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• 2- sulfate reducing <br />S04 + LN4 (organic matter) bacteria ~- <br />HS + HC03 + HZO (8) <br />Depending on the hydrological, geochemical, and biological processes that predominate in <br />an area, the ground water can be of a calcium magnesium bicarbonate, sodium bicarbonate, <br />calcium magnesium sulfate, or sodium sulfate type. <br />Site Specific Grountl Water Quality. The fo]lowing section discusses the results of <br />chemical analyses for ground water samples collected within and adjacent to the Nucla antl <br />Nucla East mining areas. The monitor well locations are presented on Exhibit 7-1. <br />Water quality samples are collected by Peabody Coal Company personnel using a submersible <br />pump. Volumes of water pumped prior to sampling, fieltl water chemical analyses, <br />calibration of field meters, field water sample preservation and handl~i ng procedures, and <br />laboratory analytical procedures are described in detail in Tab 15, Hydrologic Monitoring <br />Program, <br />• I <br />h <br />f <br />ll <br />t <br />di <br />i <br />if <br />i <br />li i <br />i <br />th <br />i (N <br />I <br />d <br /> n t <br />e <br />ow <br />ng wa <br />er qua <br />ons, aqu <br />ers <br />o <br />ty <br />scuss ng areas <br />n <br />e two m <br />n a an <br />UC <br /> Nucla East) comprising the Nuc1a Mine will be discussed separately se that any <br />significance of the mining disturbance at the Nucla mining area can be separated from the <br />undisturbed setting at the Nucla East mining area. Because of the significance of the <br />irrigation water on the local ground water hydrology, an attempt is made to separate <br />irrigation period effects from non-irrigation period effects. Additionally, any seasonal <br />variability irrespective of irrigation periods is addressed. Data presented for trace <br />elements is limited to the period from 1985 to the present, because of the questionable <br />nature of the chemical data from earlier analyses. A further qualifier is that lead <br />levels above the detection limit, even after 1985~are ignored, because the only measurable <br />values all occurred on the same date in 1986 and measurable levels have not been detected <br />since. Thus, the 1986 values are considered lab errors. The special chemical parameters <br />(Be, Co, Li and V) required under ground water agricultural standards from the Colorado <br />Water Quality Control Commission were analyzed for exclusively in the Nucla East mining <br />area and the one Nucla mining area spoils well. <br /> Nucla Mining Area. One monitoring well in the Nucla mining area, CW-N9 is multiply <br />• completed in bath the overburden and Dakota coal aquifers. A statistical summary of the <br />7-30 Revised 04/11/88 <br />