br />Glauconite 3.20.5.80 4.50 K, Mo, Fe, AI, <br />Silicate <br />Kaolinite 0.00.1.x9 0.63 AI, Silicate <br />smectite 0.00-0.60 0?2 Ca, Na. Mg, AI <br />Silicate <br />Chlorite 0 0 Mg, Fe. AI, <br />Silicate <br />'Averaee shale = 29c - 3.59c potassium <br />the spectral log is affecte the mud additives barite and <br />KCI (Table 7.7). The effects vary depending on tool <br />design (Company), and the algorithms used to derive <br />abundances. If only the tlvee energy windows around the <br />high energy gamma ray emission peaks are used (Figure <br />7.4), barite does not affect the result while KCI will only <br />affect the potassium result and can be corrected for. But <br />when the low energy part of the gamma ray spectrum is <br />used, the barite effect on this pan of the specwm causes <br />an increase in thorium and decrease in uranium. KCl <br />causes an increase in the potassium (as to be expected) <br />but also a decrease in the uranium. Chars and computer <br />algorithms are available to correct for these errors but are <br />not entirely adequate since they are non-linear. <br />7.5 Geochemical behaviour of <br />potassium, thorium and uranium <br />and natural radioactivity <br />The old tenet that the gamma ra}' log is a 'shale log' was <br />based on its use as a black box, not understanding what <br />was inside. In modem interpretation an understanding of <br />the mineralogy and geochemistry leading to radiation is <br />used. Described below are the natural cecutrences of the <br />radioactive minerals and their geological significance. <br />Potassium <br />Potassium is both chemically active and volumetrically <br />common in naturally occurring rocks. Because of its chem- <br />ical activity it is generally chemically combined. In the <br />clay minerals, for example, it (and invariably its radioactive <br />isotope) occurs in the clay silicate structure. In evaporates it <br />occurs chetttically az a salt, and in rock-forming minerals, <br />such az the feldspars, it is again chemically combined in <br />the silicate structure. The behaviour of potassium can <br />therefore be considered in terms of chemical composition, <br />as can its contribution to radioactivity. <br />The potassium content of the clay mineral species <br />varies considerably. Illites contain by far the greatest <br />amount, while kaolinite has very little or none (Table <br />7.8). The consequence of this is that clay mixtures with <br />a high kaolinite or high smectite content will have lower <br />potassium radioactivity than clays made up essentially <br />of illite (mica) (Figure 7.1 ). However, since most clays <br />are mixtures of several clay minerals, the differences <br />discussed above are muted. The averaee shale has a <br />potassium content of about 2% - 3.5% (Table 7.8). <br />Potassium is present in man}' rock-forming minerals <br />besides the micas, considered above as clay minerals. <br />The most important of these are the feldspars. Microcline <br />contains approximately 16% potassium by weight, and <br />orthoclase approximately 14%; such percentages render <br />the feldspars highly radioactive in geological terms (see <br />Table 7.15). Fzldspathic sediments ma}' therefore be <br />detected by their radioactivity. <br />Finally, potassium is found in some of the less commonly <br />occurring evaporates but in sufficient quantities to have an <br />74 <br />I, , <br />