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44 wells, but all of these are a case where the detection limit (50 to 400 ug/1, depending <br />upon analytical technique and interferences) exceeds the standard. The selenium standard <br />(20 ug/11 was exceeded at 2 wells for a total of 3 out of 42 samples. The maximum value <br />observed, however, was only 30 ug/1. The TDS standard (2000 mg/1) was exceeded at 25 <br />wells for a total of 295 out of 423 samples. The sulfate standard (200 mg/1) was exceeded <br />at 34 wells. Generally, each sample from these wells exceeded the sulfate standard. In <br />conclusion, it should be noted that no ground water is bei no pumped ire the Seneca i; area <br />far irrigation. <br />3. Sui`ace Water <br />a. Total Dissolved Solids <br />TDS plots are provided for all stream and NPDES sites and Spoil Spring M1. Review of <br />these plots indicate stable or decreasing trends for sites currently being monitored at <br />surface water Sites 5, 11, 12, and 13. All other streams, along wlih all NPDES sites and <br />Spoil Spring M1, display increasing TDS trends. <br />b. Water Quality Standards <br />Table 7-114 compares surface water quality data to the livestock standards provided in <br />• Table 7-110. The aluminum standard of 5.0 mg/1 was exceeded a2 3 sites for a total of 10 <br />out of 69 samples. These high aluminum values are a result of high suspended solids, of <br />which a major component is clay li.e., aluminum silicate mineralsl. The chromium standard <br />I50 ug/1) was exceeded at 2 sites for a total of 2 out of 35 samples. This low number of <br />occurrences indicates possible lab error. The pH standard (6.5-B.51 was exceeded at 15 <br />sues for a Loral ~f 295 out of 2890 samples. However, only one rite, SW-52-5 ;SSLGS, <br />located abc:e n=nrng ca upper Li it_e Grassy L'r eek), hoc pH values above 9.0 and only two <br />spots se :nqs, r6 and •10 ISSSPGS anc SSS PG -. ~~;, had pH va'_ues below 5.5. The f:uc ride <br />standare (2_0 mg/11 was exceeded only once at eacn of twc sites. The mercury standard <br />(0.2 ug/11 was exceeded at 6 sites fcr a tota'_ of 7 out oI 153 samples. High detection <br />1_'mits, rel alive tc L-~e standard, niay influerme these exceed ences. The TDS standard (SOCC <br />me/1) was exceeded a: 2 sites for a total of S ou[ of 70 samples. The sulfate standard <br />13000 mg/ll was exceed ed at 2 sites fcr a tctz: of 6 out of 53 samples. <br />Table 7-115 compares surface water quality data to irn gation standards proaid ed in Table <br />7-ill. The aluminua, standard 15.0 mg/11 is the same as the livestock standard and, <br />therefore, expen enced the same number of exceed ences as discussed in the previous <br />paragraph. The chloride standard (100 mg/11 was exceeded at 2 sites for a total of 20 ou; <br />cf 196 samples. The chromium (100 ug/1) and copper (200 ug/1) standards were exceeded <br />or,'_y once, both at the same site and date. The pH standard (6.5-8.51 is the same as the <br />7-371 Revised 02/05/97 <br />