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ACZ Laboratories, Inc. <br />2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 <br />Brown and Caldwell ACZ Project ID: L42294 <br />.- .. <br /> <br />L42294-01 WG160043 Calcium, dissolved M200.7 ICP MA One spike recovery was outside of the method limits: the <br /> tluplicate spike and the method control recoveries were <br /> within the method limits. <br />WG160012 Iron, tlissolved M200.7 ICP BC Target analyte detected in calibration blank at or above <br /> method reporting limit. Concentration found in the sample <br /> was 20 times above the concentration found in the <br /> calibration blank. <br /> Manganese, dissolved M200.7 ICP M2 Matrix spike recovery was low, the method control sample <br /> recovery was acceptable. <br /> M200.7 ICP ZK Target analyte tletecled in the blank as a negative result al <br /> or above the negative method limit (i. e. high negative bias). <br /> Sample wncenlration is al a minimum ten times greater <br />. than positive method reporting limit. <br />WG161715 Mercury, dissolved M1631, Atomic Fluorescence H7 Sample analysis pertortned past holding time. See case <br /> narrative. <br />L42294-02 WG160043 Calcium, dissolved M200.7 ICP MA One spike recovery was outside of the method limits; the <br /> duplicate spike antl the melhotl control recoveries were <br /> within the method Ilmlta. <br />WG160012 Iron, dissolved M200.7 ICP BC Target analyte detected in calibration blank at or above <br /> method reporting limit. Concentration found in the sample <br /> was 20 times above the concentration found in the <br /> calibration blank. <br />Manganese, dissolved M200 7 ICP M2 Matrix spike recovery was low, the method control sample <br /> recovery was acceptable. <br /> M200 7 ICP ZK Target analy[e detected in the blank as a negative result at <br /> or above the negative method limit (i.e. high negative bias). <br /> Sample concentration is at a minimum ten times greater <br /> than positive method reporting limit. <br />WGi61715 Mercury, dissolved M1631, Atomic Fluorescence Hi Sample analysis performed Oast holding time. See case <br /> narrative. <br />L42294-03 WG160043 Calcium, dissolved M200.7 ICP MA One spike recovery was outside of the method limits; the <br /> duplicate spike and the melhotl control recoveries were <br /> within the melhotl limits. <br />WG160012 Manganese, dissolved M200.7 ICP M2 Matrix spike recovery was low, the method control sample <br /> rewvery was acceptable. <br /> M200.7 ICP ZK Target analyte detected in the blank as a negative result at <br /> or above the negative melhotl limit (i.e. high negative bias). <br /> Sample wncentration is at a minimum ten times greater <br /> than positive method reporting limit. <br />WGi61715 Mercury, dissolved M1631, Atomic Fluorescence Hi Sample analysis performed past holding time. See case <br /> narrative. <br />L42294-04 WG160043 Calcium, dissolved M200.7 ICP MA One spike rewvery was outside of the method limits; the <br /> duplicat¢ spike and the method control recoveries were <br /> within the method limits. <br />WG160012 Iron, dissolved M200.7 ICP BC Target analyte detected in calibration blank at or above <br /> method reporting limit Concentration fountl in [he sample <br />- was 20 times above the wncentration fountl in the <br /> calibration blank. <br />Manganese, dissolved M200.7 ICP M2 Matrix spike rewvery was low, the method control sample <br /> recovery was acceptable. <br /> M200.7 ICP ZK Target analyte detected in the blank as a negative result at <br /> or above the negative method limit (i.e. high negative bias). <br /> Sample concentration is at a minimum ten times greater <br /> Than positive method reporting limit. <br />WG161716 Mercury, dissolved Mi631, Atomic Fluorescence H1 Sample analysis pertormetl past holding lime. See case <br /> narrative. <br />L42294-05 WG160043 Calcium, dissolved M200.7 ICP MA One spike rewvery was outside of the method limits; the <br /> duplicate spike and the method control recoveries were <br /> within the method limits. <br />L42294-g6 WG161715 Mercury, tlissolved M1631, Atbmic Fluorescence H1 Sample analysis pertormetl past holtling lime. See case <br /> narrative. <br />EXTQUAL.11.20.02.01 <br />L42294: Page 17 of 28 <br />