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MATERIAL SAFETY DATA SHEET
<br />UPDATES AVAILABLE AT 1VWW.GREENBOOK.NET
<br />RSENAL®
<br />~Arsenalo herbicide
<br />Date Prepared: 6/13/2000
<br />Date Revised: 121/2004
<br />BASF Corporation
<br />Agdcullural Products Group
<br />P.O. Box 13628.
<br />Research Triangle Park, NC 27709 '
<br />(919) 597-2000
<br />EMERGENCY TELEPHONE NUMBERS:
<br />BASF Corporation: 1 (800) 832-HELP
<br />CHEMTREC: 7 (800) 424-9300 '
<br />SECTION 1
<br />Trade Name: Arsena herbicide
<br />Chemical Name: 2-(4,5-dihydro-4-methyF4-(1-me-
<br />thYlethyl}5-oxo-7 H-imdazoF2-yp-3-pyridinecarboxyfic
<br />acid, salt with 2-propanamine (7:1)
<br />Synonyms: IsgpropYlarrime of rrnazapyr; AC252, 925;
<br />Arsenal NS Herbicide
<br />FOrmUN: C(73)H(75)N(3)O(3).C(3)H(9)N
<br />Chemical Family: Imidazol'uwru3
<br />Mol Wt: 320.4
<br />SECTION ii -INGREDIENTS
<br />PEl/rLV .
<br />COMPONENT Cqs NO. % SOURCE
<br />Isopropybmhe e1510.93-0 aB.T O.e mplm3
<br />aaY PllmaraPYr TWA BASF
<br />emmmen0.ea
<br />MMe WA 71.3 Nona enublebe4
<br />SARA TKIe III Section 313: Not listed
<br />SECTION 111 -PHYSICAL DATA
<br />BOILING/MELTING POINT ~ 760mm Hg: N/D
<br />H: 6.6 - 72
<br />/APOR PRESSURE mmHg ~ 20'C: N/D
<br />PECIFIC GRAVITY OR BULK DENSITY: 7,04.1.07
<br />.._ - ~~
<br />SOLUBILITY IN WATER: Soluble
<br />APPEARANCE: Clear blue liquid
<br />ODOR: Ammonia
<br />' INTENSITY: Slight
<br />SECTION N -FIRE AND EXPLOSION DATA
<br />FLASH POINT (TEST METHOD): >270'F SFGC
<br />AUTOIGNRION TEMP: > 200'F
<br />FLAMMABILITY LIMITS IN AIR (% BV VOLj:
<br />LOWER: NID
<br />UPPER: N/D
<br />NFPA 704 HAZARD CODES
<br />HEALTH:?
<br />FLAMMABLE:1
<br />INSTABILITI':0
<br />OTHER: N/R
<br />NFPA 30 STORAGE CLASSIFICATION: Class 1118
<br />EXTINGUISHING MEDIUM: Use water fog, foam,
<br />' CO(2J, or dry chemical extinguishing media.
<br />SPECIAL FIREFIGHTING PROCEDURES: Firefght-
<br />ers should be equipped with self-contannetl breahing
<br />apparatus and turnout gear.
<br />UNUBUAL FIRE EXPLOSION HAZARDS: None
<br />known.
<br />SELECT ACRONYM KEY
<br />rated; N/E -Not
<br />SECTION V-HEALTH DATA
<br />TOXICOLOGICAL TEST DATA:
<br />Data for formulated product
<br />Rao Oral LD50 (combined sexes) > 50D0 mg/kg
<br />Rabbit, Dermal LD50 (combined sexes)> 2000 mg/kg
<br />at. Inhalation LC50 (4 hr) > 4.62 mgA.
<br />Rat, Inhalation LC50 (1 hr calculated) > 18.48 mgR
<br />ab68, Eye Irritation -Nor Irtilating
<br />fiabbi4 SkM Irritation - MUdly irr)tafing
<br />Guinea pig, Dermal Sensh¢er -Not Sensitizer
<br />OSHA, NTP, or IARC Carcinogen: Not Usted.
<br />EFFECTS OF OVEREXPOSURE:
<br />See Protluct Label and Directions For Use for ad-.
<br />ditional precautionary statements.
<br />CAUTION
<br />Avoid contact wiM skin, eyes, and clothing. Avod
<br />breathing spray mist.
<br />Existing medical wnditions aggravated by this product:
<br />None known.
<br />FIRST AID PROCEDURES
<br />If on skin: Wash with plenty of soap and water. Get
<br />medical aaention 8 imitation persists.
<br />N in eyes: Flush eyes calm plenty of wafer. Cott a
<br />physician if irreation persists. -
<br />If inhaled: Remove victim to hash air. If not breafh(n9,
<br />gNe adificial respiration, preferably moNh-to-nroutil.
<br />Get metlical adentbn.
<br />If swallowed: Call a physician or Po'son Control Cen-
<br />ter. Drink 1 or 2 glasses of water and induce vomitirg
<br />by touching back of throat with finger. If persona un-
<br />conscious, do not give anyNing by rtaLnh and do cwt
<br />induce vomiting.
<br />Note tp physician: Treat symptomaticaly. No specifw
<br />antitlote.
<br />Note: Have the product container or label wUh you
<br />when calling a po'son wntrol center or tlodor or going
<br />(or treatment
<br />SECTION W -REACTIVITY DATA
<br />STABILITY: Stable. Do not store 6ebw 32'F or above
<br />t00'F,
<br />CONDITIONS TO AVOID: Store in original wntainer
<br />in cool, dry, well ventilated place away horn ignition
<br />sources, heat or Oame.
<br />CHEMICAL INCOMPATIBILITY:Oxidizing agems and
<br />reducing agerds.
<br />HAZARDOUS DECOMPOSRION PRODUCTS: In-
<br />chiding but cwt IimUed to oxides o/carbon and nkrogen.
<br />HAZARDOUS POLYMERIZATION: Does not occur.-
<br />CONDfTIONS TO AVOID: Does not poymedze.
<br />CORROSIVE TO METAL: MUd steel, brass '
<br />- OXIDIZER: No
<br />SECTION WI-PERSONAL PROTECTION
<br />Users of ~ pesticitlal end use rD otlud shoal
<br />refer tote rp odutt label %or erg sonal protective
<br />ecuipment requirements. '
<br />RECOMMENDATIONS FOR MANUFACTURING.
<br />COMMERCIAL BLENDING. AND PACKAGING
<br />WORKERS:
<br />espuatory Protection: Supplied air respkators
<br />shoukt be worn if large quantities of misutlust are gen-
<br />eratetl or probnged exposure possible.
<br />Eye Protection: Chemical goggles when respirator
<br />j tlces not provide eye protection.
<br />Protective Clothigg: Gbves and protective cothing
<br />as necessary to prevent skin tooted.
<br />Ventilation: vVhenever possible, engineedng toneoa
<br />should be used to minimize the need for personal pro-
<br />tective equipment.
<br />SECTION WII -ENVIRONMENTAL DATA
<br />ENVIRONMENTAL TOXICITY DATA
<br />See the protlud label br biormatipn regarding eml-
<br />ronmental loxkiry.
<br />SARA 3111372 REPORTING
<br />FIRE: N
<br />PRESSURE: N
<br />REACTIVITY: N
<br />ACUTE: Y
<br />CHRONIC: N
<br />7P0(Ibsj: N!R
<br />SPILL AND LEAK PROCEDURES:
<br />In case of large scale spillage of this DrotlucL avoid
<br />contact, isolate area and keep out animals antl unpro-
<br />tatted persons. Call CHEMTREC (800 424-9300) or
<br />BASF Corporation (B00 832-HELP). For a small spill,
<br />wear personal protective equipment as specifietl on
<br />the label.
<br />FOR A LIQUID SPILL: Dike and contain the spill with
<br />loan material (santl, eadh, etc.) and transfer the liquid
<br />acct Solid diking materials to separate containers for
<br />disposal.
<br />FOR A SOLID SPILL: Sweep solitl into a tlmm for re-
<br />use or disposal. Remove personal prorective equip-
<br />ment and dewntaminate U prior to reuse.
<br />HAZARDOUS SUBSTANCE SUPERFUND: No
<br />RO(Ibsj: Nore
<br />WASTE DISPOSAL METHOD:-
<br />Pesf~citle wastes are aculey hazardous. Wastes re-
<br />sulting from this product may be disposed of an site
<br />or at an approved waste disposal faciliy. Improper
<br />disposal of excess pesticide, spray ma or dnsate is
<br />a violation of federal levr. If these wastes cannot be
<br />disposed of accordog to WDeI lnsbucrions, tooted the
<br />state agerwy responsible for pesOcide regulaaon or the
<br />Hazardous Waste represeruatNe at the neares! EPA
<br />Regional Office for guidance.
<br />HAZARDOUS WASTE 40CFR261; No
<br />HAZARDOUS WASTE NUMBER: None
<br />CONTAINER DISPOSAL:
<br />FOR PLASTIC CONTAINERS: Triple dose (or equNa-
<br />lent) and add dnsate to the spray tank. Then offer for
<br />recycUng or recondUioning, a purlcfure and dispose of
<br />in a sanitary IaM811, or by incineration, or d allowed by
<br />state and local aWtodlies, by burning. 7f 6umed, slay
<br />out of smoke.
<br />FOR BIAK CONTAINERS: Reusable containers
<br />shoultl be retumatl b the po'vu of purchase for
<br />cleaning and refdNng.
<br />FOR MINIBULK CONTAINERS: Clean all tanks on an
<br />approved loading pad so dnsate can be collected aM
<br />mined Into the spray solution or inb a tledicated tank,
<br />Using a high Dressure sprayer, dose several times with
<br />small volumes of water to minimze dnsate.
<br />SECTION IX-SHIPPING DATA-PACKAGE AND
<br />BULK
<br />D.O.T. PROPER SHIPPING NAME (49GFR772.101•
<br />t02j: None
<br />HAZARDOUS SUBSTANCE (49CFR CERCLA LIST):
<br />None
<br />RO(Ibs): None '
<br />D.O.T. HAZARD CLASSIFICATION (CFR 172.101-
<br />102):
<br />PRIMARY
<br />None
<br />SECONDARY
<br />None
<br />D.O.T. LABELS REQUIRED (49CFRt72.701-702):
<br />None
<br />D.O.T. PLACARDS REQUIRED (CFR772.504): None
<br />POISON CONSTRUEHT (49CFR172.T03(Kjj: None
<br />BILL OF LADING DESCRIPTION
<br />CompouMS, tree or weed killing, NOIBN
<br />This product is not regulated by the Depadmenl of
<br />7ransponation (DOT). N tloes not meet iM definition
<br />of DO7 corrosive (49 CFR 773.136}
<br />CC NO.: Nd apPrxable
<br />UNMA CODE:
<br />SECTION X - ADDRIONAL INFORMATION
<br />Arsena herhidda
<br />EPA Reg. No. 241.346 '
<br />KEEP OUT OF REACH OF CHIL-
<br />DREN
<br />CAUTION
<br />BASF Corporton
<br />AgriculNral Products Group
<br />P.O, Sox 13528, -
<br />Researoh Triangle Perk; NC 27709 '
<br />(919) 547-2000
<br />DISCLAIMER
<br />IMPORTANT: WHILE THE DESCRIPTIONS, DE-
<br />SIGNS, DATA AND INFORMATION CONTAINED
<br />HEREIN ARE PRESENTED IN GOOD FARH AND
<br />BELIEVED TO BE ACCURATE, R IS PROVIDED
<br />FOR YOUR GUIDANCE ONLY. BECAUSE MANY
<br />FACTORS MAY AFFECT PROCESSING OR AP-
<br />PLICATIONNSE, WE RECOMMEND THAT YOU
<br />MAKE TESTS TO DETERMINE THE SUITABIL-
<br />ITY OF A PRODUCT FOR YOUR PARTICULAR
<br />PURPOSE PRIOR TO USE. NO WARRANTIES OF
<br />ANY KIND, ETHER EXPRESS OR IMPLIED, IN-
<br />CLUDING WARRANTIES OF MERCHANTABILRY
<br />OR FrtNESS FORA PARTICULAR PURPOSE, ARE
<br />MADE REGARDING PRODUCTS DESCRIBED OR
<br />DESIGNS, DATA OR INFORMATION SET FORTH,
<br />OR THAT THE PRODUCTS, DESIGNS, DATA OR
<br />Database antl format copydght ©by Vance Communication Corporation. Atl rights reserved.
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