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<br />STATE OF COLORADO <br />DIVISION OF MINERALS AND GEOLOGY <br />Department of Natural Resources <br />1313 Sherman 51., Room 215 <br />Denver, Colorado 80203 <br />Phone: 13031 866 3567 <br />FAX: U031 8 3 2-81 06 <br />DATE: May 16, 1997 <br />TO: Bruce Humphries <br />Berhan Keffelew <br />Jim Stevens <br />FROM: Harry Posey <br />RE: Preparation for meeting with hydrologic/geochemical modelers for CC&V <br />/~.. <br />I~~~ <br />DEPARTMENT OF <br />NATURAL <br />RESOURCES <br />Roy Romer <br />Governor <br />lames S Lochhead <br />Execwive Director <br />Michael B. Long <br />Division Director <br />On May 23, we are to meet with CC&V, Adrian Brown Consultants, and Shepherd-Miller to <br />lay our a project to define the hydrologic conditions of the Cresson diatreme and surrounding <br />area, and determine whether the diatreme has adequate buffering capacity to attenuate the <br />effects of acid rock drainage that will be generated in the waste rock. This memo identifies the <br />questions that I think should be answered from a geochemical perspective. Berhan already set <br />forth his thoughts on the hydrology, and I believe Jim will do so as well. <br />1. Determine wha[ portion of the water discharging from the Carlton Tunnel comes <br />through the diatreme and what portion comes through other rock. (This probably will <br />require the use of isotopic measurements such as sulfur or lead.) <br />If one could determine what portion of the discharge water comes through the <br />diatreme, then the infiltration rate could be determined explicitly. Previous estimates <br />of infiltration were based on the simple assumption that all water exiting the Carlton <br />portal came through the diatreme, but only through the diatreme. This seems <br />unrealistic given the structural complexity of the area. <br />Determine the origin of the alkalinity in the discharge water. <br />The infusion of C02 into the diatreme, which the USGS says comes from the mantle, <br />could cause carbonic acid to form as it mixes with undersaturated water in the <br />diatreme. However, the Ca to CO, ratios in some of the analyses suggest that the <br />water is saturated with respect to calcite (CaCO~). Whether the water is calcite <br />saturated due to the high COZ content coupled with the dissolution of calcium <br />minerals, and whether the Ca source is calcite, Ca-plagioclase, or other Ca mineral, is <br />not known. This needs to be determined because it should be used in the modeling <br />calculations to anchor the abundance of available alkali and thereby quantify the <br />abundance of acid neutralizing materials. <br />