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STATE OF COLORADO <br />DIVISION OF MINERALS AND GEOLOGY <br />Department of Natural Resources <br />1373 Sherman St., Room 215 <br />Denver, Colorado 80203 <br />Phone: (303) 866-3567 <br />FAX: (303) 832-8106 <br />COLORADO <br />DIVISION O F <br />MIN ORALS <br />GEOLOGY <br />RECLA MAiION•MIN ING <br />SAFETV•SCIEN<E <br />Bll QWPns <br />Governor <br />DATE: October 6, 2004 Russell George <br />Executive Direaar <br />TO: Erica Crosby Ronald W. Cattany <br />Division Director <br />Natural Resource Trustee <br />FROM: Allen Sorenson <br />RE: Review of the Proposed Ground Water Monitoring Plan, American Soda, L.L.P., Yankee <br />Gulch Sodium Minerals Project, Technical Revision TR-004, Permit No. M-1999-002 <br />In establishing the original Numeric Protection Levels (NPL) and Early Warning Indicators (EWI) <br />through technical revision TR-002, American Soda used the Dixon method to identify outliers at the <br />upper end of the data sets. If outliers were present, they were rejected and the NPL or EWI was <br />established at the highest detected level that was not an outlier (unless that highest detected level was <br />below a table value standard (TVS), in which case the TVS was selected as the NPL or EWI). This <br />practice has not been regulatorily effective; review of appendix B to TR-004 shows that numerous NPLs <br />and EWIs have been exceeded during the production period, even though there is little reason to think that <br />process water has contributed contaminants to the water being sampled. In other words, the natural <br />fluctuations in ground water chemistry result in concentrations of certain constituents that are higher than <br />the NPLs and EWIs for those constituents. DMG and American Soda must establish NPLs and EWIs in a <br />way that if exceeded, it will be a rather more clear indication of process water influence. <br />Suggested Method to Calculate NPLs and EWIs for Approval of TR-004: <br />Use the 15-month baseline data set and the Dixon calculation to determine the cutoff concentration is for <br />what would or would not be an outlier, and establish the EWIs and NPLs at that cutoff concentration for <br />the pazameters selected for on-going monitoring. <br />ca Carl Mount, DMG (via email) <br />c:~acs\LOANER MACHME\My Documentslam soda tr4.doc <br />Office of Office of Colorado <br />Mined Land Reclamation Active and Inactive Mines Geological Survey <br />