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GENERAL47956
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Last modified
8/24/2016 8:23:30 PM
Creation date
11/23/2007 3:58:14 PM
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Template:
DRMS Permit Index
Permit No
M1988112
IBM Index Class Name
General Documents
Doc Name
THE RECOVERY OF CYANIDE FROM SLURRIES
Media Type
D
Archive
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Pags d <br />coarse bubble diffusers slmplined the process, while maintaining process pedormance. Total cyanide levels <br />were routinely reduced Irom an average of 330 mg/I to less than 2.0 mg/l. <br />Also In the mid-1980's, Investlgatlons were conducted at the Noranda Research Center aimed at designing <br />a cyanide recovery. process employing packed towers and plastic, media Q). Stripping towers slgn~cantly <br />reduced the surface. area required for the~CVR process, as well as the horsepower requirements due to the <br />reduced pressure losses through the system. Employing Information derived In a bench-scale study, a ~,,.~- <br />contlnuous flow pilot plant system was designed and operated. The data obtained In the pilot study was ~" ', <br />util'¢ed In the development of a design for afull-scale stripping system to treat about 2,000 rt'/d of barren 1, ~ ! <br />solution, utilizing an air to Iiguld ratio of 330. 1'- k <br />IZo~ <br />The pilot plant evaluations Indicated the total cyanide levels could be reduced from about 4,000 mg/I to <br />about 720 mg/1, for an overall removal efficiency of 97 percent. The stripped cyanide was reabsorbed In <br />a second packed tower using a counter current caustic sdu[lon. The process empoyed a pH of 2.5 and <br />t~ considerable precipitation of copper thiocyanate and calcium sulfate was realized. It was noted that the <br />precipitated solids would eventually reduce the stripping efficiency, and mechanical cleaning of the media <br />would be necessary and difficult. The study demonstrated that use of modern mass transfer te~:hnology and <br />materials could be employed In the removal and recover of cyanide from clarified barren solutions <br />A full-scale packed tower cyanide recovery system was designed and operated from 7985.1987 by Golconda <br />Engineering and Mining Services at the Beaconsfield Gold Mine In Tasmania (B). The proces~t was termed <br />the C.R.P. or Cyankle Regeneration Process. Initially, a continuous flow pilot plant operation was conducted <br />to establish the appropriate air to liquid ratio, stripping time, and caustic requirements for the absorber. The <br />full-scale facility was-dgs_igned to treat y20Q-_lonr~g$/Q.af~arified barren water using a systen of multiple <br />packed aeration towers. A schematic of the full-scale facility Is presented in Figure t. -~' <br />`,. <br />The plant was designed using the most modern mass transfer technology, plastic media, and cyanide <br />monitoring equipment. The system was designed for maximum safety incorporating an enclosed negative <br />pressure system. Fan exhausts were monitored routinely for HCN with typical values of <7.0 rt,g/m', which <br />were t J70 of the 8-hour 10.0 mg/m' TLV for free cyanide. Cyanide recoveries of nearly 95 percent were <br />reported in the full-scale system. <br />recovery systems. <br />The various laboratory, pilot plant, and IuII-scale cyanide recovery facilities described have demonstrated <br />that application of mass transfer technology coupled with state-of-the-art monitoring equipment and <br />engineering design approaches can be employed In the construction and operation of full-sale cyanide <br />urries and the lack of adeau;it@materlals_and~quipm~r)I. <br />_~ <br />J,ruN-" <br />-ery proces:~can not ba <br />cal properties of lo- w pH._ <br />IfCi~ <br />- Since 7985, an Intensive research effort has been undertaken to expand the capabilities of tha process to <br />slurries, while minimizing the chemical and mechanical problems associated with past systems. The work <br />involved both detailed laboratory and continuous flow pilot plant evaluations conducted for Cyarus Gold of <br />New Zealand, to develop and design the first full-scale commercial cyanide recovery system for tailings <br />slurries to be Installed at the proposed Golden Cross Mine near Walhi, New Zealand. <br />Based on the test results, afull-scale cyanide recovery system utilizing packed towers would be built to treat <br />200 m'/hr of a 35 percent tailings slurry from a WAD cyanide level of 200 mgt less than to mg/I. The 'i ;~ <br />commercial cyankie recovery process <br />Is known as the Cyanlsorb Process. <br />applications <br />and a patent Is pending <br />
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