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Page 2 <br />The excess sdullons and sdlds are normally disposed of In an Impoundment. Several potential problems <br />may result from disposal Including contamination of groundwater, exposure of wBdlile and water fowl to <br />elevated cyankfe concentrations, and Impacts on surface water environments fdlowing discharge of treated <br />or untreated effluents. <br />The're' Is a need to mitigate these problems, and to minimize potential adverse environmental Impacts. The <br />conventional approach IrnoNes treatment df mflI tailings or decant sdutlons and lining of Impoundments, <br />whle Ignodng the options assxlated whh•recyde of process sdutlons and reagents. The capital and <br />operating costs of wastewater treatment and tailings disposal are substantial and often dictate the economic <br />viability of a mining project. Treatment costs are Increasing sharply due to more stringent environmental <br />regulations and the need for more sophisticated and advanced techndogies. <br />In conjunction with treatment and solid waste disposal costs, are the rapidly Increasing costs of water and <br />reagents, particularly cyanide. The cost of cyanide has risen sharply due to world-wide demands and <br />shortages. The spot•market price for cyanide In certain Instances Is several times higher than the average <br />price. The cost of cyanide is a primary concern in remote areas where cyanide availability is limited. <br />As a result, every attempt must be made to reduce reagent consumption through recycle anc' recovery to <br />minimize the costs of production and of environmental protection. One excellent approach Invdves recovery <br />and recycle of cyanide from process solutions and slurries. Historically the process, termed acidification, <br />vdatilization, and reneutralization or AVR, has been employed In the recovery of cyanide f•om clarified <br />barren or decant soutions. <br />Although cyanide recovery has been employed In the full-scale recovery of cyanide Irom sclutions, only <br />recently has considerable Interest In the process resurfaced, particularly for application with tailings slurries. <br />This paper describes In detail the history, chemistry, applications, advantages, and costs of various cyanide <br />recovery processes. <br />Emphasis is placed on the development of the Cyanisorb Process for recovery of cyanide from ;slurries. This <br />process has been tested and proven through an extensive pilot plant evaluation for application at Cyprus .. <br />Gdd's proposed Gdden Cross Mine In New Zealand, and would represent the first full-scale application of <br />cyanide recovery from slurries. <br />t.' . . <br />HISTORY OF CYANIDE RECOVERY PROCESSES <br />The recovery of cyanide from mining solutions through acidification, air stripping, and reabs.orption was <br />_ originally known as the M1Ie Crows Process (f}. The process Involved acidifying clamed barren sdution,~~•'_ " • . _ , <br />then strlpping the HCN formed and reabsorbing h from the air stream wkh a caustic or m1k d lime spray. <br />The process was employed at the Flin Flon Mine operated by Hudson Bay Smelting and Mining Company <br />' from about 1930.1975 (2,3}, The Canadian mining operation Invdved cyanidation of gold bearing talings <br />originating from the flotation of a copper•zinc ore. To condition the barren solution for stripping, the pH was I ~, <br />first adjusted downward to 2.5 with sulfuric acid supplied from the zinc electrdytic plant. <br />The acidified soution was then passed through a series of four strlpping towers packed with w~~oden grids. <br />The towers were constructed of concrete and measured about 5m x 2m x 7.Sm In height. The stripping <br />towers were operated In a series, each connected to one of lour concrete absorption tunnels by means of <br />closed loop recycled air streams. <br />The air and liquid vdumes In each strlpping loop were about 56,000 m'/hr and 1D7 m'/hr, resulting In an <br />air to I(quid ratio of about 525/1. The HCN entrained in the air stream was reabsorbed by ccntacting the j ~ <br />air stream with time slurry sprays and recollected In a central storage tank. The stripping process required <br />