2004-12-01_REVISION - M1977208 (2)

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5. FIRE-FIGHTING MEASURES (Continued) FIRE EXTINGUISHING MATERIALS: Carbon Dioxide is commonly used as an extinguishing agent, and therefore, should not present a problem when trying to control a blaze. Use extinguishing media appropriate for sunounding fire. UNUSUAL FIRE AND EXPLOSION HAZARDS: Carbon Dioxide does not bum; however, containers, when involved in fire, may rupture or burst in the heat of the fire. Dusts of various reactive metals (e.g. magnesium, zirconium, titanium alloys), are readily ignited and explode in the presence of Carbon Dioxide. Mixtures of solid Carbon Dioxide with sodium and potassium alloys are impact sensitive and explode violently. In the presence of moisture, cesium oxide ignites on contact with Carbon Dioxide. Metal acelylides or hydrides will also ignite or explode. Explosion Sensitiviri to Mechanical Impact: Noi sensitve, except as rrofed above. Explosion Sensitiviri to Static Discharge: Not Sensttive. SPECIAL FIRE-FIGHTING PROCEDURES: SWcturelfin-fighters must wear SetF-Contained Breathing Apparatus and full protective equipment. Move fire-exposed cylinders 'rf it can be done wittaut risk to firefighters. Otherwise, cool containers with hose stream and protect personnel. Withdraw immediately in case of dsing sounds from venting safety device or any discoloration of tanks due to the fire. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and protect people. Minimum Personal Protective Equipment should be Level B: protective clothing, mochantcally-resistant gloves and SeH-Contained Breathing Apparatus. Locate and seal the source of the leaking gas. Allow the gas, which is heavier than air, to dissipate. Monitor the surrounding area for Carbon Dioxide and Oxygen levels. Colorimetric tubes are available for Carbon Dioxide. The levels of Carbon Dioxide must be below those listed in Section 2 (Composition and Infonnation on Ingredients) and the atmosphere must have at least 19.5 percent Oxygen before personnel can be allowed in the area without Self-Contained Breathing Apparatus. Attempt to close the main source valve prior to entering the area. If this does not stop the release (or U it is not possible to reach the valve), allow the gas to release in-place or remove it to a safe area and allow the gas to be released there. RESPONSE TO LIQUID RELEASE: Releasing liquid will immediately tum to dry ice. Clear the affected area and allow the solid to evaporate and the gas to dissipate. Clean up the solid as detailed below. Atler the gas is formed, follow the instructions provided in the previous paragraph. If the area must be entered by emergency personnel, SCBA, Kevlar gloves, and appropriate foot and leg protection must be wpm. RESPONSE TO SOLID RELEASE: Pick-up and immediately place solid pieces of dry ice in an appropriate, thermally- insulated, vented container. Alternatively, allow the solid to sublimate and the gas that is generated to dissipate. PART III How can 1 prevent hazardous situations from occuning9 7. HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting Carbon Dioxide IN YOU. Do not eat or drink while handling chemicals. Be aware of any signs of dizziness, fatigue, or any exposure symptom described in Section 3 (Hazard Identfication); exposures to fatal wncentrations of Carbon Dioxide could occur wUhout any sgnifcant warning symptoms. STORAGE AND HANDLING PRACTICES: Cylinders should be stored in dry, well-ventilated areas away from sources of heat. Containers of Carbon Dioxide can present significant safety hazards. Store containers away from heavily trafficked areas and emergency exits. Store containers away from process and production areas, away from elevators, building and room exits or main aisles leading to exits. Containers should be stored in dry, well-ventilated areas away from sources of heat, ignition and direct sunlight. Protect containers against physical damage. Isolate from other non-compatible chemicals (refer to Section 10, Stability and Reactivity). SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Protect cylinders against physical damage. Store in cool, dry, well-ventilated, fireproof area, away from flammable materials and corrosive atmospheres. Store away from heat and ignition sources and out of direct sunlight. Do not store near elevators, corridors or loading docks. Do not allow area where cylinders are stored to exceed 52°C (125°F). Use onty storege containers and equipment (pipes, valves, fittings to relieve pressure, etc.) designed for the storage of Solid, Gaseous or Liquefied Carbon Dioxide. Do not store containers where they can come into contact with moisture. CARBON DIOXIDE • CO= MSDS (bocuur~urrrootot3l PAGE 5 OF 12