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GENERAL37354
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Last modified
8/24/2016 7:57:31 PM
Creation date
11/23/2007 9:07:17 AM
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Template:
DRMS Permit Index
Permit No
M1980244
IBM Index Class Name
General Documents
Doc Date
11/1/1994
Doc Name
REVIEW ACID BASE POTENTIAL OF CRESSON MINE OVERBURDEN CRESSON PROJECT M-80-244
Media Type
D
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<br />That is all. There is no proposal to protect surface or groundwater from contamination, even <br />though the leach tests indicate that the waste rock ("overburden") has the potential to generate acid <br />and metals in concentrations exceeding water quality standards. Thus, the proposal outlined above <br />cannot meet the requirements of the Amendment 6 Commitments to which it is meant to apply. <br />SUMMARY: Executive Summary <br />We would advise the Division not to accept the proposal outlined in the Executive Summary. <br />INTRODUCTION <br />Section 4, on background chemistry, provides several disingeneous formulas meant to represent <br />the notions of acid production and acid neutralization. The reaction of pyrite with water and oxygen <br />(reaction [1]) expresses only part of the potential for pyrite to produce acid. The reactions shown for <br />the attack of dolomite and calcite by acid are equilibrium reactions: one should not anticipate such <br />reactions in the weathering environment. Equilibrium thermodynamics should not be used to represent <br />the dissolution of minerals where the solutes can be expected to be carried away from the reaction site. <br />Simple addition of acid to carbonate minerals causes effervescence due to the generation of COZ. This <br />is not represented by the reactions shown. The reactions shown for K-feldspar and sericite dissolution <br />also are equilibrium reactions. The conversion of K-spar to sericite and quartz is a high temperature <br />reaction and cannot be used to depict the Cresson situation. The dissolution of sericite by hydrogen <br />ions and water (reaction [8]) is so slow as to be insignificant. Furthermore, because this is a charge <br />balancer! equilibrium reaction, it does not depict the fate of the potassium ion, and its potential effect <br />on metal acidity. In reality, the addition of sulfuric acid to feldspars and micas in natural open <br />systems, if solution pH is low enough, will release potassium, aluminum and silica to solution. <br />Dissolved Al', at least, may cause problems for aquatic life. <br />SUMMARY: Section 4. The section on background chemistry does not correctly represent <br />the weathering environment at Cresson, and should not be consulted for predictive purposes. <br />The better predictive tests are the acid generation and acid neutralization tests themselves. <br />Section 5.1 states that the 2 deep cores are "representative" of the entire diatreme at depth. <br />The text states also that the cores contain 3 to 6 % carbonate, even though the cazbonate minerals were <br />not identified. These statements are not adequate, as expressed in the DMG's reviews of Amendment <br />6 submittals. Firstly, there is no rational statistical reason to accept that two cores into the deeper part <br />of the diatreme are representative of the entire minerlized portion of the diatreme. Secondly, there <br />is only anecdotal justification -based on a 1906 report -for the notion that the 3-6% of unidentified <br />minerals in the cores are carbonates rather than something else. Following that, if the 3-6% of <br />unidentified minerals were cazbonates in fact, at those abundances they should have shown up on the <br />mineralogical exams. X-Ray Diffraction analyses could easily identify carbonates in concentrations <br />of perhaps 2%. <br />This section also states that jarosite will encapsulate the pyrite crystals and inhibit weathering. <br />This is highly unlikely as jarosite is extremely soluble. Jarosite will release ferric iron and actually <br />promote pyrite solution and acid generation. <br />Section 5.2 states that there is very little potential to generate acid from rocks in the oxidation <br />zone. This is not correct. CC&V's classification of rocks into "oxide," "transitional" and "sulfide" <br />zones reflect an empirical average of pyrite content and other mineralogy. However, it is recognized <br />
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