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Mrs. and Mr. Topper <br />M-1999-034 <br />February 2, 2005 <br />Page 2 <br />Division -Rocky Mountain Arsenal team, as well as Tri-County Health Department, indicate that <br />DIMP is highly soluble, and therefore not sinking or floating (neither a DNAPL nor an LNAPL), <br />especially at current RMA concentrations. The same contacts report that DIMP is not likely to <br />volatilize, as it is semi-volatile, and that it is fairly common to sample from irrigation (150 GPM) wells <br />without concerns for volatilization. <br />In the February 1, 2005, letter to Aggregate Industries, the Division clarified the Board Order's <br />requirement for a Monitoring Plan and elements that the Monitoring Plan must and should include. <br />When these items are addressed, it will simultaneously address any remaining monitoring plan <br />components noted in your October 22, 2003 letter. <br />The February 1, 2005, letter to Aggregate Industries also distinguishes the need to purge casing <br />volumes not borehole volumes and provides related calculation corrections. As we have discussed, <br />the pre-mining sample of the well will need to be repeated since the purge time was inadequate. <br />Use of a temporary inline flow meter for two well sampling events would be acceptable, but will not be <br />required by the Division. Since well and pump data is often lacking on wells sampled by TCHD, their <br />procedure is to purge wells for 45 minutes prior to sampling. In this case, well construction and pump <br />installation reports for this well from the Division of Water Resources have been used. Granted, <br />unless the pump has been replaced, it is 36 years old so its pumping capacity may have diminished. <br />However, at the time the pump was tested it delivered a constant yield of 70 GPM, but was and is <br />limited by the permit to 45 GPM. Unless you indicate otherwise, the Division will assume that a 45 <br />GPM flow rate is a low estimate, and suitable for well purge volume calculations. <br />In your December 7, 2004 a-mail, you expressed concern over "purging five boring volumes" due to <br />the waste of water and the electrical cost. Using this conservative estimate, the minimum purge time <br />is 12 minutes, much less than the 45 minutes called for in TCHD's procedures. <br />In your a-mail, you proposed that the Division review the sampling protocol per the U. S. EPA Region <br />Vlll Minimum Requirements for Field Sampling Activities. This e-mail has been forwarded to <br />Aggregate Industries, and they may propose to implement its provisions. As stated in the Division's <br />February 1, 2005 letter, "CDPHE's 'Ground-Water Permit Guidance Suggested Monitoring Well <br />Sampling Protocol' and Tri-County's extensive DIMP experience at the Rocky Mountain Arsenal and <br />targeted procedures more specifically and comprehensively address this particular analyte than any <br />others the Division has encountered. Therefore, their procedures are considered competent for our <br />purposes, as well. Lake sample collection per the Texas Commission on Environmental Quality's <br />(TCEQ, f/k/a TNRCC) 'Surface Water Quality Monitoring Procedures' is acceptable." <br />The CDPHE guidance is available online at <br />htto://www.cdohe.state.co.usJwa/PermitsUnit/GW Well Mon Guide.PDF <br />The Board Order does not require sampling separate surface water bodies. <br />The Findings of Fact in the State Engineer's Hearing Order Case No. 03-SE-08 stated that Well No. <br />32883 "cannot legally operate unless it is included in acourt-approved plan for augmentation....and <br />therefore, the well cannot legally operate at this time." Pursuant to a conversation between Mr. <br />Topper and me in November 2004, Mr. Topper was going to obtain a letter from the State Engineer's <br />Office ("SEO") authorizing pumping the well for sampling purposes. I advised providing the request, <br />in writing, to Jeff Deatherage of the SEO. The Division has still not seen the request or the SEO <br />letter. I have since spoken with the SEO, and as long as the pumped water is not put to beneficial <br />use, the well can be pumped solely for water quality monitoring purposes. <br />