My WebLink
|
Help
|
About
|
Sign Out
Home
Browse
Search
ENFORCE26625
DRMS
>
Back File Migration
>
Enforcement
>
ENFORCE26625
Metadata
Thumbnails
Annotations
Entry Properties
Last modified
8/24/2016 7:34:30 PM
Creation date
11/21/2007 11:22:02 AM
Metadata
Fields
Template:
DRMS Permit Index
Permit No
C1982056
IBM Index Class Name
Enforcement
Doc Date
9/13/2006
Doc Name
E-mail with Article on use of Polyacrylamide
From
WQCD
To
DRMS
Violation No.
CV2006006
Media Type
D
Archive
No
There are no annotations on this page.
Document management portal powered by Laserfiche WebLink 9 © 1998-2015
Laserfiche.
All rights reserved.
/
14
PDF
Print
Pages to print
Enter page numbers and/or page ranges separated by commas. For example, 1,3,5-12.
After downloading, print the document using a PDF reader (e.g. Adobe Reader).
View images
View plain text
disappearance. After 6 weeks, the rate of disappearance becomes low due to the decrease in <br />concentration of TPH in soil. In Figure 1, treatments A and B, the activity is low for initial period <br />and there is only slight loss of TPH during the initial 3 weeks. For treatment A, this may be due to <br />the sterility of the environment inside the jar during the initial period. After 3 weeks, the rate of <br />disappearance increases leading to TPH loss from the soil. The activity increases rapidly after 6 <br />weeks for treatment A, which is duo to increased growth of microorganisms. The increased <br />growth of microorganisms for treatment A can be due to the contamination of soil when the <br />containers were opened to allow all COz to escape. <br />In Figure 1 for treatment B (the initial concentration of TPH is same as treatment A but not <br />sterile), the activity is low for the initial period, i.e. rate of disappearance of TPH is low for the <br />first 3 weeks. Hereafter, there is a sharp increase in rate of disappeazance of TPH till 6 weeks. <br />This may be due to an increase in number of microorganisms biodegrading TPH in the soil. After <br />6 weeks, a lower activity is displayed by the graph of treatment B. This may be due to the <br />decrease in concentration of TPH in treatment B. It appeazs that a long time may be needed for <br />the TPH to disappear from soil at this concentration of PAM and TPH in mixtures. <br />In Figure 1 for treatment C, it is seen that at the end of 13 weeks, most of TPH has <br />disappeared. Extrapolation of the graph for treatment C appears to suggest complete <br />disappearance of TPH. <br />In Figure I for treatment D, the rate of disappearance is low for the initial 3 weeks, and <br />then the rate is slightly higher up [0 6 weeks. Overall the rate is lower for treatment D, which may <br />be due to the absence of superfloc (solid crystal PAM) in treatment D. Superfloc was added in all <br />other treatments. <br />TPH Composition and Exposure Limits <br />The identity of peaks was determined using GC/MS. A vast array of compounds was found <br />to be contained in TPH. The four prominent peaks detected were for undecane, dodecane, <br />tridecane and tetradecane. Mole fractions of the individual components are estimated as a ratio of <br />individual component counts to total TPH counts. The values obtained for mole fractions of these <br />four components are tabulated in Table 3. <br />To confirm the mole fraction values obtained by ratio of counts, mote fraction of dodecane <br />and tetradecane were also estimated by standard additions of the components to 10,000 ppm <br />standard of TPH (from cydril) in acetone. The values of mole fractions obtained agreed well with <br />those obtained by ratio method. <br />Using Raoult's Law, and the vapor pressure data in Table 1, the concentration of each <br />component in head space was calculated. The recommended exposure limit (REL) value for <br />dodecane was obtained using MSDS data from Chevron Phillips and Mallinckrodt Baker, lnc. <br />The estimated equilibrium concentration obtained is far less then the REL value as given in Table <br />4. Thus, the dodecane in TPH in the air is not expected to cause any health concern for the safety <br />of human beings in the environment. The other components REL values were not found but their <br />use is not expected to cause any concem as they fall in the same range as dodecane. <br />
The URL can be used to link to this page
Your browser does not support the video tag.