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TABLE 3. BOIL-SMP BUFFER pH AND CORRESPONDING LIME RDQUIRFMSNT (L.R.} <br />TO BRING MATERIAL TO pH 6.5" <br />L.R. L.R. <br />pH (Tons/1000 Tons)~• pH (Tons/1000 Tons)~'e <br />6.9 0.3 5.8 8.1 <br />6.8 1.0 5.7 8.9 <br />6.7 1.8 5.6 9.6 <br />6,6 2.4 5,5 10.4 <br />6.5 3.1 5.4 11.1 <br />6.4 3.9 5.3 11.7 <br />6.3 4.6 5.2 12.5 <br />6.2 5.3 5.1 1:3.2 <br />6.1 6.1 5.0 14,0 <br />6.0 6.0 4.9 14.7 <br />5.9 5.9 4,8 15.5 <br />Adapted from Shoemaker, McLeea, and Pratt, 1962. <br />•~Agricultural ground limestone TNP at least 90x. <br />3.2.10.6 Calculations-- <br />Determine lime requirement from Table 3. <br />3.2.11 Total Sulfur Estimation Bs Peroxide Oxidation <br />3.2,11,1 Princivles- <br />Pyritic minerals begin to change into two new products when exposed to the <br />atmosphere. The change may proceed slowly over a long period of tine <br />before the final products (yellavboy and sulfuric acid) are formed. The <br />sad product, "yellawboy," actually may form only when the eulfnte is <br />partially or completely neutralized by a basic substance. The chemical <br />equation for this complete chmge in pyrite follows: <br />69 <br />