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COLORAL>0 DEPARTiNEM OF PUBLIC HEALTH AND ENVIRONMEM, Y4ater Q~aliry Control Division <br />Rationale Page 12. Permit No. CO-0045!61 <br />For rainfall. to waive TSS and total iron limitations, it is necessary to cemonstrate that discharge occurred <br />within 48 hours after measurable precipitation has stopped. To waive :'ettleable solids limitations, it is <br />necessary to prove that discharge occurred within 48 hours after precipitation greater than the 10-year, <br />24-hour event has stopped. <br />For snowmelt, to waive TSS and total iron limitations, it is necessary to demonstrate that discharge <br />occurred within 48 hours after pond inflow has Stopped. To waive settleable solids limitations, it is <br />necessary to prove that discharge occurred within 48 hours after pond inflow volume greater than the <br />10-year, 24-hour event has stopped. <br />c) Antidea,~radation: Since the receiving waters are designated as Use P,~otected, an antidegradation review is <br />not required for these discharges pursuant to section 31.8(2) (b) of ~Ite Basic Standards and Methodologies <br />fgr Surface Water. <br />d) . alinity Regulations: In compliance with section 61.8 (2) (1) of the Colorado Discharge Permit Svstem <br />Regulations. the permittee shall monitor for total dissolved solids on a quarterly basis. Samples shall be <br />taken at the effluent discharge points. Salinity requirements are included in Part I.B.2. of the permit. <br />e) Whole F~Iuent Toxicity (WEB Testing: No discharges from this facility are subject to WEI'testing <br />requirements at this time. <br />Surface runoff outfalls (OOla, 002a, 003a, 004a, OOSa, 006x, 007a, 008x, 009a, OIOa) are exempted <br />because: <br />i) Iron is the primary constituent with the potential for toxicity in thtr facility surface runoff discharges. <br />Iron is much less toxic than other metals -the toxicity fevel far aquatic life is much higher for iron; <br />ii) Contact time is short, little time is available for oxidation to significantly increase the concentration of <br />iron in a discharge; <br />iii) Surface runoff discharges are expected to occur when stream flows are high and instream quality is <br />deteriorated by non-point source pollution and other sources. Temperatures of surface runoff (especially <br />snowmelt) are expected to be typically lower than the temperature of mine drainage and pit water. This <br />would slow oxidation. <br />If specific information is received in the furore that indicates the discharge has reasonable potential to cause <br />toxidry to aquatic life, the Division can reopen the permit as necessary to add WET requirements. <br />the permittee has agreed to meet a limitation of 1.0 mg/Pfar total recoverable iron for pit ptunpage water <br />(outfalls 004b, 007b, 0086, 0096, OIOb) and vehicle wash water (outfall 002b) in lieu of performing WET <br />testing on this water. They have stated that they will not pump this water to a pond unless laboratory <br />analysis shows that TSS and total recoverable iron limitations will not be exceeded. <br />Reference literature is incomplete and not consistent regarding the concentration where iron becomes toxic. <br />However, 1.0 mg/P is commonly accepted as a level where toxicity is rot found in alkaline water such as <br />that in Colorado. Additionally, this value is the total recoverable iron standard for segmeru I, which <br />includes the Yampa River below confluence with the immediate receiving waters. Discharges meeting this <br />limitation will protect the uses in the Yampa River. <br />3. Storritwater Evaluation: Starmwater from active and inactive coal mining sites that has been contaminated by <br />contact with overburden, raw material, intermediate products, byproducts, finished products or waste products <br />located at the site is required to be covered by a Colorado Discharge Permit System (CDPS) permit in order to <br />be discharged to waters of the state. Ibis coverage may be obtained under either a CDPS Industrial <br />Wastewater Discharge Permit or a CDPS Stormwater Discharge Permit. <br />