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The operator shottld describe how acid generated in the upper part of the diatreme will be <br />neutralized by cm•bonates in the deeper part of the diatreme if groundwater moves <br />domitrartth~ throtegh discrete fractures Lather than more homogeneously through the breccia <br />and other ut:jractured rock.. <br />2. Appendix A. <br />The static test data in App A accompany no explanation of how samples were measured. It is <br />presumed for purposes of this review that the tests measured the following: <br />a. total sulfur <br />b. sulfide sulfur <br />c. sulfate sulfur <br />d. organic (non-extractable) sulfur -calculated by difference <br />e. ANP by titration or some presumption of titrable alkalinity <br />If these pres:tmptiotrs are ittcon•ect, the Operator should inform the Division of such, <br />providing a explanation of the analytical procedures used for these analyses. <br />Proceeding as if the above presumptions aze correct, it appears the methods may <br />underestimate AGP that might be generated in the field while overestimating field-available <br />ANP. To wit: <br />AGP. Sulfate sulfur analyses include minerals such as the Ca-SO4 family of minerals, <br />which would be non-acid generating, and the jazosite-alunite family ofminerals -hydrous <br />metal sulfate evaporites -which could be variously acid-generating. <br />The Operator should describe the methods by which sulfate species were identified and <br />provide evidence that the jarosite-alunite family ofinetal-sulfate hydrates were <br />adequately accounted for in the calcttlatiot: of AGP. <br />ANP. The ANP method is not stated. For the system at hand, considering the <br />mineralogical composition of the diatreme described in Lindgren and Ransome, it is noted <br />that ANP calculations based on carbon and sulfur, whereby the carbon is total carbon <br />assumed to be either calcite or dolomite and total sulfur values is assumed to be sulfide sulfur <br />would be a preferable method. <br />Tl7e Operator should describe the AGP and ANP methods used fot• the static tests given <br />in Appendir A. If the carbonate minerals it:clttde an appreciable percent of either <br />siderite or ankerite, the ANP should be adjusted accotdit:gly. If total carbon tests were <br />run, and if the rock contains carbon species other than carbonates, those should be <br />t•epot•ted. If the test methods employed titt•atiotts or other ttetttralization reactions that <br />x~ould include silicate bujferit:g, the ANP values should be re-examined. Absent this, the <br />Operator shottld address the question it: a narrative or in further calculations showing <br />that, high estimated NNP values aside, the system still will be able to minimize impacts to <br />the hvdrologic balance. <br />