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MATERIAL SAFETY DATA SHEET
<br />UPONT KRENITE
<br />BRUSH CONTROL
<br />GENT
<br />M0000022
<br />Revised 2-APR-2004
<br />CHEMICAL PRODUCT/COMPAM IDENTIFICA~
<br />TION
<br />Material Identification
<br />"Krenke" is a reg'stered trademark of DuPont
<br />"DuPont" (s a trademark or DuPont.
<br />Corporate MSDS Number: D0003056
<br />Grade: COMAINS 4 LB ACTIVE INGREDIEM PER
<br />GALLON
<br />Tradenames and Synonyms
<br />"KRENITE"
<br />'Y<RENITE" S BRUSH COMROL AGEM
<br />Company Identification
<br />MANUFACTURERlDtSTRIBUTOR
<br />DuPont
<br />7007 Market Sbeet
<br />Wilmington, DE 79898
<br />PHONE NUMBERS
<br />Product Information: 1-800-041-7515 (oNSide the U.S.
<br />302-774-7000)
<br />Transport Emergency: CHEMTREC 7-B00-424-9300
<br />(outside U.S.703-527-3887)
<br />Medical Emergenry: 1-800441-3637 (oWSide the U.S.
<br />302.774-1000)
<br />COMPOSITION/INFORMATION ON INGREDIEMS
<br />Components
<br />MM~rMI CAe NamMr %
<br />FOSAMINE AMMONIUM 25950.1}6 ~ <1.5
<br />(AMMONIUM aALT OF FOSAMINE IETHYL
<br />HYDROGEN IAMINOGRBDNYL)
<br />PHOSPHONATEg
<br />INERT INGREDIENFS 56.5
<br />~l~IAZARDS IDENTIFICATION
<br />v Emergency Overview
<br />CAUTIONI Causes (moderate) eye injury (irthation).
<br />Avoid contact wdh eyes err clomirg.
<br />Potential Health ENeets
<br />Inhalation of Krenue may cause irritation W nose,
<br />throat, arq lungs, with cough, dilficutty breatlixg w
<br />shortness of Dream, antl nonspecific discomfort. such
<br />as nausea, headache, or weakness.
<br />Skin contact wim Krenue may cause skin irritation with
<br />itching, bumirg, redness, swelling or rash. Sgnificam
<br />skin penetration end systemb toxicity after skin wntacl
<br />appears unlikey.
<br />There are inconclusive or unverified reports of human
<br />sensit¢atipn.
<br />Eye contact wim Krenue may cause eye irrdation wim
<br />tearing, pain or blurred vis'xm.
<br />Ingestion of high doses of Krenue may cause nonspc
<br />cific discomfort such as nausea, headache or we9k-
<br />ness.
<br />Carcinogenicity information
<br />None of the wmponents present in this material at
<br />concentrations equal M orgreater than 0.7 % are Ilsted
<br />by IARC, NTP, OSHA or ACGIH as a carcinogen.
<br />FIRST AID MEASURES
<br />Firbt Aid
<br />IF IN EYES: Hold eye open and rinse slowly and 9enty
<br />wdh wafer tar 75-20 minutes. Remove contact lenses,
<br />if present, aher the first five minutes, then wntinue
<br />rinsing eye. Call a person control center or doctor for
<br />treatment advice.
<br />IF INHALED: No specific Intervention is indicated as
<br />the compountl is not likely to be hazardous by inhala-
<br />tion. Consult a physician if necessary.
<br />~IF SWALLOWED: No speck intervention is ihdicatetl
<br />~-- s the compound is not likely to be hazardous by in-
<br />estbn. Consun a physician d necessary.
<br />F ON SKIN OR CLOTHING: No specfc intervention is
<br />ndicatetl as the compound's not likey to be hazardous
<br />to Skin by dermal exposure. Consult a physician fl
<br />necessary.
<br />UPDATES AVAILABLE AT WWW.GREENBOOK.NET
<br />Have the product container label with you when ceRng
<br />a poison control center or doctor, err going for ueat-
<br />ment VoG may also contaM 1-800-041-3637 (or med-
<br />ical emergencies involving this product.
<br />FIRE FIGHTING MEASURES
<br />Flammable Properties
<br />NM a fve or explosion hazard.
<br />Extinguishing Medla
<br />Water Spray, Foam, Dry Chemical, C02
<br />Fire Fighting Instructions
<br />Wear self-contained breathing apparatus. Wear
<br />full protective equipment Use water spray. Cool
<br />tanWCOntainer with water spmy. Runoff from fire
<br />comrol may be a potlutbn hazard.
<br />If area is exposed to fire and wnditbns permit, let
<br />fire bum OseB out. Burning chemicals may produce
<br />by-products more toxic than the original material. If
<br />product U on fire, wear selFwnfained breaming appa-
<br />ratus antl full protective equipment Use water spmy.
<br />coma runoff.
<br />ACCIDEMAL RELEASE MEASURES
<br />Safeguards (PersonneQ
<br />NOTE:. Review FIRE FIGHTING MEASURES and
<br />HANDLING (PERSONNEL) sections before proceetl-
<br />ing with clean-up. Use appropriate PERSONAL PRO
<br />TECTIVE EQUIPMENT during clean-up.
<br />Emergency Response - Chemical resistant wveralls,
<br />waterproof gbves, waterproof boots and face/eye pro-
<br />faction. If tlusting occurs, use NIOSH approved respF
<br />rator protection.
<br />Initial Containmem
<br />Dke spill. Prevent material horn entering sewers, wa-
<br />terways, w luwareas.
<br />Spill Clean Up
<br />Soak up with sawdust, sand, oil tlry or omen absorbent
<br />material. Shovel or sweep uD. Never return fo con-
<br />tainer for reuse. Scoop into bags or boxes calm plastic
<br />or aluminum sMvel.
<br />Accidental Release Measures
<br />If spill area h on ground near valuable plants or frees,
<br />remove top 2 inches of soil aher initial cleanup.
<br />HANDLING AND STORAGE
<br />Handling (Personnel)
<br />Do not get in eyes, on sk'D, or on clothing. Avoid
<br />breathing vapors or mist. Wash maroughy after han-
<br />dling. Do not store or consume food, drink or tobacco
<br />in areas where they may become contaminated wim
<br />rots material.
<br />USERS SHOULD: Wash hands before eating, drink-
<br />ing, chew'ug gum, using tobacco w using the toilet
<br />Storage
<br />Store product in odginal container ony. Do not iwr-
<br />W urinate water, other pesticitles, fertilizer, food w feed
<br />in storage.
<br />EXPOSURE COMROLS/PERSONAL PROTECTION
<br />Engineering Controls
<br />Use ony wim atlequate ventilation. Keep container
<br />tlghty closed.
<br />Personal Protective Equipment
<br />ADDlxztors antl other handlers must wear.
<br />Long-sleeved shirt and bug pants.
<br />Shoes plus socks.
<br />Folknv manufacturers instructions for clean-
<br />inglmaintaining PPE. If rro such instructions for
<br />washables, use detergent and hat water. Keep ant
<br />wash PPE seperatey from Omer laundry.
<br />PPE required for early entry to treated areas that is per-
<br />mined under the Worker Protection Standard and that
<br />involves contact wtth anything that has been ireate4
<br />such as plants, sol7, or water, h:
<br />Coverage,
<br />Shoes plus socks.
<br />Exposure Guidelines
<br />Exposure Limits
<br />"DuPont" "KRENTE" S BRUSH CONTROL AGEM
<br />DEL (OSHA): None Established
<br />fLV (ACGIH): None Established
<br />PHYSICAL AND CHEMICAL PROPERTIES
<br />Physical Data
<br />Solubliry in Water, Soluble
<br />Forth: L'qub
<br />Cobr. Colorless to brown
<br />Specific Grevly: 1.17 Q 24'C (75'F)
<br />i STABILITY AND REACTIVITY
<br />Chemical Stability
<br />Stable of normal temperatures antl storage condttions.
<br />Incompatibility with Other MateHals
<br />None reasonabty foreseeable.
<br />Decomposition
<br />DecomposNion wiN hat oxw.
<br />Poymedzation '
<br />Potymerization wiN not occur.
<br />TOXICOLOGICAL INFORMATION
<br />Animal Data .
<br />Krenita
<br />Orel LD50: > 5000 mglkg in rats
<br />Dermal LD50: > 5000 mglkg h rabbits
<br />Inhalation LC50, 4 hr. > 5.8 mg/L h rats
<br />Krenhe is a reversible naderate to severe eye kdtanL a
<br />meld [o moderate skin krilant. but not a skin sensitizer.
<br />The effects of skin exposure to high tloses of Krenfle
<br />include non-specific effects such as weigh bss. Ro-
<br />pealed exposures W borer doses caused no signs of
<br />roxbdy,
<br />The efface of ingestion of single high doses of Krenae
<br />include diarrhea and vomiting. Repeated w krrlgterm
<br />ingestion of borer doses caused mild diarrhea in some
<br />animaLS, but no Omer clinical w pathobgkal evidence
<br />of toxicity.
<br />The effects from single, high exposures by inhabtion
<br />of Krenfe, include resp'vatory end eye imilaaon, wegM
<br />bss, and weakness.
<br />No animal data are available to define the carcirwgenic
<br />hazards of Krenfle.
<br />Krenue has not caused devebpmental toxiciy in an-
<br />imals. The active Ingredient, Fosamil7e amranium.
<br />has not caused reproduciNe toxicity h animals.
<br />Tess have shown mat Krenfle does not cause genetic
<br />tlamage in bacterial w mammalian ceN cultures, w hi
<br />animals. It has tort been tested /err hedtabk 9erre8c
<br />damage.
<br />ECOLOGICAL INFORMATION
<br />Ecotoxicologiwl lnfonnation '
<br />FOSAMINE AMMONIUM
<br />AQUATIC TOXICRY:
<br />88 how LC50 -Rainbow trout 330 mgrL.
<br />96 hour LC50 - BluegBl sunfish: 590 rtg4.
<br />96 hour LC50 - Femead minnows: > 1000 nrglL.
<br />48 hour LC50 -Daphnia magna: 1524 ppm.
<br />AVIAN TOXICfTV: '
<br />LO50 - Malard Duck: > 5000 mgArg.
<br />LD50 - Ouag. > 5000 mglkg.
<br />Acute Dietary LC50 -Mallard Duck: > SS20 ppm.
<br />Acute Dietary LC50 - Quail > 5820 ppm
<br />DISPOSAL CONSIDERATIONS
<br />Waste Disposal
<br />Treatment, storage, trensportafbn, end disposal
<br />must be h accordance wflh applicable Federal,
<br />state/provincial, ant bcal regulations. Recover
<br />nonusable bee liquid and dispose of in approved and
<br />permitted incinerator. Do not flush to surface water or
<br />sanitary sewer system.
<br />Do not wntaminate water, food or feed by disposal.
<br />Wastes resulting from me use of rota product may be
<br />disposed of on ske or at an approved waste disposal
<br />facility.
<br />ENWRONMEMAL HAZARDS
<br />Do not appy directly to water, or to areas where sur•
<br />face water rs present, or ro intertidal areas below fire
<br />mean high water mark. Do not contaminate water by
<br />cleating of equipment w disposal of equiprtlent wash~
<br />waters.
<br />Con Winer Disposal '
<br />Tdple rinse (or equivalent) the container. Then offer for
<br />recycling w rewnd'1lioning, or puncture and dispose of
<br />in a sanitary lantlfill, w by incineration, or fl avowed by
<br />state and local authorities, by burning. If burned, slay
<br />out of smoke..
<br />Database and format copyright O by Vance Commanication Corp.. All nghis reserved. Y
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