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MATERIAL SAFETY DATA SHEET <br />UPDATES AVAILABLE AT WW W,GREENBOOK,NET 1 <br />~Plateau® herbicide <br />Product No.: 579651 <br />Wteau° herbicide <br />ate Preparetl: 6/16!2000 <br />Date Revised: 12/4/2001 <br />BASF Corpora8on <br />Agdcultural Products Group <br />P.O.Box 13528, <br />Research Triangle Park, NC 27709 <br />(919) 547-2000 <br />EMERGENCY TELEPHONE NUMBERS: <br />BASF Corporation: t (BDO) 832-HELP <br />CHEMTREC: 1 (800) 424-9300 <br />SECTION I <br />Trade Name: PWteau° herbicide <br />Chemical Name: ammonium salt M 2-[4,5-dihydro- <br />4-methyl-0-(1-methylelhyl}5ozo-1 H-imitlazol-2-yQ~S <br />mefiyF3-DYridinecarboxyAb acitl, <br />Synonyms: imazapic artmonium salt; AC263,222 <br />FormuW: C14 Ht6 N3 03. NH4 <br />Chemical Famfty: imidazolinone <br />tool W[: 292.337 <br />SECTION II -INGREDIENTS <br />tOMPDNEM LAa Ne. y, PELRLV. <br />SOURCE <br />Imaiapk, 10009e<l49 ]3.e0 None <br />m eao eaesrsnn <br />' IneN WA )e.M None <br />esmoc nee <br />SARA Title III Section 313: Not listed <br />SECTION III -PHYSICAL DATA <br />BOILING/MELTING POINT@760mm Ng: N/D ' <br />pH: 6.4-7 <br />VAPOR PRESSURE mmHg @ 20'C: N/D <br />SPECIFIC GRAVRY OR BULK DENSITY: 1.07 - 7.09 <br />gnmL <br />SOLUBILITY IN WATER: Miscible <br />PPEARANCE: Pale yelbw to green liquid <br />DOR: N/D <br />INTENSITY: N/D <br />SECTION N -FIRE AND EXPLOSION DATA <br />FLASH POIM (TEST METHOD): >200'F <br />AUTOIGNITION TEMP: N/D <br />FLAMMABILITY LIMBS IN AIR (°h BY VOL): <br />- LOWER: N!D <br />UPPER: N/D <br />NFPA 704 HAZARD CODES <br />HEALTH: NIR <br />FLAMMABLE: N/R <br />INSTABILITY: D <br />OTHER: N/R <br />NFPA 30 STORAGE CLASSIFICATION: Class III 8 <br />EXTINGUISHING MEDIUM: Use water fog, foam, <br />CO(2), or dry chemical extingu¢hing media. <br />SPECIAL FIREFIGHTING PROCEDURES: Firefight- <br />ers should be equipped with se0-containetl breathing <br />apparatus and turnout gear. <br />UNUSUAL FIRE EXPLOSION HAZARDS: None <br />krawn. <br />SELECT ACRONYM KEY <br />N!A -Not available; N/D -NIX determined; NIR - <br />Not rated; N/E -Not established <br />SECTION V -HEALTH DATA <br />TOXICOLOGICAL TEST DATA: - <br />Data br the formulated product <br />Rat, Oral LDSO (combined sexes) > 5000 mglkg <br />Rabbit, Dermal L050 (combined sexes)> 5000 mgrkg <br />Rat, Inhalation LC50 (4 hr, analytical) > 2.38 mglL <br />Rat, Inhalation LC50 (t hr tabulated) > 9.52 mglL <br />Rabbd, Eye lydtation - Nd kdtatbg <br />Rabbit, Skin Inflation -Not inflating <br />Guinea pig, Dermal Sensk¢er - Not a skin sensitizer. <br />OSHA, NTP, or IARC Carcinogen: Not listed. <br />EFFECTS OF OVEREXPOSURE: <br />See Product Label and Directions For Use for atl- <br />di[ional precautionary statements. <br />CAUTION: KEEP OUT OF REACH OF CHILDREN <br />HARMFUL IF INHALED OR ABBORBED THROUGH <br />SKIN, AVOID BREATHING SPRAY MIST. <br />AVOID CONTACT WITH SKIN, EYES ORCLOTHING. <br />6cisting medical conditbns aggravated by rats product: <br />Nom known <br />FIRST AID PROCEDURES <br />R inhaled: Move person to fresh air. If person is not <br />breathing, call 911 or an ambulance, then give artificial <br />respiration, preferabty mouth-to-mouth 0 possible. Call <br />a Dotson control center or doctor for tunher irealmeM <br />advice. <br />If on skin; Take o0 contaminated cbthing. Rinse skin <br />immediately cash plenty of water for 15-20 minutes. <br />Call a poison wnVOl center or doctor for treatment <br />advice. <br />If in eyes; Hok1 eye open aM rinse slowly and gently <br />wOh water for 15-20 minmes. Remove contact lenses, <br />0 present, after fast 5 minutes, then continue rinsing. <br />CaH a poison control center or doctor for treatment <br />advice. <br />tt swallowed: Call a poison conbol center or tloctw <br />immediatey for treatment advice. Have person sip <br />a glass of water 0 able to swalbw.' Do not induce <br />vomiting unless told to by a poison control center or <br />tlcetor. Do not gWe anymirg to an unconscious person. <br />Note to physician: There is no specific antidote for <br />exposure to this material. Treatment of over¢xposure <br />shook! be directed at the control of symptoms and the <br />clinical wnd0bns. <br />Note: Have the product wntainer or label with you <br />when calling a poison wnirol tamer or doctor or going <br />for treatment <br />SECTION VI - REALTIVIT' DATA <br />STABILITY: Stable. Do rat store talow 20'F. <br />CONDTIONS TO AVOID: Store in original container <br />in ccel,dry, web ventilated place away horn gnition <br />sources, heat or flame. <br />CHEMICAL INCOMPATIBILITY: Oxitl¢ing agems, <br />corrosive zinc, iron and mild steel <br />HAZARDOUS DECOMPOSITION PRODUCTS: In- <br />cluding b W rat limhetl to oxides of carbon and nitrogen. <br />HAZARDOUS POLYMERIZATION: Dces not occur. <br />CONDITIONS TO AVOID: Does not potymehze. <br />CORROSNE TO METAL: Na <br />OXIDIZER: No <br />SECTION VII -PERSONAL PROTECTION <br />Users of P oesticidal end use r~ should <br />refer to the rod d label for ersonal orotectNe- <br />e¢uioment reauiremenis: <br />RECOMMENDATIONS FFF~ MANUFACTURING. <br />COMMERCIAL BLENDING. AND PACKAGING <br />WORKERS: <br />Respiratory Protection: <br />Supplied air respirators should be worn 0large quanti- <br />ties of misUdust are generated or Drobnged exposure <br />possible. <br />Eye Protection: <br />Chemical goggles when respirator does not provide <br />eye protection. <br />Protective Clothing: <br />Gbves and protective clothing as necessary to prevem <br />skin wntact. <br />Ventilation: <br />Whenever possble, engineering controls should be <br />used to minim¢e~ the need for personal protective <br />equipment <br />SECTION VIII -ENVIRONMENTAL DATA <br />ENVIRONMENTAL TOXICITY DATA <br />See the product label for information regartling envF <br />ronmental toxicity. <br />SARA 3111312 REPORTING <br />FfRE: N <br />PRESSURE:N <br />RFACTIVITY: N <br />ACUTE: Y <br />CHRONIC: N <br />TPO(Ibs): N/R <br />SPILL AND LEAK PROCEDURES; <br />In case of large scale spillage of this product, avoid <br />contact, isolate area and keep out animals and unpro- <br />tatted persons. Call CHEMTREC (800 424-9300) ar <br />BASF Corporation (800 832-HELP), Far a small spill, <br />wear personal protective equipment as specifietl on <br />the label. <br />FOR A SOLID SPILL' Sweep solid into a drum for re- <br />use or disppsal. Remove personal protedNe equip• <br />ment and decontaminate M1pier b re-use, <br />HAZARDOUS SUBSTANCE SUPERFUND: No <br />RO(Ibs): None <br />WASTE DISPOSAL METHOD: <br />Pesticide wastes are storey hazardous. Wastes m- <br />suairg from ih¢ produM may be disposed of on site <br />or at an approved waste disposal fadlily. Improper <br />disposal of excess pesticide, spray ma or rinsate k <br />a viola0on of federal law. If these wastes cannot be <br />disposed of according to label instructions; conact the <br />state agency responsible far pesticide regulation or the <br />Hazardous Waste representatNe at th nearest EPA <br />Regional Office for guidance. <br />HAZARDOUS WASTE 40CFR261: Nq <br />HAZARDOUS WASTE NUMBER: Nom <br />CONTAINER DISPOSAL: <br />FOR PLASTIC CONTAINERS: Triple rinse (or equiva- <br />lent) and atltl rinsate to the spray tank. Then o0er for <br />recycling or reconditbning, qr puncture and depose of <br />in a sanitary landfill, or by incineration, or tl albwed by <br />state and local authod8es, by bumkg. If burned, stay <br />out of smoke. <br />FOR BULK CONTAINERS: Reusable containers <br />should be returned to the pokd of purchase for <br />cleaning and refillirg. <br />FOR MINIBULK CONTAINERS: Clean eA tanks on an <br />approved loading pad stl dnsate can be collected and <br />mired into the spray solution or into a tledx:ated tank. <br />Using a high pressure sprayer, rinse several Ames with <br />small vdumes of water ro minimize dnsele. <br />SECTION IX -SHIPPING DATA- PACKAGE AND <br />BULK <br />D.O.T. PROPER SHIPPING NAME (49CFR172.101- <br />102): None <br />HAZARDOUS SUBSTANCE (49CFR CERCLA LIST): <br />RO(Ibs): None <br />D.O.T. HAZARD CLASSIFICATION (CFR 172.701- <br />102): <br />PRMIARY <br />Nona <br />SECONDARY <br />D.O.T. LABELS REQUIRED (49CFR172.101.102): <br />Nona <br />D.O.T. PLACARDS REQUIRED (CFR772.504): <br />POISON CONSTITUENT (49CFR172.203(IC)): <br />BILL OF LADING DESCRIPTION <br />Compounds, tree or weed killing (herbic'ut¢s), NOIBN <br />This Product's rat regulatetl by the Department of <br />Transponatbn. <br />CC NO.: Not applicable <br />UNMA LODE: None <br />SECTION X -ADDITIONAL INFORMATION <br />Plateau° herbicide ' <br />EPA Reg. No. 241-385 <br />KEEP OUT OF REACH OF CHIL- <br />DREN <br />CAUTION <br />BASF Corporation <br />AgdcuOUral Protlucis Group <br />P.O.Box 13525, <br />Research Triangle Park, NC 27709 <br />(919)547-2000 <br />DISCLAIMER <br />IMPORTANT: WHILE THE DESCRIPTIONS, DE- <br />SIGNS, DATA AND INFORMATION CONTAINED <br />HEREIN ARE PRESENTED IN GOOD FAffH AND <br />BELIEVED TO BE ACCURATE, n IS PROVIDED <br />FOR YOUR GUIDANCE ONLY. BECAUSE MANY <br />FACTORS MAY AFFECT PROCESSING OR AP- <br />PLICATIONAISE, WE RECOMMEND THAT YOU <br />MAKE TESTS TO DETERMINE THE SUITABIL- <br />ITY OF A PRODUCT FOR YOUR PARTICULAR <br />PURPOSE PRIOR TO USE. NO WARRANTIES OF <br />ANY KIND, ERHER EXPRESS OR IMPLIED, IN- <br />CLUDING WARRANTIES OF MERCHANTABILITY <br />OR FITNESS FOR A PARTICULAR PURPOSE, ARE <br />MADE REGARDING PRODUCTS DESCRIBED OR <br />DESIGNS, DATA OR INFORMATION SET FORTH, <br />OR THAT THE PRODUCTS, DESIGNS, DATA OR <br />INFORMATION MAY BE USED WITHOUT INFRING- <br />ING THE INTELLECTUAL PROPERTY RIGHTS OF <br />Databass antl formal copyright ®by Vance Communication Corp.. Ail rights reserved <br />r <br />