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• biased in regards to the potential °reduced" properties of these materials, <br />rather than their "weathered" characteristics. Recognizing that the refuse <br />materials sampled spanned a broad range in ages, the various refuse <br />samples were subjected to a regression analysis to determine which <br />parameters are signficantly effected by weathering or sample age, the results <br />of which are presented in Table 11. <br />Examination of these data suggests that the properties of the refuse <br />materials are spatially dynamic. In every instance where chemical changes <br />over time are statistically signficant, the changes are in the direction of <br />improvement in overall quality with increased age or weathering. Positive <br />improvements in quality with respect to pH, EC, SAR, Na, Zn and Mg are <br />evident from these data The improvement in nutrient properties involving Zn <br />are evident from these data. The decline in percent siR suggests that these <br />materials are actively weathering over time. A strict interpretation of these <br />data suggests that all of the parameters of potential concern in the refuse <br />materials are decreasing in concentrations and improving in overall quality <br />with time. This Vend is entirely consistent with the normal processes of soil <br />genesis. <br />Since the oldest refuse samples represent materials generated by <br />technologically less efficient methods of mining and processing and much <br />harsher conditions than are associated with the newer more efficient coal <br />recovery techniques, the very old samples represent poorer quality refuse <br />• materials, such as higher coal content, coarser fragments, etc., than the <br />newer samples. <br />In order to quantify the overall suitability of the refuse materials with other <br />potential cover materials that are required by regulation to be placed on the <br />refuse pile to a depth of four feet, the suitability criteria in the NMMMD and <br />WDEQ guidelines for topsoil substitute materials were applied to all of the soil <br />and refuse data available from the Southfield Mine. In order to present a <br />"worst case' comparison the properties of the soil materials were initially <br />compared with the refuse materials. Since R is known that the overall quality <br />of cover soil materials decreases with depth, this comparison grossly over <br />emphasizes potential quality of the cover soil materials. Each parameter was <br />individually evaluated using the methodology outlined in Table 12. <br />This suitability comparison indicates that the overall suitability of the refuse <br />material from the Southfield Mine is superior to that of the soil materials. The <br />refuse materials are statistically superior with respect to rock fragments less <br />than three inches in size, acid-base potential, N03-N and Fe. The soil is <br />statistically superior with respect to pH and SAR. The mean suitability values <br />for the other parameters were not statistically different. This comparison is <br />considered to be a "worst case' comparison since it is biased by the addition <br />of several very old and very new refuse samples. Sampling of the very old <br />refuse piles was restricted to areas having the very highest coal content and <br />the least amount of vegetation. Given this deliberate sampling bias, it is <br />surprising that the refuse materials have a suitability ranking as high as they <br />,, do. Inclusion of the very new refuse samples biases these samples because <br />it assumes that samples taken from a reduced environment will possess <br />identical characteristics in an aerobic environment. Such a set of <br />assumptions are chemically impossible to achieve due to the inability to <br />obtain suitable chemical equilibriums under such conditions. <br />35 <br />