more likely to evaporate then biodegrade. Hydrocarbons deep in the soil are likely to biodegrade
<br />to a larger extent than evaporate as they are not exposed to the open environment. Light weight
<br />hydrocarbons (undecane and dodecane) are more likely to volatilize from open sail microcosm
<br />than the heavier ones (ttidecane and tetradecane). In an open soil microcosm, higher molecular
<br />weight organics are more likely to biodegrade than the lighter ones.
<br />Based on the findings from microcosm studies, biodegradation of hydrocazbons is likely to
<br />occur in soil where there is less opportunity to volatilize. [n a one liter headspace at standard
<br />conditions, hydrocarbons are not expected to volatilize significantly and thus, any disappearance
<br />of hydrocarbons may be due to biodegradation and/or any other source of degradation. TPH
<br />cazbon is biodegraded to form cazbon dioxide and soil organic matter (which includes microbial
<br />biomass). A decrease in the concentration of hydrocarbons may lead to lower rates of
<br />mineralization and production of carbon dioxide. Endogeneous metabolism in which microbes
<br />feed on the existing organic matter in soil also produces carbon dioxide.
<br />Equilibrium values of the of major components of TPH in the formulations investigated are
<br />found to be below REL (Recommended Exposure Limit), which implies that these components
<br />do not pose a hazard for the indoor environment even if the equilibrium concentration is reached.
<br />The COz evolution curves obtained provide support for the biodegradation of TPH in ATM.
<br />References
<br />I. Abdelmagid, H. M., and M. A. Tabatabai., "Decomposition of Acrylamide in Soils," J
<br />Environ. Qual., 11, 701-704 (1982).
<br />2. Acros Organics, "Material Safety Data Sheets of Undecane, Tridecane and Tetradecane,"
<br />Morris Plains, NJ, USA (2000).
<br />3. Anonymous, "Acrylamide," Environmental Health Criteria 49, World Health
<br />Organization, Geneva, Switzerland, 24, (1985),
<br />4. Atlas, R. M., "Biodegradation of Hydrocarbons in the Environment," Environmental
<br />Biotechnology: Reducing Risks from Environmental Chemicals Through Biotechnology,
<br />Omenn, G.S., Editor, Plenum Press, NY, pp: 211-222 (1988).
<br />5. Atlas, R. M. and R. Bartha, "Fate and Effects of Oil Pollution in the Marine
<br />Environment," Residue Rev., 49, 49-85 (1973).
<br />6. Azzam, R., O. A. EI-Hady, A. A. Lofty, and M. Hegela., "Sand-RAPG Combination
<br />Simulating Fertile Clayey Soils," Parts 1 to IV. Int Atomic Energy Agency., SM-267/15,
<br />321-349 (1983).
<br />7. Brown, L., M. M. Rhead, K. C. C. Bancroft, and N. Allen., "Model Studies on the
<br />Degradation of Acrylamide Monomer," Water Res., 14, 775-778 (1980).
<br />8. Cherry, A. B., A. F. Gabaccia, and H. W. Senn, "The Assimilation Behavior of Certain
<br />Toxic Organic Compounds in Natural Waters," Sewage Ind. Wastes, 28, 1137-1146
<br />(1956).
<br />9. Chevron Phillips Chemical Company, "Material Safety Data Sheet of n-Dodecane
<br />(Technical Grade)," Houston, TX, USA, (1993).
<br />10. Conway, E. J., R.J. Peterson, R.F. Collingsworth, J.C. Graca, and J.W. Carter,
<br />"Assessment of the Need for and Character of Limitations on Acrylamide and its
<br />Compounds," US EPA, Contract No. 68-O1-4308, Office of Toxic Substances,
<br />Washington DC, (1979).
<br />
|