HYDRO23313

• Permit No: M1998058
• IBM Index Class Name: Hydrology
• Doc Date: 3/15/2005
• Doc Name: Water Quality Data 2003 & 2004
• From: Connell Resources Inc.
• To: DMG
• Media Type: D
• Archive: No

ACZ Laboratories, Inc.
773 Downhill Drive Steamboat Sodnas. CO 80487 !8001 33
Batch A distinct set of samples anayzed at a specdk time
Found Value of Me QC Type of interest
Limit UPPer limit for RPD, in %.
Lower Lower Recovery Lima, in % (exceDl for LCSS. mgMgj
MDL McMOd Detection Limit. Same as Minimum Reporting Limit. Albws for instrument and annual fluctuations.
PCNISCN A number assgned tc reagentslstandares to trace to the manufacturer's certficate of analysis
Pq1 Practical quantitafipn Limit, rypicaNy 5 times The MDL.
DC TNe Value of [he Centro) Sample or the amount added to the Spike
Rec Amount of the true value or spike added rewvered, in % (except for LCSS, mglKg)
• RPD Relative Percent DMerence, calculation used for Duplicate qC Types
Upper Upper Recovery Limit, in % (except for LCSS, mgMg{
Sample Value of the Sample of interest
r ~ ..d Cti,N[ s sA~~ n.. a?x-=,. , e.3H, b`^.`nW3„".N.a~`'; « n, aaw:'->.. .emu`. a...:a.:".~i
AS Analytical Spike (Post Digestion) w. LCSWD Laboatory Control Sample -Water Duplicate
ASD Analytical Spike (Post D'gestion) Duplicate LFB Laboatory Fortified Blank
CCB Continuing Calibration Blank LFM Laboratory Fortified Matrix
CCV Continuing Calivabon Verification standard LFMD Laboratory Fortfietl Matrix Duplicate
DUP Sample Duplicate LRB Laboratory Reagent Blank
ICB Initial Calibration Blank MS Matrix Spike
ICV Initial Cakbraaon Verification standard MSD Matrbe Spike Duplcate
ICSAB Inter-elemonl Conedion 5landant - A plus B solutions PBS Prep Blank - Soil
LCSS Laboratory Control Sample - SoN PBW Prep Blank -Water
LCSSD Laboalory Control Sample -Sol Dupllcale PDV Practical quantltafion Verification standard
LCSW Laboratory Control Sample- Water SDL Serial Dilution
!4 W(..& ~.a! 4C- f.. ip ,*.~y~ ~.'a`4`4 E'd ^a4°Yx6'd`q .t t".j.~,. ~"r
~~.:. 1`~'~...: .A. y,' -~~. v4~~riMC',. f' '~Ln~ Y~ ! `:§~nSY'A-'a]
Blanks Verifies Mat there a no or minimal contaminauon in me prep method or calibration procetlure.
Contrd Samples Ved0es the accuracy of the method. including the prep Drocetlure.
OuDlfcates Verifies the precision of the instrument andlor method.
Sptes/Fortified Matrix Determines sample matrix interferences, a any.
Standard Verifies the va~li~dyity of Me rallbratlon.
0 " Anayte concentration detected at a vaWe between MDL and POL.
H Analyse exceeded meMOd hold time. pH R a fiekf test wah an immediate hold time.
R Poa spike recovery accepted because the other spike in the set fell within the given limits.
T High Relative Percent Difference (RPO) accepted because sample concentrations are less than 10z Ne MDL.
U Analy[e was anatyzed for but not detectetl at the indiwtetl MDL
V High blank tlata accepted because sample concentration is 10 times higher than blank concentration
W Poor recovery for Siher Quality control is accepted because SNver often preci0dates with Chk1rge.
X qualdy cpntrpl sample is out of control.
Z Poor spike recovery is aaeptetl because sample concentration is Mur times greater Man spike concentration.
(1) EPA 60014$3-020. Methods for Chemical Anaysis of W ater and Wastes, March 1983.
(2) EPA 60082-93-100. Methods for Me Determination pf Inorganic Substances in Envronmental Samples, August 1993.
(3) EPA 600/R-94-111. Methods for the Determination of Metals in Environmental Samples -Supplement I, May 1994.
(6) EPA SW-046. Teel Methods for Evaluating Solid Waste, Third Edition with Update III, December 1996.
(6) Standard Methods for the Examination of Water and Wastewater, 19th edition, 1995.
. "2 .1 .yp x l s ,
(t) qC results calculated hom~raw data. Results may vary slightly if the rounded values are usetl in the calcuWtions.
(2) Soil, Sludge, and Plant matrices for Inorganic analyses are reported an a dry weight basis.
(3j Animal maMices far Inorganic analyses are reported on an "as received" basis.
REPIN03.11.00.01
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