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GENERAL46371
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Last modified
8/24/2016 8:19:20 PM
Creation date
11/23/2007 2:34:16 PM
Metadata
Fields
Template:
DRMS Permit Index
Permit No
M1977208
IBM Index Class Name
General Documents
Doc Date
12/10/2002
Doc Name
Literature: Tire Fire Contingency Plan
From
CEMEX Inc.
To
DMG
Media Type
D
Archive
No
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list produced by the American Conference of Governmental Industrial Hygienists. The one <br />exception to this is that some of the carcinogenic polyaromadc hydrocarbons (PAHs) that were <br />in low concentration were not singled out. Coal tar pitch volatiles were used as representative <br />of the PAH class of chemicals. <br />The third step was to determine if a threshold limit value ('I'LV) exisu for the chemical. The <br />TLVs refer to airborne concentrations and represent conditions under which it is believed that <br />nearly all workers may be repeatedly exposed eight hours a day, five days a week, without <br />adverse health effects. TLVs are based on the best available information from industrial <br />experience, and experimental studies on humans and animals, and when possible, all three. It <br />should be noted that TLVs are guidelines or recommendations, not standards for determining <br />safe or unsafe conditions. If the detected value was greater than 33~ of the TLV, it became a <br />target chemical. Thirty-three percent of the TLV was used because the TLV is based upon a <br />typical work week (8 hours/day, 40 hours/week) and in the case of a rite fire, exposure could <br />be 24 hours per day. Tn cases where several types of a chemical were listed in the TLV book <br />(e.g., nickel, nickel carbonyl, nickel sulfide), a specific chemical was selected by determining <br />which was the most likely one to come from a fire fire and/or which had the lowest TLV. In <br />this report, TLVs were one of several indicators used to select target chemicals. <br />The fourth step was to compare the detected value to the subchronic (SC) and chronic (C) <br />inhalation reference concentrations (RfC). The RfC is an estimate of the daily exposure to the <br />human population that is likely to be without an appreciable risk of adverse effects during a <br />portion of the lifetime (subchronic) or during the lifetime (chronic). Sensitive populations are <br />taken into account. The RfC is based upon the No Observable Adverse Effect Level <br />(NOAEI,) or the Lowest Observable Adverse Effect Level (LOAEL), an uncertainty factor, <br />and a modifying factor. The RfCs are for continuous, 24 hours/day exposure, and are used as <br />reference points for gauging the potential effects of exposures. Usually, doses that are less <br />than the RfC ate not likely to be associated with health risks. As the frequency of exposures <br />exceeding the RfC increases, and as the size of the excess increases, the probability increases <br />that adverse health effects may be observed in a human population. Like the TLV, the RfC is <br />not meant to be a standard or give a definitive statement about safe and unsafe conretttrations. <br />However, it is appropriate to use it in this case when choosing target chemicals. <br />The fifth step was to list the chemicals in order of decreasing value and to take the top 25% of <br />the chemicals from each data set. If a chemical had not already been targeted as a carcinogen <br />or one that exceeded the RfC or 33% of the TLV, a review of the chemical was conducted. <br />The toxicity and the concentration were evaluated and a decision was made as to whether or <br />not it should be selected as a target chemical. If no information could be found, the chemical <br />was not included as a target chemical. <br />It should be noted that if a range was reported in the EPA or Acurez data set, the maximum <br />value given was the value used during the se]ection process. It should also be noted that this <br />approach was not meant to provide an all inclusive description of the emissions from a fire <br />fire, rather, it was used to select the most likely chemicals that are released from fire fires. As <br />a check, the list of target chemicals was compared to actual fire fire data from a variety of <br />2 <br />
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