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HYDRO29104
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HYDRO29104
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Last modified
8/24/2016 8:48:09 PM
Creation date
11/20/2007 10:20:57 PM
Metadata
Fields
Template:
DRMS Permit Index
Permit No
C1980007
IBM Index Class Name
Hydrology
Doc Date
3/26/1998
Doc Name
INTERNAL MEMO MOUNTAIN COAL. WATER REPORT
From
DMG
To
DAVID BERRY
Permit Index Doc Type
CORRESPONDENCE
Media Type
D
Archive
No
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Carbon Isotope Composition <br />The carbon isotope signature was the second line of reasoning used as evidence that the water <br />issuing from the Edwards Portal spring is geochemically distinct and not the same water that <br />came from the faults. The evidence is not unequivocal. A wide range of carbon isotope <br />compositions is displayed by the waters sampled. <br />Expressed as the ratio of the carbon-13 to cazbon-12 relative to a standazd (written as d"C as a <br />per mil quantity), these S"C values range from +10.7 to -2.7 in the fault waters, certainly not <br />consistent from fault-to-fault. Water from the Lone Pine Gulch seal and the Edwards Portal <br />spring shows lighter carbon (S"C values of -5.4 and -12.9 respectively) than any of the fault <br />waters. <br />This observation doesn't eliminate the possibility that the Lone Pine Gulch and Edwards Portal <br />spring water is fault water which has undergone cazbon-13 depletion between November 1996 <br />(when B East Mains Fault water was first Bumped in the NW panel sump) and then the samples <br />from Lone Pine Gulch and Edwards Portal were taken in December 1997. One possible <br />mechanism is the simple dissolution of methane (CH,) during the time spent in the N W panel <br />sump. No S"C values are available for either the Beaz or the West Elk mines, but coal itself <br />typically displays a "C signature typical of marine sediments (around -25 per mil), with the <br />associated methane typically depleted even more in the heavier isotope carbon-13 (lower S"C <br />still) . <br />It is not unreasonable to predict that water with S~'C such as the fault waters at West Elk, would <br />show light carbon isotope numbers (low S~'C) after interacting with coal and coal-bed methane <br />for a year while stored in the NW panel sumps or traveling through the B-seam coal. <br />It must.be pointed out, however, for complete honesty, that the value of S"C presented for an <br />analyzed sample of water directly from the B-seam itself is highly positive (+24). This is another <br />piece of evidence which seems incongruous. <br />So the S"C azgument is not conclusive, as water in this environment could easily obtain lighter <br />cazbon isotopes during its residence. <br />Data Needs <br />From the hydrogeochemical perspective, the main data needs are information that tells us just <br />what is the water in the N W panel sump. We have a range of chemical analyses from water. But <br />we have no way of knowing how that relates to water in the sump. Analysis x could represent <br />l % of the volume of water put into the sump, while analysis y could represent 80%. <br />The best comparison of NW panel sump water to Edwards Portal spring water would be to use <br />water that is now up against the down-dip wall of the NW pane! sumps. We would then have <br />
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