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MATERIAL SAFETY DATA SHEET
<br />DUPONTLANDMARK
<br />P HERBtCiDE
<br />0000490
<br />evised 31-JUL-2003
<br />CHEMICAL PRODUCTICOMPANY IDENTIFICA~
<br />710N
<br />Material Identificatlon
<br />TELAR DF, OUST XP are registered trademarks o
<br />DuPont
<br />LANDMARK MP, DUPONT are trademarks of DUPOM.
<br />Tradenames and Synonyms
<br />DUPONT LANDMARK MP
<br />LANDMARK MP
<br />Company Identificatlon
<br />MANUFACTURE W DISTRIBUTOR
<br />DuPont
<br />1007 Market Street
<br />Wilmington, DE 19898
<br />PHONE NUMBERS
<br />Protluct Information: 1-800441-7515 (outside the U.S.
<br />302-774-1000)
<br />Transport Emergency: CHEMTREC 1-800-024-9300
<br />{outside U.S. 703-527-3807)
<br />Medical Emergency: T-800441-3637 (outside the U.S.
<br />302-774-1000)
<br />COMPOSITION/INFORMATION ON INGREDIENTS
<br />Components
<br />MataAl CAS NumMr X
<br />OUST XP ]4222-eT-2 50
<br />taULFOMETURON METHYL)
<br />(METHYL 2-tltlla,s-DIMEfHYL-2-PYRIMNIm'LI-
<br />gMINO1CARBONYLIAMINOiSULFONYIIBENZOATE)
<br />'TELAR pF 6a902-72-3 25
<br />(CHLORSULFUROM
<br />p-CgrtORO-NII4-METHO%Y-bMETHYL-1 3,5,-TRIAZIN-
<br />2YL)AMINOCARBONYLI BEN2ENESULFONAMIDE
<br />INERT INGREOIENTa TS
<br />Discbsure as a toxic chemical a required under Sec-
<br />ion 313 N Title III of the SuperlurW Amendments and
<br />,. eauthor¢ation Act of 1986 and 40 CFR paA 372.
<br />Components (Remarks)
<br />DuPont landmark is a two compartment baggetl prod
<br />act consisting of DuPont Ousl XP and Telar DF.
<br />HAZARDS IDENTIFICATION
<br />Emergency Overview
<br />CAUTION( Harmful if swallowed or absorbed Mrough
<br />skin. Causes moderate eye irdtalion. Avoid contact
<br />with eyes, skin ar clothing.
<br />Pot¢ntial Health Effects
<br />Based on animal tlata from wmponenis, eye contact
<br />whh DuPont landmark MP may rouse eye irritation
<br />with discomfort, testing, or hlumirg of vision.
<br />Basetl on animal tlak from components, Ingestion of
<br />DuPont Iantlmark MP may lead to red blood ceA de-
<br />atNCtlOrl.
<br />Carcinogenicity Iniormatbn
<br />None Mme components present in this material at
<br />concenirafrons equal to or greater than 0.1 % are gated
<br />by (ARC, MP, OSHA or ACGIH as a carcinogen.
<br />FIRST AID MEASURES
<br />First Aid
<br />EVE CONTACT:
<br />IF IN EYES: Hold eye open and rinse Blowy and gentry
<br />with water for 15-20 min Wes. Remove wntact lenses,
<br />H present, after the first 5 minutes, then continue dnsirg
<br />eye. Coil a poison control center wdoclor for ireatmem
<br />advice.
<br />INHALATION;
<br />IF INHALED: No speciFro intervention b indicated as
<br />the product 6 not likey to be hazardous by.inhalation,
<br />Consuk a physician d necessary.
<br />INGESTION:
<br />IF SWALLOWED: Call poison control center or doctor
<br />immediately for treatment aWice. Have a parson sip
<br />glass of water H able to swallow. Do not induce
<br />omRing unless told to do so by the Poison control
<br />enter or doctor. Do not give anyming by mouth to an
<br />unconscious person, i
<br />SKLN CONTACT:
<br />Catabase antl format copyright ®by Vance Communication Corp.. All tights reserved.
<br />F,T ':
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET
<br />IF ON SKIN OR CLOTHING: Take oft contaminated
<br />clothing. Rinse skin immediatey wkh plenty of wa-
<br />terfor 75-20 minutes. Call a poison control center Or
<br />doctor for treatment advice.
<br />Have the product container or label wNg you when
<br />calfng a poison control center or doctor, or going for
<br />treatment. You may also contact 1-800-041-3637 for
<br />emergency medical treatment information.
<br />FIRE FIGHTING MEASURES
<br />Flammable Properties
<br />~ Flammable IimHs in Air, % by Volume
<br />LEL: 0.092 g2
<br />Not a fire or explosion hazard.
<br />Like most organic powders or crystals, under severe
<br />dusting conditions, this matedaf may form expbsNe
<br />matures in air.
<br />Extinguishing Media
<br />Water Spray, Foam, Dry Chemical, C02.
<br />Fire Fighting Instmttions
<br />Wear sees-contained breathing apparatus. Wear fuA
<br />protective equipment. Use water spray. Runoff from
<br />fire wn[rol may be a pollution hazartl.
<br />ff area is expceetl to fre and condkbns permit let
<br />fire bum itseH ow. Burning chemicals may produce
<br />by-products more toxic than Lhe original makaial. If
<br />product b on fire, wear sees-contained breahing appa-
<br />retus antl fu0 protective equipment. Use water spray.
<br />Control mnoff.
<br />ACCIDENTAL RELEASE MEASURES
<br />Safeguards (Personnel)
<br />NOTE: Review FIRE FIGHTING MEASURES and
<br />HANDLING (PERSONNEL) secfx]ns before proceed-
<br />ing with clean-up. Use appropriate PERSONAL PRO-
<br />TECTIVE EQUIPMENT during clean-up.
<br />Emergency Response -Chemical resisknf coveralls,
<br />waterproof gbves, waterproof boots and face/eye pro-
<br />tection. H tlusting occurs, use NIOSH approved respi-
<br />rator protectbn.
<br />Initial Containm¢nt
<br />Dike spill. Prevent material from entenrg sewers, wa-
<br />krways, ar bw areas.
<br />Folbw applicable Fetleral, State/Provincial and Local
<br />laws/regubtbns:
<br />Spill Clean Up
<br />Shovel or sweep up.
<br />HANDLING AND STORAGE
<br />Handling (Personnel)
<br />USERS SHOULD: Wash hands before eating, drink-
<br />ing, chewing gum, using tobacco or using the toilet
<br />Do not gN in eyes. Avoid breathing dust, vapors or
<br />mist. Avoid wntact w0h eyes, skin or cothing. Wasn
<br />thoroughly after hantllirg. Wash cbllwg after use.
<br />Do not store or consume tootl, tlrink or tobacco in
<br />areas where they may become contaminated rotor this
<br />matedal.
<br />Handling (Physical Aspects)
<br />Avoid dust generation. Keep away from heat sparks
<br />and flanges.
<br />Storage
<br />Store product in orginal container ony. Do not con-
<br />taminate water, other pesticitles, fertil¢er, food or feed
<br />in storage.
<br />EngMeering Controls
<br />Use only with adequate ventilalbn. Ke¢p container
<br />fighty cbsed.
<br />Personal Protective Equipment
<br />Ahvays follow the label instructions when handling this
<br />product
<br />Use of Landmark MP herbicide on noncroD sites is not
<br />wAhin Me scope of the Worker Protection Standard.
<br />Do clot enter or aNow others ro enter the treated area
<br />untA sprays have drkd.
<br />Exposure Guidelines
<br />Applicable Exposure Limits
<br />ousr xP
<br />PEL (OSHA): Norte Established
<br />iLV (ACGIH): 5 mg/m3, 8 Hr. TWA A4
<br />4EL' (DuPont): 10 mg/m3, B 8 12 Hr. TWA total dust
<br />iELAR DF
<br />'EL (OSHA): None Established
<br />RV (ACGIH): None Establishetl
<br />AEL' (DuPont): 10 mg/m3, S 8 12 Hr. TWA .
<br />AEL is DuPonfs Accaptabk Exposure Limes. Where
<br />governmentaiy imposetl occupat(onal exposure corks
<br />which are bwer than the AEL are in effecl,.such limits
<br />shall take precedence.
<br />PHYSICAL AND CHEMICAL PROPERTIES
<br />Physical Data
<br />Physical Oata • Oust %P
<br />Solubiliy In wakr. Dispersible
<br />Odor. None
<br />Fonn: Solitl. dry flowable
<br />Color: OH-whke
<br />Bulk density (Loose): 33 ro/ca ft -
<br />Bulk densiy (Packed): 39 b/ctl ft
<br />Physical Data -Telar DP
<br />Solubility in water, Dispesibb
<br />pH: 4.5 Q 1 % suspension
<br />Otlor. None
<br />Fonn: Solid
<br />Color: Tan
<br />Specfic graviy: 0.69 ~ 25C (77F)
<br />Density: 0,64-0.74 g/mL
<br />STABIL171' AND REACTNITI'
<br />Chemical Stability
<br />Stable at normal temperetwes antl storage corM@bns.
<br />IncompatibNFty whh Other Materkls
<br />None reasonaby foreseealNe.
<br />Decomposition
<br />Decemposil'ron will not occur.
<br />Polymerization
<br />Poymenzafian wiy rwl occur.
<br />TOIUCOLOGICAL INFORMATION
<br />0 Animal Data
<br />Oust XP
<br />Inhalation 4 how LC50: > 5.3 mgrl in rats (Very low
<br />toxiciy by inhaklbn)
<br />Skin absorptron L050: > 5000 rcg4cg kg rabbits
<br />(Blighty to moderatey toxic by wntact)
<br />Oral LD50: > 5000 mg4cg h rats (Very kwr toxicity M
<br />Ingestion)
<br />Oust XP is slight to mdd skin kdknt and a mikf eye
<br />iniWnt bw is not a skm senstizer in animals.
<br />Single inhalation exposure with OustXP (Sutfdmetwan
<br />Methyl 75%) In rats roused sfigM to moderate body
<br />weight loss, nasal and owkr d'scharge, and other
<br />nonspecific effects.
<br />Single high oral doses of Oust XP (SullomeNron
<br />Methyl 75%) produced no clinical signs afi toxicity
<br />and rw lesions were observed dating pathobgical ex-
<br />amination of tissue. Repeated oral studies with the
<br />active kgredient SuHOmeturon Methyl, caused de-
<br />creased body weight gain, liver charges, red blootl cell
<br />hemoysis, and altered whke blood cell dilFerentktbn.
<br />Long-term exposure caused mBd hemoytb acemk.
<br />tlecreasetl body weight, aherafion of clinical chemical
<br />paramekrs, and changes k the bile tlwd.
<br />Oust XP (SUeometwon Methyl 75%) administered kg
<br />single high tlermal doses roused temporary severe to
<br />slight skin initation and sporerfic weigh bss.
<br />Animal testing indicates that the active ingredient Su4
<br />fometuron Methyl, does not have carcinogenic effects.
<br />In a two generatim rat reproductigg study wkh the ac-
<br />tlve ingredent Suyometuron Metlryl, decreased num-
<br />bers of pups were observetl at the 5000 ppm kvN, e
<br />dose that was also matematly toxb, No reproductive
<br />effects were observed at 500 ppm.
<br />SuHOmeturon mehyl did not produce developmerdal
<br />toxicity when tested in animals. Su6omeNron methyl
<br />did not produce genetic damage in bacterial or mam-
<br />malian ceq cutlures.
<br />Telar DF Herbicitle
<br />Oral tD50: > 5000 mg/kg in rats (Very krve toxicity) ~ ,
<br />Skin Absorption LD50: > 2000 mg/kg in rabbits
<br />{Slightly to moderatey toxb)
<br />Telar DF Hemicide is a mild reversible skin irritant and
<br />a moderate eye imkaM, but is not a skin Sensitizer In
<br />aramals.
<br />Chlorsulfuron
<br />Inhalation 4 hour LC50: > 5,9 mgll. in rats (Very kav
<br />loxbiry by InhaWibn}
<br />the effects in animals from repeated exposures by
<br />nhaWlion to ClUOrsuauron kickltle decreasetl weight
<br />'4~~1
<br />~viJi -.-)1, ..
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