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-` <br /> <br /> <br /> <br /> <br />1 <br />'( <br />1 <br /> <br />1 <br /> <br />1, :. ,. <br /> <br /> <br /> <br /> <br /> <br /> <br />~... -.. . <br />..~ .. . <br /> <br />Page 10 <br />d WAD and total cyanide to ferveis in the ranged 5-20 mg/I. By lowering the level of metals sand cyankfe <br />requiring downstream treatment, lower effluent levels can be reached. . <br />The Impoundment Into which the fallings are discharged should he designed to enhance cyanke <br />degradation, thereby minimizing downstream treatment requirements. If downstream treatment of decant <br />water is required prior to discharge to a surface water, conventional chemical or bidoglcal treatment should <br />be 'employed as these processes are'best •suRed for this purpose. The use of chemical or bldoglcal <br />treatment for slurries is unwarranted or imp~actlcal Inmost cases from both an environmental a fid economic <br />standpoint. The next section details the approach taken by Cyprus Gdd to develop the first full-scale <br />cyankfe recovery process for the tailings slurry at the proposed Gdden Cross Mine. <br />Bench and Pilot Plant Scale Investigations <br />A series d bench scale laboratory tests were first utilized In the study of cyankle recovery from slurries. A <br />schematic d the laboratory apparatus Is presented on Figure 4. The slurry utilized was olptained from <br />associated metallurgical tests. The chemistry of the fallings slurry and the expedmental results a je presented <br />In Table 6. The pH of the slurry was lowered Into the proper range wfth sulfuric acid, utilizing a 2.0-hour <br />stripping period, arxi reneutrallzatlon wfth Ifine to a pH of about 9.5 - t0.0. <br />TABLE B <br />CHEMISTRY OF TAILINGS SLURRY BEFORE AND AFTER CYANIDE RECOVEfgY <br /> Belore After C anfd Recove <br />Parameter t't Cyanide Recovery Trial 1 Tr al 2 <br />pH (In pH units) 10.4 9.7 1 d.2 <br />Total Alkalinity (as CaCO,) 575 170 169 <br />Total CN- 218 29.4 24.6 <br />WAD CN- 213 7.4 8.8 <br />Total Hardness (as CaCO,) 307 2170 203q <br />Sulfate 360 2525 2350 <br />SCN 34 37 38 <br />A5 0.8 0.6 0.7 <br />Ca 123 869 814 <br />Cd <0.01 <0.01 <q.01 <br />cr o.02 <0.02 <aoz <br />Co 0.16 0.33 a30 <br />CU 4.7 6.0 6t1 <br />Fe 1.3 8.7 6.7 <br />Pb <0.1 <0.1 <a1 <br />Mn 0.01 0.02 0102 <br />Hg 0.0155 0.0004 010001 <br />Ag 0.15 0.04 0104 <br />Zn 0.64 0.01 0106 <br />Alr Flow (L/min) ------ 80 100 <br />t'~ All values In mg/I, unless otherwise stated. <br />These experiments completed al the Department of Science and Industrial Research (DSIR) Irv Wellington, <br />New Zealand, were conducted to verify the ef(ectNeness of the process, but not to optimize chemical usage <br />or obtain design Information. The results indicated that WAD cyanide levels of 218 mg/I could be reduced <br />