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they correspond to the present operations area. Notations made on these <br />samples indicate that they represent old mine spoil approximately 30 plus <br />years old. It is most likely that these samples were collected from <br />disturbances associated with the Peacock Mine, that operated in the Red <br />Arrow Seam from 1933-1947. Thus, these samples most likely represent soils <br />that had been contaminated with waste coal for approximately 32 to 46 years. <br />It should be emphasized that these coal contaminated topsoil samples <br />represent what can probably be considered to be samples containing a much <br />higher level of waste coal than would be encountered using todays more <br />efficient mining and coal cleaning technologies. Since numerous <br />technological improvements in mining have resuRed in more efficient coal <br />recovery, the percent of coal in these samples are probably higher than what <br />would be expected in the refuse pile at the Southfield Mine. This point is <br />illustrated by the data presented in White et. al. (1982) wherein they reported <br />that some of the old refuse piles examined contained upwards of 40 percent <br />waste coal. The estimated percent coal fines in the present Southfield Mine <br />refuse is between 6 and 10 percent. As a general rule the sulfur content of <br />coal is higher than that found in the waste rock (Spaite et. al. 1979), it is <br />logical to assume that any reduction in coal content will reduce the potential <br />for aadfication of the refuse materials. In this light, it should be pointed out <br />that the following comparisons represent tinrorst case' conditions with respect <br />coal contamination and acidfication of soil materials at the Southfield Mine. <br />• A t-test comparison was made of these two groups of samples. There were <br />34 non contaminated and 8 coal contaminated samples in this evaluation. <br />The resuRs are summarized in Table 4. <br />Examination of these data reveals that the addition of waste coal to the <br />topsoil signficanty affects a number of soil parameters. Statistically <br />significant decreases in pH and siR were observed, while significant increases <br />in EC, Ca, Mg, OM, NO3-N, NH4-N, Fe, Mn, sand, and Cu were detected. <br />These changes parallel those reported for mine spoils in the Northern Great <br />Plains. Schafer et. al. (1979) reported increases in EC, Fe, Mn, and Zn, with <br />decreases in pH on coal spoils high in coal fragments in Montana. In North <br />Dakota, Safaya et. al. (1982) reported that the addition of slack coal to mine <br />sodic spoil resuRed in decreases in pH and SAR with increases in EC, OM, <br />Ca, Mg, total N, Fe, Mn and Zn. The similarities in trends between these <br />studies are most consistent. <br />The changes in the chemical and physical properties of the soil resulting <br />from the mixing of waste coal with the topsoil materials contain both positive <br />and negative aspects. The implications of these changes can best be <br />compared using established topsoil suitability guidelines. Changes must be <br />considered with respect to deficiencies as well as toxicities. Unfortunately <br />topsoil and overburden suitability guidelines place undue emphasis on <br />elevated levels and commonly ignore the deficiency aspects of soil chemical <br />levels. Since the CMLRD regulations at Rule 4.06.5 TOPSOIL- <br />RECONDITIONING require that specific deficiencies must be evaluated, this <br />• comparison will place equal emphasis on deficiencies as well as potential <br />toxicities. The following comparison evaluates the parameters in Table 4 that <br />22 <br />