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• density of 1 hole/160 acres meets the hole intensity criteria discussed above to adequately describe <br />the OIU variability. <br />Contamination. Numerous overburden sample contamination problems have been documented <br />over the last 10 years in the western United States. Drilling fluids, foam additives, and muds can <br />appreciably affect the soluble constituents (especially EC, SAR, and NH,) in the sample. During <br />rotary drilling for cores or cuttings, it is necessary to use a drilling medium such as air, water, or mud <br />for lifting cuttings from the borehole. For overburden baseline studies, it is recommended that air be <br />used whenever possible, water second, and mud (or foam) avoided unless absolutely necessary to <br />overcome circulation problems or to lift cuttings from deep holes (Barrett et al., 1980; Power and <br />Sandoval, 1976; Dollhopf et al., 1981; and Peabody Coal Company, 1987). A chemical analysis <br />should be obtained on the water, foam, and/or drilling mud whenever they are utilized. <br />Random sample contamination often results in serious misinterpretations of the data. Many <br />previously reported unsuitable copper, molybdenum, zinc, and especially lead concentrations were <br />more apt to have been caused by drill stem grease contamination than natural mineralized strata. <br />. Dollhopf and Goering (1983), Dollhopf et al. (1981), Peabody Coal Company (1986), and Rochelle <br />Coal Company (1984) all demonstrated that significant contamination resulted from zinc, copper, <br />molybdenum, and lead based drill stem joint lubricants. A noncontaminating drill stem joint lubricant <br />should be utilized when copper, lead, zinc, or molybdenum are included on the baseline parameter <br />list. <br />A noncontaminating drill stem joint lubricant (lithium based) was utilized at all 1986 sample sites <br />within the New Horizon 2 study area. Bore holes completed in 1986 were drilled exclusively with air. <br />Drilling and Collection. Overburden materials are generally sampled by utilizing one or more of the <br />following three methods; continuous cores, cuttings or chips, and highwall or outcrop grab samples. <br />Barrett et al. (1980), Dollhopf et al. (1981), MDSL (1983), Harrington (1983), WDEQ (1985), and <br />USDI-OSMRE (1985b) all recommend that a combination of continuous core and drill cuttings <br />locations be utilized for baseline OlU studies. Continuous coring is primarily utilized during the first <br />phase of an OIU sampling program to document structure and stratigraphy. Subsequently during <br />Phase II, rotary drilled chip samples are preferred to confirm chemical and physical trends because <br />• Revised 9/99 2.oa.6-1o <br /> <br />