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3. HAZARD IDENTIFICATION (Continued) <br />OTHER POTENTIAL HEALTH EFFECTS: Contact of the cold gas with the skin can lead to frostbite or dermatitis (red, <br />cracked, irkated skin), depending upon concentration and duration of exposure. Contact of the cold gas with the eyes can <br />cause pain, redness, bums, and severe exposure could cause blindness. Symptoms of frostbite include change in skin <br />color to white orgrayish-yellow. The pain after contact with cold gas pn quickly subside. Moisture in the air could lead to <br />the formation of carbonic acid, which can be irritabng to the eyes. <br />HEALTH EFFECTS OR RISKS FROM F-XPOSURE: An Explanation in Lav Terms. Overexposure to Carbon Dioxide may <br />cause the following health effects: <br />ACUTE: Inhaling high concentrations of Carbon Dioxide can lead to coma or death. At low concentrations, inhalation of <br />Carbon Dioxide can cause nausea, dimness, visual disturbances, shaking, headache, mental confusion, sweating, <br />increased heartbeat, and elevated blood pressure and respiratory rate. High concentrations of the gas in air may cause <br />eye irritation or damage. <br />CHRONIC: Reversible effects on the aad-base balance in the blood, blood pressure, and circulatory system may occur <br />after prolonged exposure to elevated Carbon Dioxide levels. <br />TARGET ORGANS: Respiratory system, cardiovascular system, eyes. <br />Calton Dioxide Solid <br />EMERGENCY OVERVIEW: Solid Carbon Dioxide (dry ice), is a white, opaque solid which releases cobdess, <br />gas. This solid sublimates to gas quickly at standard temperatures and pressures, forming a fog in air. As a result, the <br />main hazards assodated with Carbon Dioxide are related to Carbon Dioxide gas formation and the cold temperature of <br />the solid and evolved gas. At concenrations between 2 and 10%, Carbon Dioxide pn cause nausea, dizziness, <br />headache, mental confusion, increased blood pressure and respiratory rate. If the gas concentration reaches 10°~ or <br />more, suffocation and death can occur within minutes. Contact with the solid can puss freezing of exposed tissue. <br />Moisture in the air could lead to the formation of carbonic acid which can be irritating to the eyes. Carbon Dioxide is <br />heavier than air and should not be allowed to accumulate in low Ivina areas. <br />SYMPTOMS OF OVEREXPOSURE BY ROUTE OF FJCPOSURE: The <br />most significant routes of overexposure for Carbon Dioxitle are by <br />inhalation of Carbon Dioxide gas, and skin or eye contact with the solid <br />or gas. Symptoms of such exposure are as follows: <br />INHALATION: Carbon Dioxide is an asphyxiant and a powerful cerebral <br />vasodilator. If the concentraton of Carbon Dioxide reaches t0% or <br />more, suffopfion can occur rapidly. Inhalation of concentrations <br />between 2 and 10% can puss nausea, dizziness, headache, mental <br />confusion, increased blood pressure and respiretory rate. Carbon <br />Dioxide initially stimulates respiration and then puses respiratory <br />depression. Inhalation of low concentrations (3-5%) have no known <br />permanent harmful effects. Symptoms in humans at various levels of <br />concentration are as follows: <br />CONCENTRATION SYMPTOMS OF EXPOSURE <br />1%: Slight increase in breathing rate. <br />2%: Breathing rate increases to 50% above <br /> normal; exposure puses headache, <br /> tiredness. <br />3%: Breathing increases to twig normal rate and <br /> becomes labored. Weak narcetic effect. <br /> Impaired hearing, headache, increase in <br /> blood pressure and pulse rate. <br />4-5%: Breathing increases to approximately four <br /> times normal rata, symptoms of inloxicetion <br /> become evident; slight choking may be felt. <br />5-10%: Labored breathing, headache, visual <br /> impairment, ringing in the ears, impaired <br />CARBON DIOXIDE SOLID <br />FIATPRODl1S MATERIAL II~OnAlATON <br />S1fSIEM <br /> HEALTH ~,E, z <br />~FLAMMABILIIY ~> D <br /> <br /> REACTIVITY ~ e <br /> PROTECTIVE EQUIPMEfYf B <br /> ~s r~s.m,rR. Twos ems <br /> ~ <br />Sa;tion 8 ~ ~ <br />Section 8 <br />For routine iMrsldal applicasas <br />judgment, followed by loss of gee Section 16 for Definition of Ratinms <br />wnsciousness. <br />50-100%: Unconsciousness occurs more rapidly above 10% level. Prolonged exposure to high <br />concentrations may eventually result in death from asphyxiation. <br />CARBON DIOXIDE - CO= MSDS (DOCUMENT aootot3) PAGE 3 OF 12 <br />