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Appendix D, Comments jrom Rocky Mountain Consultants, Inc., Hydrokinetics, /nr., & Hydrodynamics,Inc. (Cont.) Page 10 <br />The suggestion by the reviewers that BMR! install a reactive barrier/wall is an inadequate technical solution because of the <br />nature of the chemical changes that x~ould have to occur in order to alter the concentrations of the key constituents (i. e., sulfate <br />and manganese). A reduction in the concentration of sulfate (and TDS) can only occur tlrrouglr a c/emical transformation that <br />includes: (/) precipitation of a solid phase (e.g., gypsum) or (2) a redaz trarujonnation coupled to the precipitation of a solid <br />phase (e.g., elemental sulfur or a metal sulfide). /rr contrast, manganese removal would require an oxidizing environment <br />idealty coupled with a state of elevated pH. 71rus, the ideal chemical score of a reactive barrier for treatment of sulfate is <br />antithetical to the optimum conditions for trearrnent of manganese. <br />SPEC/FIC COMMENTS <br />Comment: <br />1. Section //.F, yaee 1 second paragraph. last sentence <br />Discharge Point 002 is not shown on either Figures / or 2 of the pennit. As noted above, Discharge Point 002 actually consists <br />of at least five separate and discrete disc/rarges: 002, the window, and 003 through 006, the jour separate seeps along the Rito <br />Seca. <br />Response: <br />Revised language for 002 has been included in the pennit and rationale, and is identified in figure 2 of the permit. Also, see the <br />response to the first comment under the heading GENERAL COMMENTS. <br />Comment: <br />2. Section /l.G. oaee 2 <br />77re duration of the "initial "and "(titer" rune periods for Discharge Point 001 must be defined. <br />It is implied drat the discharge rates jrom Discharge Point 001 rill progressively decrease (i. e., 400 gprn to 250 gpm to 1 /0 <br />gpm). This progression roust be specifieA. Ij there is cause to seven back to a higher pumping rate, it would indicate that the <br />"water management plan " /ras failed, and the rationale for the pennit should be re-erarnined of that time. <br />There are no rnarimum discharge rate lirnitatians listed for Discharge Point 002, the location of which is never given. Assuming <br />that it is the seepage front, note that Item 3 on page 1 /10 in the August 30, 1999 document CDPS Permit Application: Minimal <br />Discharge Industrial Wastewater submitted by BMR/, states that pumping of the system at a capacity of 400 gpm will reverse the <br />gradient away from the Rito Seco, thereby eliminating the seepage front. However, jrom a location along the County Road, <br />Castilla County Conservancy District (CCCD) ofj4cials observed flow from one of the seeps on the bank of the Rim Seco on April <br />30, 2000 (M. McGowan, CCCD, electronic commun.). <br />/n subsequent sections, the permit states tlut! BMP's are to be used in association xdth Discharge Point 002, but again does not <br />address the discharge rates jrom either the window or the springs. We believe that quantification of these flows is important. <br />The applicant estimates West Pit outflows in Section 3.1.4.4 of TR-26. Through monitoring ojthe water levels in the alluvium, <br />arsd the utilization oJthe penneabilities determined from aquifer testing, the applicant should be able to reasonably quantify <br />groundwater flow through the restricted "window". If successful, the BMP's should terminate Jlaw through the xdndow during <br />active pumping. Quantification of flows through the xdndow should assist !n assessing the degree ojsuccess achieved by the <br />BMP's daring active remediation, and will assist in evalua[ing the system in the passive treatment period until contamination is <br />no longer a problem. <br />Response: <br />At the time of subrniltal of the pennit application, initial and later time periods for the discharge flow rates were indicated; but <br />at this point, these periods are no longer applicable. The tiered-discharge approach for Discharge Point 001 provides the <br />fieribiliry necessary to reasonably represent the probable range of flows tha! are e_cpected to occur during t/re extraction of <br />groundwater jrom the West Pit. For the purposes of the CDPS pennit, BMR/ will pump the backfilled West Pit as necessary, up <br />to a maximum Jlaw rate oJ400 gprn (30 day average), to maintain a state of reversed /rydraulic gradient. See also the previous <br />discussion on page 24 of the rationale. <br />