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<br />high cost of deep drill holes. What variability hypothesis does Dr. Posey want disproved <br />with more drill holes? It is CC&V's position that these two drill holes and cores are <br />representative of the mineralogy at depth. <br />Role of Jarosite. <br />Dr. Posey continues, on page 2, to observe "This section also states that jazosite will <br />encapsulate the pyrite crystals and inhibit weathering. This is highly unlikely as jazosite is <br />extremely soluble. Jazosite will release ferric iron and actually promote pyrite solution and <br />acid generation." CC&V disagrees. In Secondary Minerals and Acid-Water Chemistry, <br />Alpers, C.N., Blowes, D.W., Nordstrom, D.K, and Jambor, J.L. list jarosite in the category <br />of "less soluble sulfates" (pages 247-270). An actual solubility constant for jarosite is not, as <br />yet, available. Jarosite is more soluble than pyrite. Jazosite is a common mineral in acidic <br />and high sulfate environments. <br />Acid Generation From Oxide Material. <br />On page 2 of the Memorandum, Dr. Posey states "Section 5.2 states that there is very little <br />potential to generate acid from rocks in the oxidation zone. This is not correct. CC&V's <br />classification of rocks into "oxide," "transitional" and "sulfide" zone reflect an empirical <br />average of pyrite and other mineralogy. However, it is recognized that the mineralogy of <br />these zones is not unique or homogeneous. Pyrite is found in the oxide zone and, if exposed <br />to weathering, will produce acid. The degree to which it will produce acid depends on the <br />degree of crushing (amount of surface exposure) and the amount of pyrite in discrete <br />segments of the rock mass. Because some parts of the so~alled oxide zone have higher <br />pyrite concentrations than others, the degree to which those parts can produce acid and <br />metals depends on their mineralogy, not on CC&V's classification." <br />CC&V's "classification" is based on logical grouping of the samples not only by mineralogy <br />but also by sulfur analyses and the results of the humidity cell tests. Dr. Posey, we presume, <br />recognizes the weathering process that the in-situ rocks have already experienced. In this <br />context, the oxide zone, which all who have investigated agree exists, has already generated <br />acid, some of which has been neutralized by carbonates. A relatively minor amount of <br />additional acid was generated by the humidity cell rests. No pre-historic of historic adverse <br />affects on downstream or downgradient waters as a result of this weathering have been <br />postulated. Thus substantial portions of pyrite have already been removed and neutralized <br />without reported adverse affects on water quality. The Arequa Gulch watershed is, of <br />course, plated with this oxide rock -millions of tons of it. Arequa Gulch is slightly acidic <br />from the spring system fed by ground water, but surface runoff reaching the Gulch channel is <br />generally not particulazly acidic. <br />The humidity cell, as well as the static, tests use material ground to pass a #10 mesh. In <br />fact, the overburden will likely range in size from about 4 feet to about a 40 mesh <br />(estimated) screen. The median size may be on the order of 8 inches. Thus the test <br />procedures would appear to expose much more pyrite than would the mining and reclamation <br />procedures. <br />16 <br />