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COLORADO DEPARTMENT OF HEALTH, Water Quality Control Division <br />Rationale - Page 26. Permit No. CO-0027154 <br />VII. PUBLIC NOTICE COMMENTS (continued) <br />The permittee submitted several pages of silver effluent monitoring data for outfalls <br />001, 005 and 007. The data were collected for the mining permit issued by the Colorado <br />Division of Minerals and Geology (CDMG). The Water Quality Control Division reviewed <br />the data and determined that the levels for outfalls 001, 005 and 007 were well below <br />the applicable limitations. The data are summarized in the following table. <br />Outfall Maximum Concentration No. of Samoles Period of Racord <br />001 0.2 ug/Z 24 10/80 - 6/91 <br />005 70 ug/F* 350+/- 3/64 - 9/91 <br />007 0.8 ug/Y 16 9/85 - 6/91 <br />* The high data point occurred in April, 1984. Data from 1/85 through 6/91 show no <br />values higher than 4.9 ug/Y. The majority are below the detection limit. <br />These data show that the actual discharge concentrations for outfalls 001 and <br />007 are well below the effluent limitations of 0.003/0.079 mg/Y (or 3/79 ug/Y) <br />(30-day average/daily maximum). On the basis of all summarized effluent data, <br />silver limitations are being excluded from outfalls 001 and 007. Periodic <br />monitoring will be required to determine whether the concentrations remain low. <br />If levels rise, the permit may be reopened to add limitations and/or other <br />appropriate conditions. Because outfall 005 effluent silver levels have <br />exceeded the chronic limitation, silver effluent limitations will be imposed. <br />The permittee would need to demonstrate that effluent concentrations in the <br />future are well below these limitations for a minimum of two years before the <br />Division could consider eliminating these limitations. <br />TVS Hardness Value: Tha Division used a hardness value of 839 mg/Z to calculate <br />the TVS standards for copper and silver. After the draft permit went to public <br />notice, the Division was informed by EPA of guidance that recommended using <br />upper and lower default values for hardness when actual values were outside the <br />defaults. The upper default 1s 400 mg/Y. The Division communicated this <br />guidance to the permittee. The permittee submitted several more data points.of <br />hardness than were previously available. Although a new mean hardness has not <br />been 'calculated, this data would raise the mean even higher than 839 mg/Y. The <br />Division's Standards Unit reviewed the data along with available aquatic survey <br />information and concluded that the receiving water would be protected with <br />effluent limitations based on the 839 mg/Y hardness value. As pzeviously <br />discussed, silver limitations are not necessary at this time. Copper <br />limitations will remain unchanged for the time being. After at least ona year, <br />if the permittee believes they have accumulated effluent data to support removal <br />of copper limitations for one or more of these outfalls, they can request a <br />permit amendment at that time. <br />