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PERMFILE46036
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PERMFILE46036
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Entry Properties
Last modified
8/24/2016 10:48:19 PM
Creation date
11/20/2007 12:35:04 PM
Metadata
Fields
Template:
DRMS Permit Index
Permit No
M1999002
IBM Index Class Name
Permit File
Doc Date
6/18/1999
Doc Name
LATERALLY EXPANDING OIL SHALE PERMEABILIZATION
Media Type
D
Archive
No
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<br />7 <br />3,759,328 <br />horizontally separated patterns that each contain one <br />or more wells opening into a layer rich in water soluble <br />minerals can be operand as described in connection <br />with FIG. 2 to form horizontally expanding permeable <br />zones and produce shale oil. The sizes of the permeable <br />zones can be monitored by means oC acoustic, clecvo- <br />magnetic the like meazuremenu of the ezunu of the <br />substantially void space and/or measuremcnu of the <br />volume of fluids that are contained into caverru. The <br />horizontal expansion of the caverns can be controlled <br />to provide an efficient recovery of oil from noninter- <br />secting, generally vertically extensive zones that are <br />spaced so that undisturbed columns capable of sup- <br />porting the overburden are lefr between the depleted <br />zones. <br />During the initial stages of expanding a tvbble- <br />containing cavern in accordance with the prcunt pro- <br />cess, it is not necessary and is generally undesirable to <br />use a temperature high enough to decompox a pre- <br />dominant proportion of the fluid•contacud heat unsi- <br />tive carbonate material, It is preferable to keep the cav- <br />ern substan[iallyfull o(aqueous liquid in which the car• <br />bonate material is soluble. This unds to provide the <br />best heat economy since it minimizes the decomposi- <br />tion reaction (which is an endothermic reaction that <br />comsumes heat). In order to keep the cavern substan- <br />tially filled with aqueous liquid it is preferable to main- <br />tain the pressure within the cavern above the decompo- <br />sition pressure of the heat xnsitive carbonate material <br />at the [emperature within the cavern. [n general the <br />pressure within the cavern cannot be kept high enough <br />to prevent such a decomposition during an oil recover- <br />ing stage. The retorting and hydrocarbon recovery is <br />preferably conducted at a temperature above about <br />500° F, and at the depths at which oil shalt is usually <br />encountered, the pressure in the cavern cannot be high <br />enough to prevent decomposition of heat xnsitive car• <br />bonate material at such a temperature, without a dan- <br />ger of ereatinglarge xalefractures which are extended <br />into locations in which (ractures are undesirable. <br />When one or a plurality of generally vertcaly exten• <br />attic permeable zones have been expanded horizontally <br />to substantially the extent desired, the circulation of <br />fluid within throne zones or caverns is preferably ad- <br />justed to minimize the rate of horizontal growth and/or <br />maximize the rate of oil recovery. Such an adjustment <br />can be effected by increasing the temperature and/or <br />decreasing the aqueous liquid content of the fluid <br />within the cavern. A higher temperature tends to in• <br />crease the rate of oil recovery (particularly with re• <br />specs to the gaseous componenu of shale oil). Altcma- <br />tivcly, adecrease in the aqueous liquid conunt tends <br />to reduce the rate of dissolution o! soluble mineral. <br />Whcrc the removal of solid material hom the oil shale <br />ie confined to a removal of the fluid products of the py- <br />rolyeie reaction and/or the COs and water vapor pro- i <br />duced by the decomposition of heat unsitive Carbon-' <br />arcs, the volume of the depleted oil shale tends to be <br />eutlicient, relative to the volume o(solids that are re• <br />moved, to terminate the growth o(the permeable zone <br />(unless the oil shale is ono that contains an exception- <br />ally large propo~on of heat sensitive carbonate min• <br />eral).The aqueous liquid content of the fluid within [he <br />cavern can be reduced by, for example, circulating sub- <br />stantially dry steam, or a mixture oC a dry steam and <br />e.g., carbon dioxide, et a race end temperature at which <br />aqueous liquid lift within the cavern Contains a rela- <br />tively high proportion oC inert inorganic solute. <br />F1G. 3 shoos downhole equipment of the type shown <br />in FIG. 1 arranged to effect a dowmhole separation of <br />S the gaxous and liquid phaxs oC the fluid being pro- <br />duced. Particularly when the concert[ration of heat sen- <br />sitive carbonate material is relatively high, and/or the <br />temperature of the inflowing hot aqueous fluid is rela- <br />tively high, a significant amount of gaxous carbon di• <br />IO oxide and water will be formed. However, to the extent <br />that it is [easible, it is desirable to produce a relatively <br />cool liquid phase fluid that contains a sign Jcant pro• <br />portion of produced shale oil hydrocarbon. !n the ar- <br />rangement shown in FIG. 3, borehole 20 is equipped <br />t5 with pipe strings 21, 22 and 23. Some or all o[ such <br />pipes are preferably thermally insulated, as indicated <br />by coatings 24 on pipes 21 and 22. Pipe 21, through <br />which the hot aqueous fluid is inflowed, opens into [he <br />borehole at a relatively shallow depth. Pipe 22 extends <br />20 to an intermediate depth and is used to outlow fluid <br />that is relatively cool but is predominately- gaseous. <br />Pipe 23 extends to a relatively deep depth, is preferably <br />equipped wi[h doumhole pumping means (not shown), <br />and is uxd to ouNou• fluid that is predominately liquid. <br />23 The vertical xction of borehole between the ends of <br />pipes 22 and 23 xrves as a downhole gravity of xpara- <br />tion chamber. <br />Steam or a mixture of steam and hot aqueous liquid <br />(hot water) is inflowed through pipe 21. The inflowing <br />30 honest and lightest gas lends to remain above the <br />Goole[ and heavier gas and in situ generated carbon di- <br />oxide. The cooler gases outflow through pipe 22 while <br />the honer and lighter inflowing gaxs tend to t:ow along <br />the walls oC the cavern. Where desirable a relatively <br />35 light and cool gas, such as methane, hydrogen, elc., can <br />be maintained substantially static, or slowly- injected, <br />through and around the upper portion of the borehole <br />and cavern. <br />Once the rubbled oil shale cavern has been estab- <br />a0 lished and the heat xnsitive minerals and water-soluble <br />carbonates removed as an aqueous solution, the hydro- <br />carboru (oil) can be recovered by suitable means such <br />as by contacting the cobbled oil shale within the cavern <br />with a pyrolyzing fluid to effect decomposition of the <br />a3 kerogens to hydrocarbon which is removed from the <br />formation. In recovering the hydrocarbons, the pyro• <br />1}-zing fluid can be injected (FIG. 1) via 7 and recov- <br />ered via tubing 8 visa versa and in a dual sytem az <br />shoum in FIG. 3 the pyrolyzing fluid such as steam can <br />SO be injec[cd via tubing string 2] and the hydrocarbons <br />recovered via 22 or the process can be reverxd. <br />I[ is understood that various changes in the detailed <br />dcxribed to explain the invention can be made by per- <br />i5 'SOns skilled in the art within the xope of the invention <br />as ezpresxd in the appended claims. <br />1 claim as my invention: <br />1. In a process for expanding a zone of permeability <br />within a subterrurean oil shale by forming a permeable <br />zone within a portion that contairu heat xnsitive car- <br />bonate mineral and circulating hot aqueous fluid within <br />the permeable zone, the improvement which eom- <br />prixs: <br />inllowing hot aqueous fluid in[o contact with a sub• <br />~S terranean portion of oil shale that contains heat <br />unsitive carbonate mineral at a relatively shallow <br />depth, the umperature otsaid inflowing Ouid being <br />
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