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' <br />~ S2 <br /> ~~ <br /> used to characterize the stream input from the dump. <br /> The estimated changes in selected water quality parameters as the result <br /> of deep percolation in a wet year are shown in Table 14. Even this worst- <br />] case estimate indicates a very small effect on the water quality in the <br />J stream. The sodium adsa.rption ratio (SAR) downstream of the waste pile was <br />~ computed by using the computed downstream concentrations of sadiun, calcium, <br />f <br />I and magnesium. <br />1 1 The active waste dump rests on alluvial material directly adjacent to <br /> the stream. The alluvium provides a degree pf storage, in addition to that <br />~~ in the dump itself, and tends to cause seepage into the stream to occur at <br /> a reduced rate, but over a longer period of time. Thus, the discharge of <br /> <br />~ 0.01 cfs from the waste material, based on a 30 day seepage period, may be <br />' larger than actually occurs. The small seep observed during this investi- <br /> gation issued from the refuse pile near the contact between the waste and <br /> the native ground., and was several feet higher than the water table in the <br /> alluvium. Apparently, the seepage occurred from a water table perched with- <br /> <br />in the dump. Evidence of other perched water 1n the pile was not observed -, <br /> and it is believed that the bulk of deep percolation enters the alluvium <br />I before discharge to the stream. Figure 14 compares the composition plots <br /> of alluvial waters with that in the adjacent stream. The alluvium shows <br /> concentrations of sodium and sulfate that are elevated in respect to the <br />l stream beyond that attributable to the overall elevated salt concfantration. <br /> In the case of spolum, a similar elevation was observed in the alluvium at <br /> the Maxwel_1 Mine where 1t was not passible fora refuse pile to have caused <br /> the change in composition. However, the shift in composition toweird in- <br />~ creased sulfate ~nas not observed elsewhere. Table l: shows a substantial <br /> concentration of sulfate in seepage from the waste pile and, in all probability, <br /> the seepage is responsible for the shift in composition. <br /> The elevated levels of sulfate in the waste dump are somewhat: surprising <br />i in view of the fact that all other data on subsurface waters indicate sodium- <br /> bicarbonate waters. There is evidence to suggest that the observed sulfate <br />~ does not derive from sulfuric acid production from pyrite. Four samples <br /> of the waste dump materials were analyzed for pyritic sulfur, showing only <br />, <br /> low quantities ranging from 0.03-0.04 percent. Also, the pH of 8.0, low <br />