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Each borehole is capable of discharging up to 500 or 600 gpm of mine water. Dischazge through the boreholes will <br />occur on an alternating basis, with the potential of discharging simultaneously. The chemistry of the mine <br />discharge has changed so that the primary focus of the treatment is for iron removal. In order to accomplish this, <br />. the pH of the mine discharge must be raised to a range of 8.8 to 9.0. Sodium hydroxide was used for several years <br />to raise the pH and drop-out the iron in settling ponds, in order to meet the 0.5 mg/1 total recoverable iron limit in <br />CDPS Permit No. CO-0042161. <br />The as-built drawing for the system is presented in Exhibit 8K and based upon the survey data. The storage <br />capacity of each cell was calculated. Pond 1 (west cell) has a capacity of 374,728 gallons, Pond 2 has a capacity of <br />348,533 gallons and Pond 3 (east cell) has a capacity of 277,008 gallons. The total capacity of all three ponds is <br />1,000,269 gallons. The flow rate for varying detention time is as follows: <br />TIME (hrs) <br />• <br />FLOW RATE <br />(gpm) POND 1 <br />(374,728 gallons) POND 2 <br />(348,533 gallons) POND 3 <br />(277,008 gallons) TOTAL <br />DETENTION <br />300 20.8 19.4 15.4 55.6 <br />350 17.8 16.6 13.2 47.6 <br />400 15.6 14.5 11.5 41.6 <br />450 13.9 12.9 10.3 37.1 <br />500 12.5 11.6 7.2 31.3 <br />750 8.3 7.7 6.2 22,2 <br />1000 6.2 5.8 4.6 16,6 <br />1250 5.2 4.8 3.8 13.8 <br />ACZ Laboratories, Inc. conducted a titration study on the mine discharge and showed that raising the pH to 9 would <br />provide an effluent concentration of 0.63 mg/1 of the total recoverable iron after 12 hours and a concentration of <br />0.21 mg/1 at 24 hours. TCC has operated the system and has achieved compliance with its discharge permit for <br />total recoverable iron by maintaining the pH at 8.8 to 9.0 in the discharge. At a pH of 10, the total recoverable iron <br />was reported at 0.01 mg/1 after 12 hours and at 0.01 mg/1 at 24 hours. This shows that by elevating the pH, the iron <br />will precipitate at a faster rate. TCC used this information as a starting point and then fine-tuned it at the site. At <br />higher flows, TCC would be required to apply additional sodium hydroxide to achieve the same pH level. <br />The settling cells (impoundment) were constructed prior to discharge of underground mine water at the Fish Creek <br />Borehole Area. It consists of three adjacent cells, each measuring 123 feet by 37 feet, with a final depth of eight (8) <br />feet. Typically, a I S foot light duty road courses around the entire structure and on the berms separating the cells. <br />The sodium hydroxide is presently housed in the Electrical Control Building along with the metering pumps used to <br />inject the sodium hydroxide into the mine discharge. A third portable structure will be located adjacent to the <br />Electrical Control Building for more efficient storage and handling of the NaOH a chemical feed line extends from <br />the metering pumps in the Electrical Control Building to the east cell of the impoundment, near the outlet of the <br />borehole pump discharge line. An aerator has been placed downstream of the inlet into the pond so that the sodium <br />hydroxide is dispersed throughout the cell, promoting the precipitation of~ron from the mine dischazge water. <br />The water flow through the cells was modified to take advantage of additional retention time in the system. The <br />original flow path focused on using two of the three cells at any one time. Presently, all three cells are used and this <br />required installation of a new inter-pond line between the center and western cell. The baffles in the cells reduce <br />• the potential for short-circuiting, increasing the efficiency of the ponds. The final component added to the system <br />MR06-207 2.05-77 04/25/06 <br />