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MATERIAL SAFETY DATA SHEET
<br />TRANSLINE*
<br />~ERBICIDE
<br />mergency Phone: 1-800-992-5994
<br />ow AgroSclences LLC
<br />Indlenapotts, IN 46268
<br />ENectlve Date: 2/14/03
<br />Protluct Code: 17388
<br />MSDS: 0021108
<br />1. PRODUCT AND COMPANY IDENTIFICATION:
<br />PRODUCT: TransGne' Herbicide
<br />COMPANY IDENTIFICATION:
<br />Dow AgroScierlces
<br />9330 Zbnsville Road
<br />Indianapolis, IN 46268-7789
<br />2. COMPOSRIOWINFORMATION ON INGREDI-
<br />ENTS:
<br />Cwpyra40: 13,6Ditl,bro-J- CASH p5]]B4-BSS 40.8%
<br />pyMinecar4aryfc acct).
<br />MonoeNemmmlm 411
<br />Ines maaeaienaq low. inauame: ss.1x
<br />IwO•oMl akcyol CASs OpeBer.63-0
<br />PoygyoN 2&Z CnSp 069029.398 '
<br />This document's prepared pursuant to the OSHA Haz-
<br />ard Communication Standard (29 CFR) 7970.7200).
<br />In addifwn, other substances not 'Hazardous' per this
<br />OSHA Siandartl may be ps7ed. Where proprietary Gr-
<br />gredlent shows, the identity may be made available es
<br />provided in His standard.
<br />3. HAZARDOUS IDENTIFICATIONS:
<br />EMERGENCY OVERVIEW
<br />Hazartlous Chemical. Redd'sh-brown Iquid, sweet
<br />odor. Sljyht hans'aent corneal Injury may occur. Pro-
<br />longetl exposure may cause skin irritation. LDys for
<br />skin absorption in rabbhs ks >5000 mg/kg. Oral LDso
<br />- for rats le >5000 mg/kg. IMalatlon LCso for rats le
<br />>3.0 mglL
<br />EMERGENCY PHONE NUMBER: 7-B00-992-5994
<br />POTENTIAL HEALTH EFFECTS: This section To-
<br />lodes possible adverse effects, which could occur h
<br />hi3 material h not hantlbd b the recommended rtan
<br />er.
<br />May cerise very slgM transient (temporary)
<br />corneal injury. Vapors may irthate the eyes.
<br />SKIN: Prolonged exposure may cause moderate skEn
<br />irrtaton, A single prolonged exposure le not likely t0
<br />reSUN in the material being absorbed through the skin
<br />in harmful amounts. The LDto for skin absorption hr
<br />rabbhs is >5000 mg/kg,
<br />INGESTION; Single dose oral toxicity is extremey bor.
<br />The oral LDso for rats is >5000 mg/kg. No hazards
<br />anticipated from swallowing small amounts iraitleMdl
<br />to normal handling operatiors.
<br />INHALATION: Excessive vapor Concentrations are at-
<br />tainable and could be hazardous on single exposure.
<br />The aerosol LCsB for rats is >3.0 mglL for 4 hours. Ex-
<br />cessiveexposure (400 ppm) to isopropanol may cause
<br />eye, nose and throat irritation. Incoordination, coMu-
<br />sion, hypert¢nsion, hypothermia, circulatory collapse,
<br />respiratory arrest and death may occur folbwing bnger
<br />duration of higher levels. Observations in animals irv
<br />clude middle ear lining tlamage upon exposure to va-
<br />pors of isopropand.
<br />SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: In
<br />animals, effects have been reponed on the folbwing
<br />organs: liver antl kidney. Observations in animals kt-
<br />clude lethargy. For isopropanol: Kidney effects and/or
<br />Tumors have been observed in male rats. These ef-
<br />fects are berreved to be species specific and unlikey
<br />b occur in humans.
<br />CANCER INFORMATION: For the components
<br />tested, did not cause cancer in laboratory animals.
<br />TERATOLOGY (BIRTH DEFECTS): Cbpyral'Id
<br />caused birth defects in test animals. but only at greatly
<br />exaggeratetl doses Mat were severety toxic to the
<br />mothers. No birch tlefecs were observetl b animals
<br />given clopyrapd ad doses several times greater than
<br />those expected during normal exposure. Isopropyl
<br />alcohol at extremely high wncentrations has keen
<br />reportetl to cause birth defects antl fetal toxlciy in
<br />rats. At borer concentrations there were no effects on
<br />me feNs.
<br />REPRODUCTIVE EFFECTS: For the componens
<br />-_ . tested, in animal Studies, has been shown not to inter-
<br />fere with reproduction.
<br />UPDATES AVAILABLE AT VYWW.GREEN8O0K.NET 1
<br />4. FIRST AID:
<br />EYES: Hold eyes open antl r'nse shorty and gently
<br />wiM water for 15-20 minutes. Remove contact lenses,
<br />R present after the first 5 minutes, then continue rine
<br />ing eyes. Call a poison control center w doctor for
<br />treatment advice.
<br />SHIN: Take pR contaminated cbfhing. Rinse skin irrF
<br />mediatey wiNr plenty of water for 1520 minutes. Call
<br />a poison control center or doctor for lreatmeni advice,
<br />INGESTION: Call a pbison ~contrd center or doctor
<br />immediafey for treatment advice. Have person sip
<br />a gWss of water 8 able to swapow. Do trot induce
<br />vomhkg unless told to do so by the prison control
<br />center or doMw. W not give anything by mouth to an
<br />unconxiau person.
<br />INHALATION: Move person to fresh air. If person is
<br />tort breathing, cap 977 w ambulance, then give ar0-
<br />ficial respiration, preferably by mouth to mouth. Cap
<br />a poBOn control center w tlociw for further treatment
<br />advice.
<br />NOTE TO PHYSICIAN: No specific anfitlote. SuppoA-
<br />ive care. Treatment based on jutlgment of the physL
<br />ciao in response to reactions of foe patient
<br />5. FIRE FIGHTING MEASURES:
<br />FLASH POINT: 1 tTF (47.2'C)
<br />METHOD USED: TCC
<br />FLAMMABLE LIMITS
<br />LFL: Not determined
<br />UFL' Not determined
<br />EXTINGUISHING MEDIA: Water fog, alwhol resistant
<br />foam, COB, dry chemical, or foam prefertetl.
<br />FIRE 8 EXPLOSION HAZARDS: Toxic, irrhatlng
<br />fumes may be produced tt product is involved In a
<br />fire. Conta'ni water from fre-fighting to prevent entry
<br />Into sudace or grountl water.
<br />FIRE-FIGHTING EQUIPMENT: Untler fire conditons
<br />use a poshive-pressure sett-confainetl breathing appa-
<br />ratus and protective Clothing.
<br />6, ACCIDENTAL RELEASE MEASURES:
<br />ACTION TO TAKE FOR SPILLS/LEAKS: Absorb
<br />small 5pi115 wah inert material such as sawdust or sera.
<br />Report large sprits a Dow AgroSciences on i-800-992-
<br />5990.
<br />7. HANDLING AND STORAGE:
<br />PRECAUTIONS TO BE TAKEN IN HANDLING AND
<br />STORAGE: Keep oN of reach of chiltlren and ani-
<br />mals. Do not swalbw. Avob contact with eyes, skin
<br />and clothing. Wash thoroughy after handling. Re-
<br />move and wash contaminated clothing. Store in ory-
<br />inal wntainer with the lid tightly cased. This product
<br />Is combustible. Do rat use or store mi5 product near
<br />a heat source, open Rame or other sources d ignition,
<br />paniculary tt storage temperatures are n¢ar the flash
<br />point (17TF, 47.2'C). Noxious fumes may be formed
<br />under fire conditions,
<br />8. EXPOSURE CONTROLS/PERSONAL PROTEC-
<br />TION:
<br />These precautions are suggested for contlNons where
<br />the potential for exposure exiss. Emergency condF
<br />Lions may require add'Aional Drecautbns. '
<br />EXPOSURE GUIDELINES:
<br />isopropyl ebuhol: ACGIH TLV antl OSHA PEL are
<br />400 ppm TWA, 500 ppm STEL.
<br />PELs are in accord with those recommended by OSHA
<br />as h the 1989 revisbn of PELS.
<br />Polygycol 252: Dow AgroSCiences Industrial Hygiene
<br />Guideline is 2 m9/MB.
<br />Cbpyralid: Dow AgroSclences Industrial Hygiene
<br />Guideline is 70 mg/M .
<br />ENGINEERING CONTROLS: Provide general and/or
<br />local exhaust ventilation to control airborne levels be-
<br />ow the exposure guidelines. Use onty whh adequate
<br />ventilation
<br />RECOMMENDATIONS FOR MANUFACTURING,
<br />COMMERCL4L BLENDING, AND PACKAGING
<br />NORKERS:
<br />RESPIRATORY PROTECTION: Atmospheric levels
<br />;taunt be maintained below the exposure guidelines.
<br />Nhen respiratory protection Is required use a NIOSH
<br />approved au-purifying orpositive-pressure supplied-air
<br />esp'vator tlepending on the potential airborne wncen-
<br />ratbn. Fw emergency and other cendifans where
<br />Database and format copyright Cri by C8P Press. All rights reserved.
<br />-~aii i ,., m- ,-~_-
<br />the exposure guideline may be greatly exceeded, use
<br />a NIOSH approved pospive-pressure sapcontained
<br />hreathing apparatus pr posidve•pressure airiine whh
<br />auxiliary seh-contained air soppy. In confined or prwdy
<br />vendated areas, use a NIOSH approved posttive
<br />pressure supplied-air respirator.
<br />SKIN PROTECTION; Use gbves impervbus a this
<br />material when probnged w frequently repeated con-
<br />tact mould ocwr.
<br />EYE PROTECTION: Use safety glasses. R vapor ex-
<br />posure causes eye dLScemforL use a NIOSH approved
<br />fop-face respirator '
<br />APPLICATORS AND ALL OTHER HANDLERS: Re
<br />ter to the Predud label for personal protecOve cbtdng
<br />antl equipment.
<br />8. PHYSICAL AND CHEMICAL PROPERTIES:
<br />BOILING POINT: 212'F (100'C)
<br />VAPOR PRESSURE: 23.5 mmHg @ 20'C
<br />VAPOR DENSIT': 1.06 @ 20'C
<br />SOLUBILITY IN WATER: Maude
<br />SPECIFIC GRAVRY: 1.161 @ 6B'F, 20'C
<br />APPEARANCE: Reddish brown I'quid
<br />ODOR: Sweet
<br />pH: 7.58.0
<br />10. STABILIT' AND REACTIVITY;
<br />STABILITY: (CONDITIONS TO AVOID) Store uMer
<br />coot, dry conditiors. Avob elevated temperatures and
<br />direct sunlight Combustible. Do not use or store near
<br />heat, open flame, or other sources bf ignition, espe-
<br />cially R temperaures are near or at the flash point
<br />INCOMPA7IBILfTY: (SPECIFIC MATERIALS iO
<br />AVOID) Avoid. acid, oxitl¢kg mat¢rial, habgenated
<br />wganbs, brass, copper, zinc, and alundnum.
<br />HAZARDOUS DECOMPOSITK)N PRODUCTS: Hy-'
<br />drogen chbride, nhrogen pxides under free coMRicns,
<br />chlodrated PYridine.
<br />HAZARDOUS POLYMERIZATION; Not knmvn to ou
<br />Wr.
<br />17. TOXICOLOGICAL INFORMATION:
<br />MUTAGENICIT/: For the comlanents tested, in-vibo
<br />antl animal mulagenbiy studies were negatlve.
<br />12. ECOLOGICAL INFORMATION:
<br />ENVIRONMENTAL FATE:
<br />MOVEMENT 8 PARTRIONING: Based Wgey w
<br />opmpletey on iMOmlation for ctopyraGd, B'aconcerF
<br />tration potental le bw (BCF X700 w Log Pow <3).
<br />Potential for mobipy in sort le very high (KOC between
<br />0 and 50).
<br />DEGRADATION 8 PERSISTENCE: Based lergey w
<br />completey on hdorrnation for cbpyralb. Biodegrade
<br />tbn under aerobic aboraary centliticns le bebw tle-
<br />tectable IimhS. The pholdysis haR-life in water is 261
<br />days. The photoys's haH-life in soil le >t2 years. Un-
<br />der aerobic sop conditions the haR-life is 71 days.
<br />ECOTOXtCOLOGY: Based largey w completey
<br />on informafron for cbpyralitl. Material is pracircaly
<br />non-toxic to aquatic organisms on an ache hoses
<br />(LCso/ECM >700 mglL'm most senstlNe species,
<br />13. DISPOSAL CONSIDERATIONS:
<br />DISPOSAL METHOD: Do not wntaminale food, fried,
<br />or water by storage w disposal. Wastes are toxb.
<br />Improper disposal or excess waste. spray mixNre. w
<br />rinsate is a violation of federal taw. R wastes resul6rM
<br />from the use of this produq cannot be disposed M
<br />according tc label instructions, dispose of these wastes
<br />at an approved taciliry. Contact your state pesticide or
<br />envrronmentat control agency, or the hazardous waste
<br />representative at the nearest EPA regional office for
<br />guidance.
<br />14. TRANSPORT INFORMATION:
<br />U.S. DEPARTMETR OF TRANSPORTATION INFOR-
<br />MATION:
<br />FOR ALL PACKAGE SIZES:
<br />BY LAND: NM regutated for transportation.
<br />BY AIR OR VESSEL: FLAMMABLE LIQUIDS, N.O.S.
<br />(CONTAINS ISOPROPANOL)/3NNt993/PG111'
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