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MATERIAL SAFETY DATA SHEET
<br />REDEEM* R8LP
<br />ERBICIDE
<br />ergency Phone: 800.992-5994
<br />ow AgroSciences LLC .
<br />Indianapolis, IN 46268
<br />Effective Date: 3/72/01
<br />Produet Cotle: 78163
<br />MSDS: 003599
<br />1, PRODUCT AND COMPANY IDENTIFICATION:
<br />PRODUCT: Redeem' R&P Herbicide
<br />COMPANY IDENTIFICATION:
<br />Dow AgroSciences
<br />9330 Zionsville Road
<br />Intlianapotk, IN 46268-1189
<br />2. COMPOSITION/INFORMATION ON INGREDI~
<br />ENTS:
<br />Tidopyr CAS# 33.0%
<br />((3,5,6-1dMlwo-2- 05]213.69.7
<br />pydtlinygOxy)ace0c eddy.
<br />es ate bieNylamine eelt
<br />Clopyrali0 (3.64iWOro-2- CASp 12.1%
<br />pyddinecarboxylic add), OS]>5a-BSb
<br />es the tderhylamine sett
<br />Irian iigredients, total, CAS# 54.9%
<br />inducing: 000111.4a41
<br />N,N-piemNemanamine
<br />EDiA (ENylenediamine
<br />Teaaaratic CAS#
<br />Add)(Elhanol) 000060-00.4
<br />This document ¢ preparetl pursuant to the OSHA Haz-
<br />ard Communicatbn Standard (29 GFR 1970.1200). In
<br />atltlition, other substances not 'Hazardous' per this
<br />OSHA Standard may be listetl. Where proprietary h-
<br />gredientshows, the kentiy may be made available as
<br />provked in this standartl.
<br />3. HAZARDOUS IDENTIFICATIONS:
<br />EMERGENCY OVERVIEW
<br />azardous chemical. Clear amber liquid, slight amine
<br />or. May cause severeeye irpatiora arw/a moderate
<br />rneal injury. The LDSO for skin absorpClon in rabbits
<br />>2000 mglkg. The oral LDso for rats is 2164 mg/kg
<br />male) antl 1521 (female). Material is sligMy toxic to
<br />aquatlc organLSms.
<br />EMERGENCY PHONE NUMBER: 8lN)-992-5994
<br />POTENTIAL HEALTH EFFECTS: This section in
<br />eludes possible aWerse eflecLS, which souk occur p
<br />IDis material is nd handled in the recommended man-
<br />ner.
<br />EYE: May cause severe eye irritation wOh motler4le
<br />corneal injury. Ettecs may be sbw to heal. Vapors
<br />M amires may cause swelling of the cornea resulting
<br />in visual disturbances such as blurretl, smoky or halo
<br />vision.
<br />SKIN: Prolonged exposure is not pkey to cause signd-
<br />icanl skin irr0ation. Proonged or frequenty repeated
<br />Skin contact may Cause allergic skin reactions in some
<br />intlivitluals. A single prolonged exposure is not Nkey
<br />1o result in the matedal being absorbed through skin
<br />in harmful amounts. The LDsa for skin absorption M
<br />rabbits is >2000 mg/kg. May cause allergic skin re-
<br />acrbn in susceptible indivkuals. With the dilute mhc,
<br />no allergic skin reac8on is expected.
<br />INGESTION: Single dose oral tozkity is low. The oral
<br />LDss Tor male rats's 2764 mg/kg and females k 1527
<br />mghg. Small amounts swalbwed incidental to nor-
<br />mal handling operatbns are not pkey ro cause injury;
<br />swallowing larger amounts may cause injury. Ingestion
<br />may cause gastrointestinal Irthation or ulceration.
<br />INHALATION: Single exposure to vapors a not Nkey
<br />to be hazardous. LCsp for rats is >7.06 mg/L for 4
<br />hours.
<br />SYSTEMIC (OTHER TARGET ORGAN)EFFECTS: In
<br />animals, effects have been reported on the folowing
<br />orgaru: heaA, kitlney, and liver.
<br />CANCER INFORMATION: Triclopyr and clopyralid tlitl
<br />not cause cancer in laboratory animals. This material
<br />comains ethanol. Epidemiology studies provke evi-
<br />dence that tlrinking of alcoholk beverages (containing
<br />thano9 is associated with cancer, and IARC has clas•
<br />ifietl alcoholic beverages as carcinogenic to humans.
<br />ERATOLOGY (BIRTH DEFECTS): Tdclopyr did not
<br />cause birth defects in laboratory animak. Clopyralid
<br />caused birth defects in test animals, but ony at grealty
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET
<br />exaggerated doses that were severely toxic to the
<br />rtrofhers. No birth defects were observed m animals
<br />gNen cbpyralid at doses several times greater tllan
<br />those expected during normal exposure.
<br />REPRODUCTIVE EFFECTS: For trklopyr and cbpy-
<br />ralitl, in laboratory animal studies, effects on repro-
<br />tluctbn have been seen only of doses that produced
<br />significant toxkiry to the parent.
<br />4. FIRST AID:
<br />EYES: Irrigate whh flowing water immetliatey antl cen
<br />tinuousy for 15 minutes. ConsuO medical personnel.
<br />SKIN: Wash off in flowing water or shower.
<br />INGESTION: Do not induce vomiting. Give large
<br />amounts of water or milk h available and transport
<br />io medical facility. Do not give anything by mouth to
<br />an unconscious person.
<br />INHALATION: Remove to fresh air p effects occur.
<br />ConsuO a physician.
<br />NOTE TO PHYSICIAN: May cause tissue destruction
<br />katlkg b strbture. If lava9e is pedormed, erMotra-
<br />cheal and/or esophageal control is suggested. Ex-
<br />posure tc amine vapors may cause minor transbnt
<br />edema of the corneal ephhelium (glaucopsia) wi0t
<br />blurted vision. blue haze antl nabs around bngM ob
<br />)acts. Effects tlisaDpear in a few hours antl tempomrlly
<br />reduce ability to drive vehkle. No specific antkde.
<br />Supponive care. Treatment based on judgment d 81e
<br />physkian in response to reactions of the paClenL
<br />6. FIRE FIGHTING MEASURES:
<br />FLASH POINT: t50-F (66'C)
<br />METHOD USED: FCC
<br />FLAMMABLE LIMBS
<br />LFL: Nd determined
<br />UFL: Not determined
<br />EXTINGUISHING MEDIA: Foam, COz
<br />FIRE AND EXPLOSION HAZARDS: Irritating vapors
<br />under tse condM1ans, Material k a water solution and
<br />except under grass fire conditions should rat bum.
<br />Avoid centaminatrng water supplies whh rurarofl water.
<br />FIRE-FIGHTING EQUIPMENT: Under fire contliaons
<br />use posiWe-pressur¢, self-contained breaming appa-
<br />raNS and futl protecave clothing.
<br />6. ACCIDENTAL RELEASE MEASURES:
<br />ACTION TO TAKE FOR SPILLS: Absorb small spills
<br />with fined materials Such as Zorball, Hazorb or sand.'
<br />Report large spills to Dow AgroSciences 7-800.992-
<br />5984.
<br />7. HANDLING AND STORAGE:
<br />PRECAUTIONS TO BE TAKEN IN HANDLING AND
<br />STORAGE: Keep out of reach of chOdren. Harmful 8
<br />swaMwed, inhaled, or absorbed through skin. Causes
<br />eye irtitation. May cause allergic Skin reactions iri some
<br />intl'rvkuals. Avok contact with eyes, skin, antl cbthing.
<br />Store in original container with the lid tighty cbsetl.
<br />8. EXPOSURE CONTROLS/PERSONAL PROTEC-
<br />TION:
<br />70ese precautions are suggestetl for condi8ons where
<br />the potenfsl for exposure exists. Emergency condo
<br />lions may require additional precautbns.
<br />EXPOSURE GUIDELINES:
<br />3,S,6-Trichbro-2-pyridyloxyacedc acid (Trkbpyr), trf-
<br />efhylamine salt: Dow AgroSciences Industrial Hygiene
<br />Guideline is 2 mg/MS as acid equivalent, Skin.
<br />ideihylamine; ACGIH TLV 's 1 ppm, TWq 3 ppm
<br />6TEL, Skin. A4. OSHA PEL is t0 ppm TWA, 75 ppm
<br />STEL
<br />3,6-Dkhloroplcolinic acid (Clopyralid): Dow Agro-
<br />6ciences Industrial Hygiene Guideline is 10 m
<br />Ethanol (ethyl alcohol): ACGIH TLV and OSHA PEL
<br />are 7000 ppm. ACIGH class~catbn is A4.
<br />'Els era in accord with those recommended by OSHA,
<br />as in the 7989 revision d PELs.
<br />\ "skin" notation following the exposure gudeline
<br />efers to the potential for dermal absorption of the ma-
<br />erial. It is intended to alert the reader that inhalation
<br />nay not be the ony route of exposure arrd that mea-
<br />sures to minimize dermal exposures shook be wnsid-
<br />rced.
<br />:NGINEERING CONTROLS: Provide general antl/or
<br />x:al exhaust ventilation to control airborne levels ba
<br />1w the exposure guidelines.
<br />Database and format copyright B by CSP Press. Ail rights reserved.
<br />RECOMMENDATIONS FOR MANUFACTURING,
<br />COMMERCIAL BLENDING, AND PACKAGING
<br />WORKERS:
<br />RESPIRATORY PROTECTION: Atmospherk levels
<br />should be mairnainetl bebw the exposure guideline.
<br />When respiratory protection Ls required tar certain oP.
<br />era0ons, use a NIOSH approved air-purifying respire-
<br />tar.
<br />SKIN PROTECTION: When proonged ar frequently
<br />repeated conact cook occur, use lxotec8ve dothin9
<br />impervious to tries material. Selectkm of specific hems
<br />such as faceshbk, gbves, book, apron, or fulLbody
<br />soh call depentl on opera8oris.
<br />EYE PROTECTK)N: Use chemical goggles. K vapor
<br />exposure causes eye d'scemlori use a NIOSH ap-
<br />proved fulFface resPhafa.
<br />APPLICATORS AND ALL OTHER HANDLERS: Re-
<br />fer to the product label for personal protective clothing
<br />antl equipmem.
<br />9. PHYSICAL AND CHEMICAL PROPERTIES:
<br />BOILING POINT:'Approximetey 212'F (100'C)
<br />VAPOR PRESSURE: Similar W that of water
<br />VAPOR DENSITY (Ak =1): Not OetertNned
<br />SOLUBILITY IN WATER: M'scide
<br />SPECIFIC GRAVRV: 1.14 Q 68'F/68'F
<br />APPEARANCE: Clear amber figtdtl
<br />ODOR: SFgM amne amel
<br />10. STABILITY AND REACTIVITY:
<br />STABILITY; (CONDITIONS TO AVOID) Store under
<br />cad, dry wndifxxts. Avok elevated temperatures arW
<br />direct sunlight
<br />INCOMPATIBILRI': (SPECIFIC MATERIALS TO
<br />AVOID) Avoid aW, oxk'abg materbL Aakgenated
<br />organs, Dross, copper, zinc, and aluminum.
<br />HAZARDOUS DECOMPOSITION PRODUCTS: Hy-
<br />drogeq chloride, nitrogen oxkes under foe cerg8ions;
<br />chbdnated pyridine. - '
<br />HAZARDOUS POLYMERIZATION; Not krawn to 0o-
<br />cur.
<br />11. TOXICOLOGICAL INFORMATION:
<br />MUTAGENICf1Y; Fa tdcbpyr antl cbpyral'k, invaro
<br />and an'#nal mutagenkl y studies were negative. -
<br />t2. ECOLOGICAL INFORMATK)N: '
<br />ENVIRONMENTAL FATE:
<br />MOVEMENT 8 PARTITIONING: Basetl largey or
<br />completey on component informaton. Bioconcenlra-
<br />tbn potential's kaw (BCE <t00 or Log Pow <3).
<br />DEGRADATION 8 PERSISTENCE: Based largey d
<br />wmpletey on data for major components. Bialegrt
<br />datbn under aerobic static bbomtory contli0ons is high
<br />(BOD20 ar BOD28/fhOD k >40%).
<br />ECOTOXICOLOGY: Basetl on irdorma8on for tiabpyr
<br />TEA soh end rriethylartprre. Materral k s8ghty kzk b
<br />aquatic organisms on an acute bases (LCso/ECsp is be-
<br />tween 10 and t00 rtglL h the most senshive species).
<br />Based on iMormation tpr cbpyrelk. Material is praut4
<br />caly nontoxic b aquatic organisms on an acute basis
<br />(LCso/ECsp is > 100 rng4- in most senshive species).
<br />13. DISPOSAL CONSIDERATIONS:
<br />DISPOSAL METHOD: Excess wastes are toxk. Irm
<br />proper disposal of excess wastes are a vbbtbn of
<br />federal Law. tt mesa wastes cenrat be disposed of
<br />by use according k label instructions, canted your
<br />stare pesticide or envaonmcnfal comrd agency, or the
<br />hazardous waste representafrve at Me nearest EPA
<br />reg'anal office for gukarlce.
<br />14. TRANSPORT INFORMATION:
<br />For DOT regulatory iMormation, h required, wnsu#
<br />transportafan regulations, product-shipping papers, or
<br />canted your Dow AgroSciences reW~eMaBVe.
<br />NOTICE: The information herein is presemetl in good
<br />faith and believed to be accurate as of the effective
<br />date shown above. However, no wartany, express or
<br />implied, 6 given. Regulatory requirertaents are subject
<br />to change and may diner from one bcatan to another;
<br />tt is the buyefs responsib0ily to ensure that its actM-
<br />ties compy whh federal, state ar provindal, and heal
<br />laws. Tne topowing specific irAormadon 5 made for
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