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MATERIAL SAFETY DATA SHEET <br />DuPont TELAR DF <br />ERBICIDE -FOR USE <br />STATES OTHER <br />THAN CA <br />M0000385 <br />Revised 18-AUG-2004 <br />CHEMICAL PRODUCT/COMPANY IDENTIFICA~ <br />TION - <br />Materialldenti8cation - ' <br />'TELAR" is a registered trademark of DuPont <br />"DuPont" U e trademark of DuPont <br />Corporate MSOS Number: D0008091 <br />Tredenames and Synonyms <br />CHLORSULFURON 75XP <br />Company Ident~cation <br />MANUFACTURER/DISTRIBUTOR <br />DuPont <br />1007 Market Street <br />Wilmington, DE 19898 <br />PHONE NUMBERS <br />Product Intomlation: 1-800441-7515 (outside the U.S. <br />302-7741000) <br />Transport Emergenty: CHEMTREC 1.800424-9300 <br />(outside U.S. 703-527-3887) <br />Medical Emergency: 1-800447J637 (outside Me U.S. <br />302-774-1000) <br />COMPOSITION/INFORMATION ON INGREDIENTS <br />Components <br />Mxt~rlrl CAa Numbr % <br />'LHLOfraULFURON 6Cea]-T2-J 75 <br />I~TRUSIN+ Yl}4M)N'07CARBONEYL]BENZENE- <br />BULFONAMEIE) <br />INERT INGREDIEMe 2a <br />Dfscbsure as a toxic chemical a required underSec- <br />Ion 313 Df Title III of the Superfund Amendments and <br />~teauthoifzalion Acr of 7986 and 00 CFR par1372. <br />E -' AZARDS IDENTIFICATION <br />Emergency Overview <br />CAUTION! HarmWl'rf absorbed through skin. Causes <br />moderate eye inflation. Avoitl contact with skin, eyes, <br />or clothin8. Wash thoroughly wkh soap and water after <br />' handl'vlg. <br />Potential Health ETtects <br />Basetl on animal data, Telar DF Herbicide may rouse <br />eye initason with discomfort, tearing, or blurdrg of <br />visbn. <br />Basetl on animal tlata. Teiar OF Hembide may cause <br />skin irdtason with discomfort or rash. <br />Cardnogenieiy Information <br />None of the components present in this material at <br />wncenaations equal to or greater than 0.1% are I¢ted <br />by IARC, NTP. OSHA or ACGIH as a carcinogen. <br />FIRST AIO MEASURES <br />First Aid <br />INHALA710N: <br />No specific intervenson is indicated as the compound <br />is not likely to he hazardous by inhalation. Consub a <br />physician M necessary. <br />SKIN CONTACT: <br />Take off contaminated cbihirg. Rinse skin immedi- <br />atey wtlh plenty of water for 7520 mimes. Ca0 a <br />poison conllol center or tloctor for further treatment <br />advice. <br />EYE CONTACT: <br />Hold eye open andTinse slowly and gently cash water <br />for 15-20 minutes. Remove contact lenses, 6 presen4 <br />after the first 5 minutes, men continue rinsing eye. CaA <br />a poison control center or doctor for further, treatment <br />advice. <br />INGESTION: <br />~~~gi}N55ilo specNC intervention b indicated, as the compound <br />not likely to be hazardous by ingesson. Consuk a <br />physician if necessary. <br />eve the product wntainer or label wim you when <br />ailing a poison control center or tlodor, or going for <br />treatment You may also contact 7-800441-3637 /w <br />emergency medical treatment informatbn. <br />UPDATES <br />FIRE FIGHTING MEASURES <br />Flammable Properties <br />The material poses no expbsion hazard In granular <br />form. <br />Like most organic powders or crystals, under severe. <br />dusting conditions, [his material may form explosive <br />m&Wres in ev. <br />Extinguishing Media <br />Water Spray, Foam, Dry Chemical, C02. <br />Fire Fighting Instructions <br />Wear sett-Contained breaming apparatus. Use water <br />spray. Cool tanWCOntainer cash water spray. <br />If area is heaviy exposed to fire and 6 conditions per- <br />mk, let fire burn iLses out since water may increase the <br />area contaminated. <br />ACCIDENTAL'RELEASE MEASURES <br />Safeguards (Personnel) <br />NOTE: Review FIRE FIGHTING MEASURES and <br />HANDLING (PERSONNEL) sections before proceed- <br />ing wim clean-up. Use appropriate PERSONAL PRO- <br />TECTIVE EQUIPMENT during clean-up, <br />Emergency Response -Chemical resistant coveralls, <br />waterproof gloves, waterproof boots and face/eye pro- <br />tecaon. M tlussng occurs, use NIOSH approved respF <br />rebr pratecibn. <br />Initial Containment <br />Dke spill. Prevent material from entedng sewers, wa- <br />terways, or low areas. <br />Spill Clean Up <br />Shovel or sweep up. <br />HANDLING AND STORAGE <br />Handling (Personnel) <br />Avoid breathing tlusL Avoitl contact wim eyes, skin, or <br />doming. Wash [Droughty after handling. Oo not store <br />or wnsume footl, drink or use tobacco in areas where <br />may may become Contaminated wflh tMS material <br />USERS SHOULD: Wash hands before eating, tlrink- <br />ing, chewing gum, using tobacco or using the toilet <br />Handling (Physical Aspects) <br />Keep away hom-heat, sparks and flames. <br />Storage <br />Store product in odginel container ony. Do not con- <br />taminate water, other pesnckles, fertil¢er, food or feed <br />in storage. <br />EXPOSURE CONTROLSIPERSONAL PROTECTION <br />Engineering Controls <br />Use only with adequate ventilation. <br />Personal Protective Equipment <br />For non-agricukural use. No PPE 'IS specified; how- <br />ever, avoid contact with skin, eyes, and doming. <br />Exposure Gu(tlelines <br />Applicable Exposure Limib <br />CHLORSULFURON <br />PEL (OSHA): None Eslabl'ahed <br />TLV (ACGIH): None Established <br />AEL • (DuPont): 10 mg/m3, 8 8 72 Hr. TWA <br />'AEL is DuPOnt's Acceptable Exposure Limit Where <br />governmentaly imposed occupafpnal exposure limbs <br />which are bwer than the AEL are in effect, such limits <br />shall lake precedence. <br />PHYSICAL AND CHEMICAL PROPERTIES <br />Physical Data. <br />SoWhAity in Warer: Dupersfble <br />pH: 4.5 @ 1% suspension <br />Odor; None <br />Form: Sotltl <br />Cobr. Tan <br />Specific Gravity: 0.69 @ 25C (77F) <br />Density: 0.64-0.74 glmL <br />BTABILI71' AND REACTIVITY <br />Chemtwl Stabilly <br />sable at normal temperatures and storage cond6ipns <br />ncomDatibifiry with Other Mafertals <br />Jong reasonably foreseeable. <br />rolymerization <br />'otymerization will not occur. - <br />4VAILASLE AT WWW,GREENBOOK.NET 1 <br />TOXICOLOGICAL INFORMATION <br />Animal Data <br />Telar DF Herbkide <br />Oral LD50: > 5000 mglkg in rats (Very krv toxbiry) <br />Skin Absoryson LD50: > 2000 mgdcg m rabbits <br />(Slighsy to nwderatety tozk) <br />Telar DF Herbicide is a mild reversible skin lrnlanl, and <br />a moderate eye ImkaM, bN is rot a skin sensflaer N <br />animals. <br />Chlorsuliuron <br />Inhalation 4 hour LC50: > 5.9 nglL in rats (Very bw <br />toxbiry by inhalation} <br />The effects in animals from repeated exposures by <br />inhalation to ChklrsuMUrm klcNxle decreased weight <br />gain, reversible k{tlney and spleen eftecls,.arW bone <br />mnnow changes. <br />Toxicity descdbetl in animals from the atlministratan <br />of a single dose of Chbrsumxon include lung changes, <br />weakness and other nonspecific egects. Repeated <br />dosing caused decreased weigh gain, and hemalo- <br />bgical and clinical chemkal changes. Long-term dos- <br />ing (500 ppm) resuned in decreased body weight gain, <br />and slight hemambgicel charges. Longterm dosing <br />at even higher dose kveLS (2500 ppm) causetl a s1igM <br />tlecrease in fertl5ty. <br />Animal tessrg irxlirate5 that Chbrsu6uron, the active <br />irgredienL did mt show camirogenb egects. DeveF <br />opmental tozwlty has been observed but ony at me- <br />', lernalty toxk dose leveb. <br />i Chbrsulfuron dxl not produce genetic damage in beC• <br />terbl or mammalian cell cultures. It did not produce <br />hersable genetic damage. <br />ECOLOGICAL INFORMATION <br />Ecotoxicobgiwl tnfomratbn <br />AQUATIC TOXICITY: <br />CHLORSULFURON <br />96 hour LC50 - SheepshR.atl minnow: > 980 nglL. <br />48 hour EC50 -Oysters: 365 mglL. <br />AVIAN TOXICITY: <br />CHLORSULFURON Acute Oral LD50 - Mallartl Duck: <br />> 5000 mg/kg. . <br />Acute Oral LD50 -Bobwhite QUZB: > 5000 mg/kg <br />DISPOSAL CONSIDERATIONS <br />Waste Disposal <br />Do not wntaminate wager suppy, food or feed by stor- <br />age or disposal <br />Wastes resuttkg from me use or ms product may be <br />disposed of on she or at an apProvetl waste tlislxrsal <br />facility, Treatmem, staage, bansponatbn, and tli5- <br />posal must be in accordance with apPficeble Federal, <br />SUte/provincial, ant bcal regulatiora. <br />ENVIRONMENTAL HAZARDS <br />Do not aDPly directly to water, or to areas where strc- <br />face is present w to intertldaf areas below Ifs; mean <br />high water mark. Do rqt contaminate water when dis• <br />posing of equipment washweters. <br />Container Disposal <br />Tdple rinse (or equWaleni) the wntalner. Then offer for <br />recycling or rewndlCloning, or puncture antl dispose of <br />in a sanitary landfill, or by incineration, or 0 allowed by <br />state and local authorises, by' burning. 0 burned, stay <br />out of smoke. ' <br />TRANSPORTATION INFORMATION <br />Shipping Infonnalion <br />DOTlIMO <br />Proper Shipping Name: Not Regulated <br />REGULATORY INFORMATION <br />U.S. Federal Regulations <br />TITLE III HAZARD CLASSIFICATIONS SECTIONS <br />311, 312 <br />Acute: Yes <br />ChronK: No <br />Fire: No <br />Reactiv'Iry: No <br />Pressure: No <br />In me Unitetl States ih's produQ is regulated by the <br />US Environmental Protecl'x)n Agency under the Fed- <br />eral Insecticide, Fungkide antl Rodentkitle Act. It b a <br />violation of federal law tD use this product in a manner <br />incronsislent wim its tabeiing. <br />EPA Reg. No. 352-522 <br />Database and Tormat copyright ~ by Vance Communication Corporation. All rights reserved. <br />t 3L..,.:. i <br />^£'~' ~ sq~~i .._ lac.,: r--,~t~i <br />.-Asosz.t_:-,_r:,y.., .~_. raab.m„vrs Tti- <br />